Controlled deposition of silver nanoparticles in mesoporous single- Or multilayer thin films: From tuned pore filling to selective spatial location of nanometric objects
Silver nanoparticle assemblies are embedded within mesoporous oxide thin films by an in situ mild reduction leading to nanoparticle-mesoporous oxide thin-film composites (NP@MOTF). A quantitative method based on X-ray reflectivity is developed and validated with energy dispersive spectroscopy in ord...
Guardado en:
| Autores principales: | , , , , |
|---|---|
| Formato: | JOUR |
| Materias: | |
| Acceso en línea: | http://hdl.handle.net/20.500.12110/paper_16136810_v5_n2_p272_Fuertes |
| Aporte de: |
| id |
todo:paper_16136810_v5_n2_p272_Fuertes |
|---|---|
| record_format |
dspace |
| spelling |
todo:paper_16136810_v5_n2_p272_Fuertes2023-10-03T16:28:09Z Controlled deposition of silver nanoparticles in mesoporous single- Or multilayer thin films: From tuned pore filling to selective spatial location of nanometric objects Fuertes, M.C. Marchena, M. Marchi, M.C. Wolosiuk, A. Soler-Illia, G.J.A.A. Electroless deposition Mesoporous materials Multilayers Nanostructures Silver nanoparticles Carbon fiber reinforced plastics Film preparation Mesoporous materials Metallic compounds Multilayer films Multilayers Nanoparticles Nanostructures Optical instruments Oxide films Raman scattering Silica Thin films Titanium dioxide Titanium oxides Complex 1 Controlled depositions Drastic conditions Electroless deposition Energy dispersive Formaldehyde solutions In-situ Mesoporous oxides Mesoporous silicas Mesoporous titania Metal oxides Multi-layer thin films Multi-layered Nanometric Pore fillings Potential applications Quantitative methods Silver nanoparticles Spatial locations Thin-film X-ray reflectivities Silver metal metal nanoparticle nanoparticle oxide silicon dioxide silver titanium titanium dioxide article chemistry methodology nanotechnology optics Raman spectrometry spectrofluorometry surface property transmission electron microscopy X ray Metal Nanoparticles Metals Microscopy, Electron, Transmission Nanoparticles Nanotechnology Optics and Photonics Oxides Silicon Dioxide Silver Spectrometry, Fluorescence Spectrum Analysis, Raman Surface Properties Titanium X-Rays Silver nanoparticle assemblies are embedded within mesoporous oxide thin films by an in situ mild reduction leading to nanoparticle-mesoporous oxide thin-film composites (NP@MOTF). A quantitative method based on X-ray reflectivity is developed and validated with energy dispersive spectroscopy in order to assess pore filling. The use of dilute formaldehyde solutions leads to control over the formation of silver nanoparticles within mesoporous titania films. Inclusion of silver nanoparticles in mesoporous silica requires more drastic conditions. This difference in reactivity can be exploited to selectively synthesize nanoparticles in a predetermined layer of a multilayered mesoporous stack leading to complex 1D-ordered multilayers with precise spatial location of nanometric objects. The metal oxide nanocomposites synthesized have potential applications in catalysis, optical devices, surface-enhanced Raman scattering, and metal enhancement fluorescence. © 2009 Wiley-VCH Verlag GmbH & Co. KGaA. Fil:Marchi, M.C. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. Fil:Soler-Illia, G.J.A.A. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. JOUR info:eu-repo/semantics/openAccess http://creativecommons.org/licenses/by/2.5/ar http://hdl.handle.net/20.500.12110/paper_16136810_v5_n2_p272_Fuertes |
| institution |
Universidad de Buenos Aires |
| institution_str |
I-28 |
| repository_str |
R-134 |
| collection |
Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA) |
| topic |
Electroless deposition Mesoporous materials Multilayers Nanostructures Silver nanoparticles Carbon fiber reinforced plastics Film preparation Mesoporous materials Metallic compounds Multilayer films Multilayers Nanoparticles Nanostructures Optical instruments Oxide films Raman scattering Silica Thin films Titanium dioxide Titanium oxides Complex 1 Controlled depositions Drastic conditions Electroless deposition Energy dispersive Formaldehyde solutions In-situ Mesoporous oxides Mesoporous silicas Mesoporous titania Metal oxides Multi-layer thin films Multi-layered Nanometric Pore fillings Potential applications Quantitative methods Silver nanoparticles Spatial locations Thin-film X-ray reflectivities Silver metal metal nanoparticle nanoparticle oxide silicon dioxide silver titanium titanium dioxide article chemistry methodology nanotechnology optics Raman spectrometry spectrofluorometry surface property transmission electron microscopy X ray Metal Nanoparticles Metals Microscopy, Electron, Transmission Nanoparticles Nanotechnology Optics and Photonics Oxides Silicon Dioxide Silver Spectrometry, Fluorescence Spectrum Analysis, Raman Surface Properties Titanium X-Rays |
| spellingShingle |
Electroless deposition Mesoporous materials Multilayers Nanostructures Silver nanoparticles Carbon fiber reinforced plastics Film preparation Mesoporous materials Metallic compounds Multilayer films Multilayers Nanoparticles Nanostructures Optical instruments Oxide films Raman scattering Silica Thin films Titanium dioxide Titanium oxides Complex 1 Controlled depositions Drastic conditions Electroless deposition Energy dispersive Formaldehyde solutions In-situ Mesoporous oxides Mesoporous silicas Mesoporous titania Metal oxides Multi-layer thin films Multi-layered Nanometric Pore fillings Potential applications Quantitative methods Silver nanoparticles Spatial locations Thin-film X-ray reflectivities Silver metal metal nanoparticle nanoparticle oxide silicon dioxide silver titanium titanium dioxide article chemistry methodology nanotechnology optics Raman spectrometry spectrofluorometry surface property transmission electron microscopy X ray Metal Nanoparticles Metals Microscopy, Electron, Transmission Nanoparticles Nanotechnology Optics and Photonics Oxides Silicon Dioxide Silver Spectrometry, Fluorescence Spectrum Analysis, Raman Surface Properties Titanium X-Rays Fuertes, M.C. Marchena, M. Marchi, M.C. Wolosiuk, A. Soler-Illia, G.J.A.A. Controlled deposition of silver nanoparticles in mesoporous single- Or multilayer thin films: From tuned pore filling to selective spatial location of nanometric objects |
| topic_facet |
Electroless deposition Mesoporous materials Multilayers Nanostructures Silver nanoparticles Carbon fiber reinforced plastics Film preparation Mesoporous materials Metallic compounds Multilayer films Multilayers Nanoparticles Nanostructures Optical instruments Oxide films Raman scattering Silica Thin films Titanium dioxide Titanium oxides Complex 1 Controlled depositions Drastic conditions Electroless deposition Energy dispersive Formaldehyde solutions In-situ Mesoporous oxides Mesoporous silicas Mesoporous titania Metal oxides Multi-layer thin films Multi-layered Nanometric Pore fillings Potential applications Quantitative methods Silver nanoparticles Spatial locations Thin-film X-ray reflectivities Silver metal metal nanoparticle nanoparticle oxide silicon dioxide silver titanium titanium dioxide article chemistry methodology nanotechnology optics Raman spectrometry spectrofluorometry surface property transmission electron microscopy X ray Metal Nanoparticles Metals Microscopy, Electron, Transmission Nanoparticles Nanotechnology Optics and Photonics Oxides Silicon Dioxide Silver Spectrometry, Fluorescence Spectrum Analysis, Raman Surface Properties Titanium X-Rays |
| description |
Silver nanoparticle assemblies are embedded within mesoporous oxide thin films by an in situ mild reduction leading to nanoparticle-mesoporous oxide thin-film composites (NP@MOTF). A quantitative method based on X-ray reflectivity is developed and validated with energy dispersive spectroscopy in order to assess pore filling. The use of dilute formaldehyde solutions leads to control over the formation of silver nanoparticles within mesoporous titania films. Inclusion of silver nanoparticles in mesoporous silica requires more drastic conditions. This difference in reactivity can be exploited to selectively synthesize nanoparticles in a predetermined layer of a multilayered mesoporous stack leading to complex 1D-ordered multilayers with precise spatial location of nanometric objects. The metal oxide nanocomposites synthesized have potential applications in catalysis, optical devices, surface-enhanced Raman scattering, and metal enhancement fluorescence. © 2009 Wiley-VCH Verlag GmbH & Co. KGaA. |
| format |
JOUR |
| author |
Fuertes, M.C. Marchena, M. Marchi, M.C. Wolosiuk, A. Soler-Illia, G.J.A.A. |
| author_facet |
Fuertes, M.C. Marchena, M. Marchi, M.C. Wolosiuk, A. Soler-Illia, G.J.A.A. |
| author_sort |
Fuertes, M.C. |
| title |
Controlled deposition of silver nanoparticles in mesoporous single- Or multilayer thin films: From tuned pore filling to selective spatial location of nanometric objects |
| title_short |
Controlled deposition of silver nanoparticles in mesoporous single- Or multilayer thin films: From tuned pore filling to selective spatial location of nanometric objects |
| title_full |
Controlled deposition of silver nanoparticles in mesoporous single- Or multilayer thin films: From tuned pore filling to selective spatial location of nanometric objects |
| title_fullStr |
Controlled deposition of silver nanoparticles in mesoporous single- Or multilayer thin films: From tuned pore filling to selective spatial location of nanometric objects |
| title_full_unstemmed |
Controlled deposition of silver nanoparticles in mesoporous single- Or multilayer thin films: From tuned pore filling to selective spatial location of nanometric objects |
| title_sort |
controlled deposition of silver nanoparticles in mesoporous single- or multilayer thin films: from tuned pore filling to selective spatial location of nanometric objects |
| url |
http://hdl.handle.net/20.500.12110/paper_16136810_v5_n2_p272_Fuertes |
| work_keys_str_mv |
AT fuertesmc controlleddepositionofsilvernanoparticlesinmesoporoussingleormultilayerthinfilmsfromtunedporefillingtoselectivespatiallocationofnanometricobjects AT marchenam controlleddepositionofsilvernanoparticlesinmesoporoussingleormultilayerthinfilmsfromtunedporefillingtoselectivespatiallocationofnanometricobjects AT marchimc controlleddepositionofsilvernanoparticlesinmesoporoussingleormultilayerthinfilmsfromtunedporefillingtoselectivespatiallocationofnanometricobjects AT wolosiuka controlleddepositionofsilvernanoparticlesinmesoporoussingleormultilayerthinfilmsfromtunedporefillingtoselectivespatiallocationofnanometricobjects AT solerilliagjaa controlleddepositionofsilvernanoparticlesinmesoporoussingleormultilayerthinfilmsfromtunedporefillingtoselectivespatiallocationofnanometricobjects |
| _version_ |
1807323373414383616 |