Enhanced extraction of phenolic compounds from mango by-products using deep eutectic solvents

Deep eutectic solvents (DESs) potential for the extraction of polyphenolic compounds (PC) from mango by-products (peel and seed) was evaluated. Ultrasound (US) and agitation were applied to evaluate the effects of solvent and extraction methodology. The extracts were characterized with antioxidant c...

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Autores principales: Ojeda, Gonzalo Adrián, Vallejos, Margarita, Sgroppo, Sonia Cecilia, Sánchez Moreno, Concepción, De Ancos, Begoña
Formato: Artículo
Lenguaje:Inglés
Publicado: Elsevier 2024
Materias:
Bioactive
DFT
Eutectic solvent
Mangiferin
Mango
Acceso en línea:http://repositorio.unne.edu.ar/handle/123456789/54794
Aporte de:
RIUNNE - Repositorio Institucional de la Universidad Nacional del Nordeste (UNNE) de Universidad Nacional del Nordeste
id I48-R184-123456789-54794
record_format dspace
spelling I48-R184-123456789-547942025-07-15T18:11:37Z Enhanced extraction of phenolic compounds from mango by-products using deep eutectic solvents Ojeda, Gonzalo Adrián Vallejos, Margarita Sgroppo, Sonia Cecilia Sánchez Moreno, Concepción De Ancos, Begoña Bioactive DFT Eutectic solvent Mangiferin Mango Deep eutectic solvents (DESs) potential for the extraction of polyphenolic compounds (PC) from mango by-products (peel and seed) was evaluated. Ultrasound (US) and agitation were applied to evaluate the effects of solvent and extraction methodology. The extracts were characterized with antioxidant capacity and HPLC-DAD profile. A theoretical study was performed using density functional theory and the QTAIM approach. β-alanine and choline chloride based DESs were effective to extract PC from peel and seed. Some DES increased PC extraction up to three times for peel (23.05 ± 1.22 mg/g DW) and up to five time for seeds (60.01 ± 1.40 mg/g DW). The PC profile varied with the solvent (DES vs EtOH/MeOH), procedure (US vs agitation) and material (peel or seed). Mangiferin extraction from peels was significantly increased with β-alanine based DES (676.08 ± 20.34 μg/gDW). The strength of H-bonds had a determining effect on the viscosity of DESs. The solute-solvent solvation energy was suitable to estimate the strength of H-bond interactions between DES and target compounds. This study demonstrates the remarkable capacity of DESs to extract PC from mango by-products and provides insights into the factors controlling extraction properties. 2024-08-28T15:05:08Z 2024-08-28T15:05:08Z 2023-06 Artículo Ojeda. Gonzalo Adrián, et al., 2023. Enhanced extraction of phenolic compounds from mango by-products using deep eutectic solvents. Heliyon. Amsterdam: Elsevier, vol. 9, no. 6, p. 1-14. ISSN 2405-8440. 2405-8440 http://repositorio.unne.edu.ar/handle/123456789/54794 eng https://doi.org/10.1016/j.heliyon.2023.e16912 openAccess http://creativecommons.org/licenses/by-nc-nd/2.5/ar/ application/pdf p. 1-14 application/pdf Elsevier Heliyon, 2023, vol. 9, no. 6, p. 1-14.
institution Universidad Nacional del Nordeste
institution_str I-48
repository_str R-184
collection RIUNNE - Repositorio Institucional de la Universidad Nacional del Nordeste (UNNE)
language Inglés
topic Bioactive
DFT
Eutectic solvent
Mangiferin
Mango
spellingShingle Bioactive
DFT
Eutectic solvent
Mangiferin
Mango
Ojeda, Gonzalo Adrián
Vallejos, Margarita
Sgroppo, Sonia Cecilia
Sánchez Moreno, Concepción
De Ancos, Begoña
Enhanced extraction of phenolic compounds from mango by-products using deep eutectic solvents
topic_facet Bioactive
DFT
Eutectic solvent
Mangiferin
Mango
description Deep eutectic solvents (DESs) potential for the extraction of polyphenolic compounds (PC) from mango by-products (peel and seed) was evaluated. Ultrasound (US) and agitation were applied to evaluate the effects of solvent and extraction methodology. The extracts were characterized with antioxidant capacity and HPLC-DAD profile. A theoretical study was performed using density functional theory and the QTAIM approach. β-alanine and choline chloride based DESs were effective to extract PC from peel and seed. Some DES increased PC extraction up to three times for peel (23.05 ± 1.22 mg/g DW) and up to five time for seeds (60.01 ± 1.40 mg/g DW). The PC profile varied with the solvent (DES vs EtOH/MeOH), procedure (US vs agitation) and material (peel or seed). Mangiferin extraction from peels was significantly increased with β-alanine based DES (676.08 ± 20.34 μg/gDW). The strength of H-bonds had a determining effect on the viscosity of DESs. The solute-solvent solvation energy was suitable to estimate the strength of H-bond interactions between DES and target compounds. This study demonstrates the remarkable capacity of DESs to extract PC from mango by-products and provides insights into the factors controlling extraction properties.
format Artículo
author Ojeda, Gonzalo Adrián
Vallejos, Margarita
Sgroppo, Sonia Cecilia
Sánchez Moreno, Concepción
De Ancos, Begoña
author_facet Ojeda, Gonzalo Adrián
Vallejos, Margarita
Sgroppo, Sonia Cecilia
Sánchez Moreno, Concepción
De Ancos, Begoña
author_sort Ojeda, Gonzalo Adrián
title Enhanced extraction of phenolic compounds from mango by-products using deep eutectic solvents
title_short Enhanced extraction of phenolic compounds from mango by-products using deep eutectic solvents
title_full Enhanced extraction of phenolic compounds from mango by-products using deep eutectic solvents
title_fullStr Enhanced extraction of phenolic compounds from mango by-products using deep eutectic solvents
title_full_unstemmed Enhanced extraction of phenolic compounds from mango by-products using deep eutectic solvents
title_sort enhanced extraction of phenolic compounds from mango by-products using deep eutectic solvents
publisher Elsevier
publishDate 2024
url http://repositorio.unne.edu.ar/handle/123456789/54794
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AT vallejosmargarita enhancedextractionofphenoliccompoundsfrommangobyproductsusingdeepeutecticsolvents
AT sgropposoniacecilia enhancedextractionofphenoliccompoundsfrommangobyproductsusingdeepeutecticsolvents
AT sanchezmorenoconcepcion enhancedextractionofphenoliccompoundsfrommangobyproductsusingdeepeutecticsolvents
AT deancosbegona enhancedextractionofphenoliccompoundsfrommangobyproductsusingdeepeutecticsolvents
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