Electrochemical copolymerization of aniline and ortho-aminobenzylamine. Studies on its conductivity and chemical derivatization

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The electrochemical copolymerization of aniline and o-aminobenzylamine (ABA) leads to a polymer with aliphatic amino groups able to be derivatized. The synthesized material has a stoichiometry ABA:aniline ca. 1:1 when their ratio in the precursor solution range between 90:10 and 75:25. It presents s...

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Detalles Bibliográficos
Autores principales:	Raffa, D.L., Leung, K.T., Battaglini, F.
Formato:	JOUR
Materias:	0-Aminobenzylamine Aniline Conductivity Copolymerization Derivatization Polyaniline Derivatives Electric conductance Electrochemistry Reaction kinetics Solutions Stoichiometry Synthesis (chemical) O-aminobenzylamine Amines
Acceso en línea:	http://hdl.handle.net/20.500.12110/paper_15726657_v587_n1_p60_Raffa
Aporte de:	Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA) de Universidad de Buenos Aires

id	todo:paper_15726657_v587_n1_p60_Raffa
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spelling	todo:paper_15726657_v587_n1_p60_Raffa2023-10-03T16:27:28Z Electrochemical copolymerization of aniline and ortho-aminobenzylamine. Studies on its conductivity and chemical derivatization Raffa, D.L. Leung, K.T. Battaglini, F. 0-Aminobenzylamine Aniline Conductivity Copolymerization Derivatization Polyaniline Copolymerization Derivatives Electric conductance Electrochemistry Reaction kinetics Solutions Stoichiometry Synthesis (chemical) Aniline Derivatization O-aminobenzylamine Polyaniline Amines The electrochemical copolymerization of aniline and o-aminobenzylamine (ABA) leads to a polymer with aliphatic amino groups able to be derivatized. The synthesized material has a stoichiometry ABA:aniline ca. 1:1 when their ratio in the precursor solution range between 90:10 and 75:25. It presents similar conducting properties as polyaniline in acid medium. The conductance of the prepared polymer shows significant improvement compared to polyaniline in weak acidic to neutral media. The resulting product is able to be derivatized by mild reactions with molecules bearing a carboxylate or a carbonyl group. We show that approximately 20% of the added functional groups can be easily modified. © 2005 Elsevier B.V. All rights reserved. JOUR info:eu-repo/semantics/openAccess http://creativecommons.org/licenses/by/2.5/ar http://hdl.handle.net/20.500.12110/paper_15726657_v587_n1_p60_Raffa
institution	Universidad de Buenos Aires
institution_str	I-28
repository_str	R-134
collection	Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA)
topic	0-Aminobenzylamine Aniline Conductivity Copolymerization Derivatization Polyaniline Copolymerization Derivatives Electric conductance Electrochemistry Reaction kinetics Solutions Stoichiometry Synthesis (chemical) Aniline Derivatization O-aminobenzylamine Polyaniline Amines
spellingShingle	0-Aminobenzylamine Aniline Conductivity Copolymerization Derivatization Polyaniline Copolymerization Derivatives Electric conductance Electrochemistry Reaction kinetics Solutions Stoichiometry Synthesis (chemical) Aniline Derivatization O-aminobenzylamine Polyaniline Amines Raffa, D.L. Leung, K.T. Battaglini, F. Electrochemical copolymerization of aniline and ortho-aminobenzylamine. Studies on its conductivity and chemical derivatization
topic_facet	0-Aminobenzylamine Aniline Conductivity Copolymerization Derivatization Polyaniline Copolymerization Derivatives Electric conductance Electrochemistry Reaction kinetics Solutions Stoichiometry Synthesis (chemical) Aniline Derivatization O-aminobenzylamine Polyaniline Amines
description	The electrochemical copolymerization of aniline and o-aminobenzylamine (ABA) leads to a polymer with aliphatic amino groups able to be derivatized. The synthesized material has a stoichiometry ABA:aniline ca. 1:1 when their ratio in the precursor solution range between 90:10 and 75:25. It presents similar conducting properties as polyaniline in acid medium. The conductance of the prepared polymer shows significant improvement compared to polyaniline in weak acidic to neutral media. The resulting product is able to be derivatized by mild reactions with molecules bearing a carboxylate or a carbonyl group. We show that approximately 20% of the added functional groups can be easily modified. © 2005 Elsevier B.V. All rights reserved.
format	JOUR
author	Raffa, D.L. Leung, K.T. Battaglini, F.
author_facet	Raffa, D.L. Leung, K.T. Battaglini, F.
author_sort	Raffa, D.L.
title	Electrochemical copolymerization of aniline and ortho-aminobenzylamine. Studies on its conductivity and chemical derivatization
title_short	Electrochemical copolymerization of aniline and ortho-aminobenzylamine. Studies on its conductivity and chemical derivatization
title_full	Electrochemical copolymerization of aniline and ortho-aminobenzylamine. Studies on its conductivity and chemical derivatization
title_fullStr	Electrochemical copolymerization of aniline and ortho-aminobenzylamine. Studies on its conductivity and chemical derivatization
title_full_unstemmed	Electrochemical copolymerization of aniline and ortho-aminobenzylamine. Studies on its conductivity and chemical derivatization
title_sort	electrochemical copolymerization of aniline and ortho-aminobenzylamine. studies on its conductivity and chemical derivatization
url	http://hdl.handle.net/20.500.12110/paper_15726657_v587_n1_p60_Raffa
work_keys_str_mv	AT raffadl electrochemicalcopolymerizationofanilineandorthoaminobenzylaminestudiesonitsconductivityandchemicalderivatization AT leungkt electrochemicalcopolymerizationofanilineandorthoaminobenzylaminestudiesonitsconductivityandchemicalderivatization AT battaglinif electrochemicalcopolymerizationofanilineandorthoaminobenzylaminestudiesonitsconductivityandchemicalderivatization
_version_	1807314851076243456

Electrochemical copolymerization of aniline and ortho-aminobenzylamine. Studies on its conductivity and chemical derivatization

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