A monoclinic form of dendocarbin A: A borderline case of one-dimensional isostructural polymorphism

The title compound, dendocarbin A [systematic name: (1R,5aS,9aS,9bR)-1-hydroxy-6,6,9a-trimethyldodecahydronaphtho[1,2-c]furan-3-one], C15H22O3, is a sesquiterpene lactone isolated from Drimys winteri var chilensis. The monoclinic phase described herein displays an identical molecular structure to th...

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Autores principales: Paz, C., Burgos, V., Suarez, S., Baggio, R.
Formato: JOUR
Materias:
Dendocarbin A
Drimys winteri extract
isostructural polymorphism
monoclinic polymorphic form crystal structure
natural product
sesquiterpene lactone
Esters
Isostructural
Natural products
Polymorphic forms
Sesquiterpene lactones
Crystal structure
Drimys winteri
dendocarbin A
lactone
sesquiterpene
chemical structure
chemistry
crystallization
Drimys
isolation and purification
Crystallization
Lactones
Molecular Structure
Sesquiterpenes
Acceso en línea:http://hdl.handle.net/20.500.12110/paper_20532296_v71_n_p294_Paz
Aporte de:
Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA) de Universidad de Buenos Aires
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record_format dspace
spelling todo:paper_20532296_v71_n_p294_Paz2023-10-03T16:39:00Z A monoclinic form of dendocarbin A: A borderline case of one-dimensional isostructural polymorphism Paz, C. Burgos, V. Suarez, S. Baggio, R. Dendocarbin A Drimys winteri extract isostructural polymorphism monoclinic polymorphic form crystal structure natural product sesquiterpene lactone Esters Dendocarbin A Drimys winteri extract Isostructural Natural products Polymorphic forms Sesquiterpene lactones Crystal structure Drimys winteri dendocarbin A lactone sesquiterpene chemical structure chemistry crystallization Drimys isolation and purification Crystallization Drimys Lactones Molecular Structure Sesquiterpenes The title compound, dendocarbin A [systematic name: (1R,5aS,9aS,9bR)-1-hydroxy-6,6,9a-trimethyldodecahydronaphtho[1,2-c]furan-3-one], C15H22O3, is a sesquiterpene lactone isolated from Drimys winteri var chilensis. The monoclinic phase described herein displays an identical molecular structure to the orthorhombic phase that we reported previously [Paz Robles et al. (2014). Acta Cryst. C70, 1007-1010], while varying significantly in chain pitch, and can thus be considered as a borderline case of one-dimensional isostructural polymorphism. © 2015 International Union of Crystallography. Fil:Suarez, S. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. JOUR info:eu-repo/semantics/openAccess http://creativecommons.org/licenses/by/2.5/ar http://hdl.handle.net/20.500.12110/paper_20532296_v71_n_p294_Paz
institution Universidad de Buenos Aires
institution_str I-28
repository_str R-134
collection Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA)
topic Dendocarbin A
Drimys winteri extract
isostructural polymorphism
monoclinic polymorphic form crystal structure
natural product
sesquiterpene lactone
Esters
Dendocarbin A
Drimys winteri extract
Isostructural
Natural products
Polymorphic forms
Sesquiterpene lactones
Crystal structure
Drimys winteri
dendocarbin A
lactone
sesquiterpene
chemical structure
chemistry
crystallization
Drimys
isolation and purification
Crystallization
Drimys
Lactones
Molecular Structure
Sesquiterpenes
spellingShingle Dendocarbin A
Drimys winteri extract
isostructural polymorphism
monoclinic polymorphic form crystal structure
natural product
sesquiterpene lactone
Esters
Dendocarbin A
Drimys winteri extract
Isostructural
Natural products
Polymorphic forms
Sesquiterpene lactones
Crystal structure
Drimys winteri
dendocarbin A
lactone
sesquiterpene
chemical structure
chemistry
crystallization
Drimys
isolation and purification
Crystallization
Drimys
Lactones
Molecular Structure
Sesquiterpenes
Paz, C.
Burgos, V.
Suarez, S.
Baggio, R.
A monoclinic form of dendocarbin A: A borderline case of one-dimensional isostructural polymorphism
topic_facet Dendocarbin A
Drimys winteri extract
isostructural polymorphism
monoclinic polymorphic form crystal structure
natural product
sesquiterpene lactone
Esters
Dendocarbin A
Drimys winteri extract
Isostructural
Natural products
Polymorphic forms
Sesquiterpene lactones
Crystal structure
Drimys winteri
dendocarbin A
lactone
sesquiterpene
chemical structure
chemistry
crystallization
Drimys
isolation and purification
Crystallization
Drimys
Lactones
Molecular Structure
Sesquiterpenes
description The title compound, dendocarbin A [systematic name: (1R,5aS,9aS,9bR)-1-hydroxy-6,6,9a-trimethyldodecahydronaphtho[1,2-c]furan-3-one], C15H22O3, is a sesquiterpene lactone isolated from Drimys winteri var chilensis. The monoclinic phase described herein displays an identical molecular structure to the orthorhombic phase that we reported previously [Paz Robles et al. (2014). Acta Cryst. C70, 1007-1010], while varying significantly in chain pitch, and can thus be considered as a borderline case of one-dimensional isostructural polymorphism. © 2015 International Union of Crystallography.
format JOUR
author Paz, C.
Burgos, V.
Suarez, S.
Baggio, R.
author_facet Paz, C.
Burgos, V.
Suarez, S.
Baggio, R.
author_sort Paz, C.
title A monoclinic form of dendocarbin A: A borderline case of one-dimensional isostructural polymorphism
title_short A monoclinic form of dendocarbin A: A borderline case of one-dimensional isostructural polymorphism
title_full A monoclinic form of dendocarbin A: A borderline case of one-dimensional isostructural polymorphism
title_fullStr A monoclinic form of dendocarbin A: A borderline case of one-dimensional isostructural polymorphism
title_full_unstemmed A monoclinic form of dendocarbin A: A borderline case of one-dimensional isostructural polymorphism
title_sort monoclinic form of dendocarbin a: a borderline case of one-dimensional isostructural polymorphism
url http://hdl.handle.net/20.500.12110/paper_20532296_v71_n_p294_Paz
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AT burgosv amonoclinicformofdendocarbinaaborderlinecaseofonedimensionalisostructuralpolymorphism
AT suarezs amonoclinicformofdendocarbinaaborderlinecaseofonedimensionalisostructuralpolymorphism
AT baggior amonoclinicformofdendocarbinaaborderlinecaseofonedimensionalisostructuralpolymorphism
AT pazc monoclinicformofdendocarbinaaborderlinecaseofonedimensionalisostructuralpolymorphism
AT burgosv monoclinicformofdendocarbinaaborderlinecaseofonedimensionalisostructuralpolymorphism
AT suarezs monoclinicformofdendocarbinaaborderlinecaseofonedimensionalisostructuralpolymorphism
AT baggior monoclinicformofdendocarbinaaborderlinecaseofonedimensionalisostructuralpolymorphism
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