Surface modification of muitiwalled carbon nanotubes via esterification using a biodegradable polyol
Multiwalled carbon nanotubes (MWCNT) were surface modified firstly oxidizing them with a H 2SO 4/HNO 3 mixture to obtain more reactive carboxylic groups on their surface and then higher functionality. Secondly the oxidized nanotubes (MWCNT-COOH) were dispersed in tetrahydrofuran (THF) and made react...
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todo:paper_15334880_v9_n10_p6064_DArlas2023-10-03T16:21:33Z Surface modification of muitiwalled carbon nanotubes via esterification using a biodegradable polyol D'Arlas, B.F. Goyanes, S. Rubiolo, G.H. Mondragon, I. Corcuera, M.A. Eceiza, A. Biodegradable polyol Esterification Multiwalled carbon nanotubes AFM Biodegradable polyol Caprolactone Carboxylic group Different solvents Graft polymers Hydroxyl groups Process steps Surface modification Surface-modified Tetrahydrofurans Atomic force microscopy Atomic spectroscopy Carbon nanotubes Esterification Esters Fourier transform infrared spectroscopy Graft copolymers Gravimetric analysis Spectroscopic analysis Ultraviolet spectroscopy Multiwalled carbon nanotubes (MWCN) carbon nanotube furan derivative poly(hexamethylene carbonate co caprolactone)diol poly(hexamethylene carbonate-co-caprolactone)diol polyester tetrahydrofuran article atomic force microscopy chemistry esterification infrared spectroscopy oxidation reduction reaction solubility surface property ultraviolet spectrophotometry Esterification Furans Microscopy, Atomic Force Nanotubes, Carbon Oxidation-Reduction Polyesters Solubility Spectrophotometry, Ultraviolet Spectroscopy, Fourier Transform Infrared Surface Properties Multiwalled carbon nanotubes (MWCNT) were surface modified firstly oxidizing them with a H 2SO 4/HNO 3 mixture to obtain more reactive carboxylic groups on their surface and then higher functionality. Secondly the oxidized nanotubes (MWCNT-COOH) were dispersed in tetrahydrofuran (THF) and made react via esterification with a poly(hexamethylene carbonate-co-caprolactone)diol, a potentially biodegradable polyol with hydroxyl groups at its ends. Modification process steps were characterized using Fourier transform infrared spectroscopy, FT-IR, ultraviolet spectroscopy, UV, solubility in different solvents, thermo-gravimetric analysis, TGA, as well as atomic force microscopy, AFM. Results suggest that surface carboxylic groups are reactive enough to graft polymer chains onto their surface. © 2009 American Scientific Publishers. Fil:Goyanes, S. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. JOUR info:eu-repo/semantics/openAccess http://creativecommons.org/licenses/by/2.5/ar http://hdl.handle.net/20.500.12110/paper_15334880_v9_n10_p6064_DArlas |
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Universidad de Buenos Aires |
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I-28 |
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R-134 |
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Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA) |
| topic |
Biodegradable polyol Esterification Multiwalled carbon nanotubes AFM Biodegradable polyol Caprolactone Carboxylic group Different solvents Graft polymers Hydroxyl groups Process steps Surface modification Surface-modified Tetrahydrofurans Atomic force microscopy Atomic spectroscopy Carbon nanotubes Esterification Esters Fourier transform infrared spectroscopy Graft copolymers Gravimetric analysis Spectroscopic analysis Ultraviolet spectroscopy Multiwalled carbon nanotubes (MWCN) carbon nanotube furan derivative poly(hexamethylene carbonate co caprolactone)diol poly(hexamethylene carbonate-co-caprolactone)diol polyester tetrahydrofuran article atomic force microscopy chemistry esterification infrared spectroscopy oxidation reduction reaction solubility surface property ultraviolet spectrophotometry Esterification Furans Microscopy, Atomic Force Nanotubes, Carbon Oxidation-Reduction Polyesters Solubility Spectrophotometry, Ultraviolet Spectroscopy, Fourier Transform Infrared Surface Properties |
| spellingShingle |
Biodegradable polyol Esterification Multiwalled carbon nanotubes AFM Biodegradable polyol Caprolactone Carboxylic group Different solvents Graft polymers Hydroxyl groups Process steps Surface modification Surface-modified Tetrahydrofurans Atomic force microscopy Atomic spectroscopy Carbon nanotubes Esterification Esters Fourier transform infrared spectroscopy Graft copolymers Gravimetric analysis Spectroscopic analysis Ultraviolet spectroscopy Multiwalled carbon nanotubes (MWCN) carbon nanotube furan derivative poly(hexamethylene carbonate co caprolactone)diol poly(hexamethylene carbonate-co-caprolactone)diol polyester tetrahydrofuran article atomic force microscopy chemistry esterification infrared spectroscopy oxidation reduction reaction solubility surface property ultraviolet spectrophotometry Esterification Furans Microscopy, Atomic Force Nanotubes, Carbon Oxidation-Reduction Polyesters Solubility Spectrophotometry, Ultraviolet Spectroscopy, Fourier Transform Infrared Surface Properties D'Arlas, B.F. Goyanes, S. Rubiolo, G.H. Mondragon, I. Corcuera, M.A. Eceiza, A. Surface modification of muitiwalled carbon nanotubes via esterification using a biodegradable polyol |
| topic_facet |
Biodegradable polyol Esterification Multiwalled carbon nanotubes AFM Biodegradable polyol Caprolactone Carboxylic group Different solvents Graft polymers Hydroxyl groups Process steps Surface modification Surface-modified Tetrahydrofurans Atomic force microscopy Atomic spectroscopy Carbon nanotubes Esterification Esters Fourier transform infrared spectroscopy Graft copolymers Gravimetric analysis Spectroscopic analysis Ultraviolet spectroscopy Multiwalled carbon nanotubes (MWCN) carbon nanotube furan derivative poly(hexamethylene carbonate co caprolactone)diol poly(hexamethylene carbonate-co-caprolactone)diol polyester tetrahydrofuran article atomic force microscopy chemistry esterification infrared spectroscopy oxidation reduction reaction solubility surface property ultraviolet spectrophotometry Esterification Furans Microscopy, Atomic Force Nanotubes, Carbon Oxidation-Reduction Polyesters Solubility Spectrophotometry, Ultraviolet Spectroscopy, Fourier Transform Infrared Surface Properties |
| description |
Multiwalled carbon nanotubes (MWCNT) were surface modified firstly oxidizing them with a H 2SO 4/HNO 3 mixture to obtain more reactive carboxylic groups on their surface and then higher functionality. Secondly the oxidized nanotubes (MWCNT-COOH) were dispersed in tetrahydrofuran (THF) and made react via esterification with a poly(hexamethylene carbonate-co-caprolactone)diol, a potentially biodegradable polyol with hydroxyl groups at its ends. Modification process steps were characterized using Fourier transform infrared spectroscopy, FT-IR, ultraviolet spectroscopy, UV, solubility in different solvents, thermo-gravimetric analysis, TGA, as well as atomic force microscopy, AFM. Results suggest that surface carboxylic groups are reactive enough to graft polymer chains onto their surface. © 2009 American Scientific Publishers. |
| format |
JOUR |
| author |
D'Arlas, B.F. Goyanes, S. Rubiolo, G.H. Mondragon, I. Corcuera, M.A. Eceiza, A. |
| author_facet |
D'Arlas, B.F. Goyanes, S. Rubiolo, G.H. Mondragon, I. Corcuera, M.A. Eceiza, A. |
| author_sort |
D'Arlas, B.F. |
| title |
Surface modification of muitiwalled carbon nanotubes via esterification using a biodegradable polyol |
| title_short |
Surface modification of muitiwalled carbon nanotubes via esterification using a biodegradable polyol |
| title_full |
Surface modification of muitiwalled carbon nanotubes via esterification using a biodegradable polyol |
| title_fullStr |
Surface modification of muitiwalled carbon nanotubes via esterification using a biodegradable polyol |
| title_full_unstemmed |
Surface modification of muitiwalled carbon nanotubes via esterification using a biodegradable polyol |
| title_sort |
surface modification of muitiwalled carbon nanotubes via esterification using a biodegradable polyol |
| url |
http://hdl.handle.net/20.500.12110/paper_15334880_v9_n10_p6064_DArlas |
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