Functionalized dithienylthiazolo[5, 4-d]thiazoles for solution-processable organic field-effect transistors
A series of 5′-aryl-substituted 2, 5-bis(3′-hexylthiophen- 2′-yl)thiazolo[5, 4-d]thiazole derivatives was synthesized and these expanded semiconductors were investigated as active materials for solution-processable organic field-effect transistors. Field-effect mobilities of up to 10 -3 cm 2V -1s -1...
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| Acceso en línea: | http://hdl.handle.net/20.500.12110/paper_21926506_v77_n10_p923_VanMierloo |
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todo:paper_21926506_v77_n10_p923_VanMierloo2023-10-03T16:40:20Z Functionalized dithienylthiazolo[5, 4-d]thiazoles for solution-processable organic field-effect transistors Van Mierloo, S. Vasseur, K. Van Den Brande, N. Boyukbayram, A.E. Ruttens, B. Rodriguez, S.D. Botek, E. Liégeois, V. D'Haen, J. Adriaensens, P.J. Heremans, P. Champagne, B. Van Assche, G. Lutsen, L. Vanderzande, D.J. Maes, W. Conducting materials Field-effect transistors Organic electronics Thiazolo[5,4-d]thiazoles Thin film morphology A series of 5′-aryl-substituted 2, 5-bis(3′-hexylthiophen- 2′-yl)thiazolo[5, 4-d]thiazole derivatives was synthesized and these expanded semiconductors were investigated as active materials for solution-processable organic field-effect transistors. Field-effect mobilities of up to 10 -3 cm 2V -1s -1 were obtained, representing the first reasonable FET behavior for highly soluble thiazolo[5, 4-d]thiazole-based small organic compounds suitable for printable electronics. Thermal and electrooptical material properties were studied by thermogravimetric analysis, differential scanning calorimetry, cyclic voltammetry, and UV/Vis spectroscopy. Trends in thermal and optical data were supported by (time-dependent) density functional theory calculations. Additional X-ray diffraction, atomic force microscopy, and scanning electron microscopy studies provided insight in the relationship between the molecular structures, film morphologies, and FET performances. The fibrillar microcrystalline structure observed for the best-performing thienyl-substituted material was linked to the high mobility. © 2012 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim. Fil:Rodriguez, S.D. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. Fil:Botek, E. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. JOUR info:eu-repo/semantics/openAccess http://creativecommons.org/licenses/by/2.5/ar http://hdl.handle.net/20.500.12110/paper_21926506_v77_n10_p923_VanMierloo |
| institution |
Universidad de Buenos Aires |
| institution_str |
I-28 |
| repository_str |
R-134 |
| collection |
Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA) |
| topic |
Conducting materials Field-effect transistors Organic electronics Thiazolo[5,4-d]thiazoles Thin film morphology |
| spellingShingle |
Conducting materials Field-effect transistors Organic electronics Thiazolo[5,4-d]thiazoles Thin film morphology Van Mierloo, S. Vasseur, K. Van Den Brande, N. Boyukbayram, A.E. Ruttens, B. Rodriguez, S.D. Botek, E. Liégeois, V. D'Haen, J. Adriaensens, P.J. Heremans, P. Champagne, B. Van Assche, G. Lutsen, L. Vanderzande, D.J. Maes, W. Functionalized dithienylthiazolo[5, 4-d]thiazoles for solution-processable organic field-effect transistors |
| topic_facet |
Conducting materials Field-effect transistors Organic electronics Thiazolo[5,4-d]thiazoles Thin film morphology |
| description |
A series of 5′-aryl-substituted 2, 5-bis(3′-hexylthiophen- 2′-yl)thiazolo[5, 4-d]thiazole derivatives was synthesized and these expanded semiconductors were investigated as active materials for solution-processable organic field-effect transistors. Field-effect mobilities of up to 10 -3 cm 2V -1s -1 were obtained, representing the first reasonable FET behavior for highly soluble thiazolo[5, 4-d]thiazole-based small organic compounds suitable for printable electronics. Thermal and electrooptical material properties were studied by thermogravimetric analysis, differential scanning calorimetry, cyclic voltammetry, and UV/Vis spectroscopy. Trends in thermal and optical data were supported by (time-dependent) density functional theory calculations. Additional X-ray diffraction, atomic force microscopy, and scanning electron microscopy studies provided insight in the relationship between the molecular structures, film morphologies, and FET performances. The fibrillar microcrystalline structure observed for the best-performing thienyl-substituted material was linked to the high mobility. © 2012 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim. |
| format |
JOUR |
| author |
Van Mierloo, S. Vasseur, K. Van Den Brande, N. Boyukbayram, A.E. Ruttens, B. Rodriguez, S.D. Botek, E. Liégeois, V. D'Haen, J. Adriaensens, P.J. Heremans, P. Champagne, B. Van Assche, G. Lutsen, L. Vanderzande, D.J. Maes, W. |
| author_facet |
Van Mierloo, S. Vasseur, K. Van Den Brande, N. Boyukbayram, A.E. Ruttens, B. Rodriguez, S.D. Botek, E. Liégeois, V. D'Haen, J. Adriaensens, P.J. Heremans, P. Champagne, B. Van Assche, G. Lutsen, L. Vanderzande, D.J. Maes, W. |
| author_sort |
Van Mierloo, S. |
| title |
Functionalized dithienylthiazolo[5, 4-d]thiazoles for solution-processable organic field-effect transistors |
| title_short |
Functionalized dithienylthiazolo[5, 4-d]thiazoles for solution-processable organic field-effect transistors |
| title_full |
Functionalized dithienylthiazolo[5, 4-d]thiazoles for solution-processable organic field-effect transistors |
| title_fullStr |
Functionalized dithienylthiazolo[5, 4-d]thiazoles for solution-processable organic field-effect transistors |
| title_full_unstemmed |
Functionalized dithienylthiazolo[5, 4-d]thiazoles for solution-processable organic field-effect transistors |
| title_sort |
functionalized dithienylthiazolo[5, 4-d]thiazoles for solution-processable organic field-effect transistors |
| url |
http://hdl.handle.net/20.500.12110/paper_21926506_v77_n10_p923_VanMierloo |
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