Thermal decomposition of cyclic glutaraldehydeDiperoxide UV spectroscopic analysis
The thermal decomposition reaction of Cyclic GlutaraldehydeDiperoxide (3,6-dibutanal-1,2,4,5-tetroxane) in solution of methanol in the temperature range of 130.0-166.0°C and initial concentration of 1.69 x10-3 mol/L, follows first-order kinetic laws. Under the experimental conditions, the activa...
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| Autores principales: | , , , , , |
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| Formato: | Artículo |
| Lenguaje: | Inglés |
| Publicado: |
Science Journal of Pure and Applied Chemistry
2023
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| Materias: | |
| Acceso en línea: | http://repositorio.unne.edu.ar/handle/123456789/51647 |
| Aporte de: |
| Sumario: | The thermal decomposition reaction of Cyclic
GlutaraldehydeDiperoxide (3,6-dibutanal-1,2,4,5-tetroxane) in
solution of methanol in the temperature range of 130.0-166.0°C and
initial concentration of 1.69 x10-3 mol/L, follows first-order kinetic
laws. Under the experimental conditions, the activation parameters of
the reaction are bigger than the obtained ones for other tetroxanos
with different substituent’s in the same solvent, which indicates us
that the substituents stabilize the condition of transition decreasing
the energetic barrier. |
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