Thermal decomposition of cyclic glutaraldehydeDiperoxide UV spectroscopic analysis

The thermal decomposition reaction of Cyclic GlutaraldehydeDiperoxide (3,6-dibutanal-1,2,4,5-tetroxane) in solution of methanol in the temperature range of 130.0-166.0°C and initial concentration of 1.69 x10-3 mol/L, follows first-order kinetic laws. Under the experimental conditions, the activa...

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Autores principales: Bordón, Alexander Germán, Jorge, María Josefa, Profeta, Mariela Inés, Romero, Jorge Marcelo, Jorge, Nelly Lidia, Castro, Germán Alberto
Formato: Artículo
Lenguaje:Inglés
Publicado: Science Journal of Pure and Applied Chemistry 2023
Materias:
DPG
Thermal descomposition
Solvent
Acceso en línea:http://repositorio.unne.edu.ar/handle/123456789/51647
Aporte de:
RIUNNE - Repositorio Institucional de la Universidad Nacional del Nordeste (UNNE) de Universidad Nacional del Nordeste
id I48-R184-123456789-51647
record_format dspace
spelling I48-R184-123456789-516472025-03-06T10:57:54Z Thermal decomposition of cyclic glutaraldehydeDiperoxide UV spectroscopic analysis Bordón, Alexander Germán Jorge, María Josefa Profeta, Mariela Inés Romero, Jorge Marcelo Jorge, Nelly Lidia Castro, Germán Alberto DPG Thermal descomposition Solvent The thermal decomposition reaction of Cyclic GlutaraldehydeDiperoxide (3,6-dibutanal-1,2,4,5-tetroxane) in solution of methanol in the temperature range of 130.0-166.0°C and initial concentration of 1.69 x10-3 mol/L, follows first-order kinetic laws. Under the experimental conditions, the activation parameters of the reaction are bigger than the obtained ones for other tetroxanos with different substituent’s in the same solvent, which indicates us that the substituents stabilize the condition of transition decreasing the energetic barrier. 2023-06-08T13:14:40Z 2023-06-08T13:14:40Z 2015 Artículo Bordón, Alexander Germán, Jorge, María Josefa, Profeta, Mariela Inés, 2015. Thermal decomposition of cyclic glutaraldehydeDiperoxide UV spectroscopic analysis. Science Journal of Pure and Applied Chemistry. Nigeria: Science Journal of Pure and Applied Chemistry, vol. 2015, p. 1-5. ISSN 2276-6308. 2276-6308 http://repositorio.unne.edu.ar/handle/123456789/51647 eng openAccess http://creativecommons.org/licenses/by-nc-nd/2.5/ar/ application/pdf p. 1-5 application/pdf Science Journal of Pure and Applied Chemistry Science Journal of Pure and Applied Chemistry, 2015, vol. 2015, p. 1-5.
institution Universidad Nacional del Nordeste
institution_str I-48
repository_str R-184
collection RIUNNE - Repositorio Institucional de la Universidad Nacional del Nordeste (UNNE)
language Inglés
topic DPG
Thermal descomposition
Solvent
spellingShingle DPG
Thermal descomposition
Solvent
Bordón, Alexander Germán
Jorge, María Josefa
Profeta, Mariela Inés
Romero, Jorge Marcelo
Jorge, Nelly Lidia
Castro, Germán Alberto
Thermal decomposition of cyclic glutaraldehydeDiperoxide UV spectroscopic analysis
topic_facet DPG
Thermal descomposition
Solvent
description The thermal decomposition reaction of Cyclic GlutaraldehydeDiperoxide (3,6-dibutanal-1,2,4,5-tetroxane) in solution of methanol in the temperature range of 130.0-166.0°C and initial concentration of 1.69 x10-3 mol/L, follows first-order kinetic laws. Under the experimental conditions, the activation parameters of the reaction are bigger than the obtained ones for other tetroxanos with different substituent’s in the same solvent, which indicates us that the substituents stabilize the condition of transition decreasing the energetic barrier.
format Artículo
author Bordón, Alexander Germán
Jorge, María Josefa
Profeta, Mariela Inés
Romero, Jorge Marcelo
Jorge, Nelly Lidia
Castro, Germán Alberto
author_facet Bordón, Alexander Germán
Jorge, María Josefa
Profeta, Mariela Inés
Romero, Jorge Marcelo
Jorge, Nelly Lidia
Castro, Germán Alberto
author_sort Bordón, Alexander Germán
title Thermal decomposition of cyclic glutaraldehydeDiperoxide UV spectroscopic analysis
title_short Thermal decomposition of cyclic glutaraldehydeDiperoxide UV spectroscopic analysis
title_full Thermal decomposition of cyclic glutaraldehydeDiperoxide UV spectroscopic analysis
title_fullStr Thermal decomposition of cyclic glutaraldehydeDiperoxide UV spectroscopic analysis
title_full_unstemmed Thermal decomposition of cyclic glutaraldehydeDiperoxide UV spectroscopic analysis
title_sort thermal decomposition of cyclic glutaraldehydediperoxide uv spectroscopic analysis
publisher Science Journal of Pure and Applied Chemistry
publishDate 2023
url http://repositorio.unne.edu.ar/handle/123456789/51647
work_keys_str_mv AT bordonalexandergerman thermaldecompositionofcyclicglutaraldehydediperoxideuvspectroscopicanalysis
AT jorgemariajosefa thermaldecompositionofcyclicglutaraldehydediperoxideuvspectroscopicanalysis
AT profetamarielaines thermaldecompositionofcyclicglutaraldehydediperoxideuvspectroscopicanalysis
AT romerojorgemarcelo thermaldecompositionofcyclicglutaraldehydediperoxideuvspectroscopicanalysis
AT jorgenellylidia thermaldecompositionofcyclicglutaraldehydediperoxideuvspectroscopicanalysis
AT castrogermanalberto thermaldecompositionofcyclicglutaraldehydediperoxideuvspectroscopicanalysis
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