The reduction of nickel dimethylglyoxime complex preadsorbed on mercury

The voltammetric reduction of NiII(DMGH)2 complex preadsorbed on mercury both in 1 M NH4Cl + NH3 buffer and in 0.1 M borate buffer solutions was studied. In this work experimental evidence points to NiII(DMGH)2 reduction with simultaneous decomposition of the ligand DMGH- and reduction of Ni(II) to...

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Detalles Bibliográficos
Autores principales:	Ramírez, S., Gordillo, G.J., Posadas, D.
Formato:	JOUR
Materias:	Nickel dimethylglyoxime complex Peak current Voltammetric reduction Adsorption Electrochemical electrodes Mercury (metal) Nickel cadmium batteries Reaction kinetics Reduction Surface phenomena Nickel dimethylglyoxime Nickel compounds
Acceso en línea:	http://hdl.handle.net/20.500.12110/paper_15726657_v431_n2_p171_Ramirez
Aporte de:	Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA) de Universidad de Buenos Aires

id	todo:paper_15726657_v431_n2_p171_Ramirez
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spelling	todo:paper_15726657_v431_n2_p171_Ramirez2023-10-03T16:27:25Z The reduction of nickel dimethylglyoxime complex preadsorbed on mercury Ramírez, S. Gordillo, G.J. Posadas, D. Nickel dimethylglyoxime complex Peak current Voltammetric reduction Adsorption Electrochemical electrodes Mercury (metal) Nickel cadmium batteries Reaction kinetics Reduction Surface phenomena Nickel dimethylglyoxime Voltammetric reduction Nickel compounds The voltammetric reduction of NiII(DMGH)2 complex preadsorbed on mercury both in 1 M NH4Cl + NH3 buffer and in 0.1 M borate buffer solutions was studied. In this work experimental evidence points to NiII(DMGH)2 reduction with simultaneous decomposition of the ligand DMGH- and reduction of Ni(II) to Ni(O). The experimental sweep rate dependence of peak current and potential is explained in terms of a ErCi surface reaction scheme and a rate expression that takes into account attractive forces between the adsorbed reactant complex. © 1997 Elsevier Science S.A. Fil:Ramírez, S. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. Fil:Gordillo, G.J. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. JOUR info:eu-repo/semantics/openAccess http://creativecommons.org/licenses/by/2.5/ar http://hdl.handle.net/20.500.12110/paper_15726657_v431_n2_p171_Ramirez
institution	Universidad de Buenos Aires
institution_str	I-28
repository_str	R-134
collection	Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA)
topic	Nickel dimethylglyoxime complex Peak current Voltammetric reduction Adsorption Electrochemical electrodes Mercury (metal) Nickel cadmium batteries Reaction kinetics Reduction Surface phenomena Nickel dimethylglyoxime Voltammetric reduction Nickel compounds
spellingShingle	Nickel dimethylglyoxime complex Peak current Voltammetric reduction Adsorption Electrochemical electrodes Mercury (metal) Nickel cadmium batteries Reaction kinetics Reduction Surface phenomena Nickel dimethylglyoxime Voltammetric reduction Nickel compounds Ramírez, S. Gordillo, G.J. Posadas, D. The reduction of nickel dimethylglyoxime complex preadsorbed on mercury
topic_facet	Nickel dimethylglyoxime complex Peak current Voltammetric reduction Adsorption Electrochemical electrodes Mercury (metal) Nickel cadmium batteries Reaction kinetics Reduction Surface phenomena Nickel dimethylglyoxime Voltammetric reduction Nickel compounds
description	The voltammetric reduction of NiII(DMGH)2 complex preadsorbed on mercury both in 1 M NH4Cl + NH3 buffer and in 0.1 M borate buffer solutions was studied. In this work experimental evidence points to NiII(DMGH)2 reduction with simultaneous decomposition of the ligand DMGH- and reduction of Ni(II) to Ni(O). The experimental sweep rate dependence of peak current and potential is explained in terms of a ErCi surface reaction scheme and a rate expression that takes into account attractive forces between the adsorbed reactant complex. © 1997 Elsevier Science S.A.
format	JOUR
author	Ramírez, S. Gordillo, G.J. Posadas, D.
author_facet	Ramírez, S. Gordillo, G.J. Posadas, D.
author_sort	Ramírez, S.
title	The reduction of nickel dimethylglyoxime complex preadsorbed on mercury
title_short	The reduction of nickel dimethylglyoxime complex preadsorbed on mercury
title_full	The reduction of nickel dimethylglyoxime complex preadsorbed on mercury
title_fullStr	The reduction of nickel dimethylglyoxime complex preadsorbed on mercury
title_full_unstemmed	The reduction of nickel dimethylglyoxime complex preadsorbed on mercury
title_sort	reduction of nickel dimethylglyoxime complex preadsorbed on mercury
url	http://hdl.handle.net/20.500.12110/paper_15726657_v431_n2_p171_Ramirez
work_keys_str_mv	AT ramirezs thereductionofnickeldimethylglyoximecomplexpreadsorbedonmercury AT gordillogj thereductionofnickeldimethylglyoximecomplexpreadsorbedonmercury AT posadasd thereductionofnickeldimethylglyoximecomplexpreadsorbedonmercury AT ramirezs reductionofnickeldimethylglyoximecomplexpreadsorbedonmercury AT gordillogj reductionofnickeldimethylglyoximecomplexpreadsorbedonmercury AT posadasd reductionofnickeldimethylglyoximecomplexpreadsorbedonmercury
_version_	1807318489480822784

The reduction of nickel dimethylglyoxime complex preadsorbed on mercury

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