Structures and Properties of Ordered Nanostructured Oxides and Composite Materials
Ordered nanostructured oxides are materials in which nano-objects are arranged in an array with a defined periodicity. Among them, ordered mesoporous oxides (OMPO), such as TiO2, SiO2, and ZrO2 are considered for a wide range of technological applications due to their low-cost reproducible synthesis...
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todo:paper_97835276_v2-3_n_p1031_MartinezRicci2023-10-03T16:45:07Z Structures and Properties of Ordered Nanostructured Oxides and Composite Materials Martínez Ricci, M.L. Bilmes, S.A. Composite materials Mesostructured thin films Optical properties Ordered mesoporous oxides Ordered nanostructured oxides Photonic crystals Sol-gel method Chemical stability Composite materials Energy gap Film preparation Mesoporous materials Metal nanoparticles Nanocomposite films Optical properties Photonic band gap Photonic crystals Plasmonics Self assembly Silica Sol-gel process Sol-gels Thin films Titanium dioxide Zirconia Amphiphilic molecules Mesostructured Nanostructured oxides Ordered mesoporous Semiconductor nanoparticles Sol-gel synthesis process Structures and properties Technological applications Optical films Ordered nanostructured oxides are materials in which nano-objects are arranged in an array with a defined periodicity. Among them, ordered mesoporous oxides (OMPO), such as TiO2, SiO2, and ZrO2 are considered for a wide range of technological applications due to their low-cost reproducible synthesis and chemical stability. These OMPO films exhibit calibrated size pores (2-50nm) and a large surface area that can be tuned using sol-gel synthetic pathways combined with self-assembly of amphiphilic molecules. Functional optical properties of OMPO films can be tailored reacting to changes in the environment, such as relative humidity or vapors in a selective way. Multilayers of OMPO with different composition grown by sol-gel behave as photonic crystals where the photonic band gap can be fitted by tuning the pore's size and shape. In addition to these composite structures, those derived from embedding metal or semiconductor nanoparticles within OMPO films produce new plasmonic and luminescent materials enhancing the possibility of new applications. In this chapter we present some basic concepts on the optical properties of OMPO in relation with sol-gel synthesis process, and we discuss the potential applications for the design of optical sensors. © 2015 Wiley-VCH Verlag GmbH & Co. KGaA. CHAP info:eu-repo/semantics/openAccess http://creativecommons.org/licenses/by/2.5/ar http://hdl.handle.net/20.500.12110/paper_97835276_v2-3_n_p1031_MartinezRicci |
institution |
Universidad de Buenos Aires |
institution_str |
I-28 |
repository_str |
R-134 |
collection |
Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA) |
topic |
Composite materials Mesostructured thin films Optical properties Ordered mesoporous oxides Ordered nanostructured oxides Photonic crystals Sol-gel method Chemical stability Composite materials Energy gap Film preparation Mesoporous materials Metal nanoparticles Nanocomposite films Optical properties Photonic band gap Photonic crystals Plasmonics Self assembly Silica Sol-gel process Sol-gels Thin films Titanium dioxide Zirconia Amphiphilic molecules Mesostructured Nanostructured oxides Ordered mesoporous Semiconductor nanoparticles Sol-gel synthesis process Structures and properties Technological applications Optical films |
spellingShingle |
Composite materials Mesostructured thin films Optical properties Ordered mesoporous oxides Ordered nanostructured oxides Photonic crystals Sol-gel method Chemical stability Composite materials Energy gap Film preparation Mesoporous materials Metal nanoparticles Nanocomposite films Optical properties Photonic band gap Photonic crystals Plasmonics Self assembly Silica Sol-gel process Sol-gels Thin films Titanium dioxide Zirconia Amphiphilic molecules Mesostructured Nanostructured oxides Ordered mesoporous Semiconductor nanoparticles Sol-gel synthesis process Structures and properties Technological applications Optical films Martínez Ricci, M.L. Bilmes, S.A. Structures and Properties of Ordered Nanostructured Oxides and Composite Materials |
topic_facet |
Composite materials Mesostructured thin films Optical properties Ordered mesoporous oxides Ordered nanostructured oxides Photonic crystals Sol-gel method Chemical stability Composite materials Energy gap Film preparation Mesoporous materials Metal nanoparticles Nanocomposite films Optical properties Photonic band gap Photonic crystals Plasmonics Self assembly Silica Sol-gel process Sol-gels Thin films Titanium dioxide Zirconia Amphiphilic molecules Mesostructured Nanostructured oxides Ordered mesoporous Semiconductor nanoparticles Sol-gel synthesis process Structures and properties Technological applications Optical films |
description |
Ordered nanostructured oxides are materials in which nano-objects are arranged in an array with a defined periodicity. Among them, ordered mesoporous oxides (OMPO), such as TiO2, SiO2, and ZrO2 are considered for a wide range of technological applications due to their low-cost reproducible synthesis and chemical stability. These OMPO films exhibit calibrated size pores (2-50nm) and a large surface area that can be tuned using sol-gel synthetic pathways combined with self-assembly of amphiphilic molecules. Functional optical properties of OMPO films can be tailored reacting to changes in the environment, such as relative humidity or vapors in a selective way. Multilayers of OMPO with different composition grown by sol-gel behave as photonic crystals where the photonic band gap can be fitted by tuning the pore's size and shape. In addition to these composite structures, those derived from embedding metal or semiconductor nanoparticles within OMPO films produce new plasmonic and luminescent materials enhancing the possibility of new applications. In this chapter we present some basic concepts on the optical properties of OMPO in relation with sol-gel synthesis process, and we discuss the potential applications for the design of optical sensors. © 2015 Wiley-VCH Verlag GmbH & Co. KGaA. |
format |
CHAP |
author |
Martínez Ricci, M.L. Bilmes, S.A. |
author_facet |
Martínez Ricci, M.L. Bilmes, S.A. |
author_sort |
Martínez Ricci, M.L. |
title |
Structures and Properties of Ordered Nanostructured Oxides and Composite Materials |
title_short |
Structures and Properties of Ordered Nanostructured Oxides and Composite Materials |
title_full |
Structures and Properties of Ordered Nanostructured Oxides and Composite Materials |
title_fullStr |
Structures and Properties of Ordered Nanostructured Oxides and Composite Materials |
title_full_unstemmed |
Structures and Properties of Ordered Nanostructured Oxides and Composite Materials |
title_sort |
structures and properties of ordered nanostructured oxides and composite materials |
url |
http://hdl.handle.net/20.500.12110/paper_97835276_v2-3_n_p1031_MartinezRicci |
work_keys_str_mv |
AT martinezricciml structuresandpropertiesoforderednanostructuredoxidesandcompositematerials AT bilmessa structuresandpropertiesoforderednanostructuredoxidesandcompositematerials |
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1807323846994296832 |