Emissive cyanide-bridged bimetallic compounds as building blocks for polymeric antennae
A series of cyanide-bridged bimetallic compounds of the general formula [Ru(L)(bpy)(μ-NC)(M)]2-/-/2+ (L = tpy, 2,2′-6′, 2′′-terpyridine, or tpm, tris(1-pyrazolyl)methane, bpy = 2,2′-bipyridine, M = RuII(CN)5, Os III(CN)5, OsII(CN)5, Ru II(py)4(CN), py = pyridine) have been synthesized and fully char...
Guardado en:
Autores principales: | , , , , , |
---|---|
Formato: | JOUR |
Materias: | |
Acceso en línea: | http://hdl.handle.net/20.500.12110/paper_14779226_v42_n48_p16723_Cadranel |
Aporte de: |
id |
todo:paper_14779226_v42_n48_p16723_Cadranel |
---|---|
record_format |
dspace |
spelling |
todo:paper_14779226_v42_n48_p16723_Cadranel2023-10-03T16:19:15Z Emissive cyanide-bridged bimetallic compounds as building blocks for polymeric antennae Cadranel, A. Aramburu Trošelj, B.M. Yamazaki, S. Alborés, P. Kleiman, V.D. Baraldo, L.M. Bimetallic compound Bipyridines Building blockes Cyanide-bridged General formulas Intra-molecular electron transfer Photophysical properties Terpyridines Cyanides Methane Osmium Synthesis (chemical) Rubidium compounds A series of cyanide-bridged bimetallic compounds of the general formula [Ru(L)(bpy)(μ-NC)(M)]2-/-/2+ (L = tpy, 2,2′-6′, 2′′-terpyridine, or tpm, tris(1-pyrazolyl)methane, bpy = 2,2′-bipyridine, M = RuII(CN)5, Os III(CN)5, OsII(CN)5, Ru II(py)4(CN), py = pyridine) have been synthesized and fully characterized. Most of them present MLCT emission (λ = 690-730 nm, Φ = 10-3-10-4) and their photophysical properties resemble the ones of the respective mononuclear Ru(L)(bpy) species. The exception is when M is OsIII(CN)5, where an intramolecular electron transfer quenching mechanism is proposed. The conditions that should be met for avoiding the reductive or oxidative quenching of the excited state are also discussed. © 2013 The Royal Society of Chemistry. Fil:Cadranel, A. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. Fil:Alborés, P. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. Fil:Baraldo, L.M. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. JOUR info:eu-repo/semantics/openAccess http://creativecommons.org/licenses/by/2.5/ar http://hdl.handle.net/20.500.12110/paper_14779226_v42_n48_p16723_Cadranel |
institution |
Universidad de Buenos Aires |
institution_str |
I-28 |
repository_str |
R-134 |
collection |
Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA) |
topic |
Bimetallic compound Bipyridines Building blockes Cyanide-bridged General formulas Intra-molecular electron transfer Photophysical properties Terpyridines Cyanides Methane Osmium Synthesis (chemical) Rubidium compounds |
spellingShingle |
Bimetallic compound Bipyridines Building blockes Cyanide-bridged General formulas Intra-molecular electron transfer Photophysical properties Terpyridines Cyanides Methane Osmium Synthesis (chemical) Rubidium compounds Cadranel, A. Aramburu Trošelj, B.M. Yamazaki, S. Alborés, P. Kleiman, V.D. Baraldo, L.M. Emissive cyanide-bridged bimetallic compounds as building blocks for polymeric antennae |
topic_facet |
Bimetallic compound Bipyridines Building blockes Cyanide-bridged General formulas Intra-molecular electron transfer Photophysical properties Terpyridines Cyanides Methane Osmium Synthesis (chemical) Rubidium compounds |
description |
A series of cyanide-bridged bimetallic compounds of the general formula [Ru(L)(bpy)(μ-NC)(M)]2-/-/2+ (L = tpy, 2,2′-6′, 2′′-terpyridine, or tpm, tris(1-pyrazolyl)methane, bpy = 2,2′-bipyridine, M = RuII(CN)5, Os III(CN)5, OsII(CN)5, Ru II(py)4(CN), py = pyridine) have been synthesized and fully characterized. Most of them present MLCT emission (λ = 690-730 nm, Φ = 10-3-10-4) and their photophysical properties resemble the ones of the respective mononuclear Ru(L)(bpy) species. The exception is when M is OsIII(CN)5, where an intramolecular electron transfer quenching mechanism is proposed. The conditions that should be met for avoiding the reductive or oxidative quenching of the excited state are also discussed. © 2013 The Royal Society of Chemistry. |
format |
JOUR |
author |
Cadranel, A. Aramburu Trošelj, B.M. Yamazaki, S. Alborés, P. Kleiman, V.D. Baraldo, L.M. |
author_facet |
Cadranel, A. Aramburu Trošelj, B.M. Yamazaki, S. Alborés, P. Kleiman, V.D. Baraldo, L.M. |
author_sort |
Cadranel, A. |
title |
Emissive cyanide-bridged bimetallic compounds as building blocks for polymeric antennae |
title_short |
Emissive cyanide-bridged bimetallic compounds as building blocks for polymeric antennae |
title_full |
Emissive cyanide-bridged bimetallic compounds as building blocks for polymeric antennae |
title_fullStr |
Emissive cyanide-bridged bimetallic compounds as building blocks for polymeric antennae |
title_full_unstemmed |
Emissive cyanide-bridged bimetallic compounds as building blocks for polymeric antennae |
title_sort |
emissive cyanide-bridged bimetallic compounds as building blocks for polymeric antennae |
url |
http://hdl.handle.net/20.500.12110/paper_14779226_v42_n48_p16723_Cadranel |
work_keys_str_mv |
AT cadranela emissivecyanidebridgedbimetalliccompoundsasbuildingblocksforpolymericantennae AT aramburutroseljbm emissivecyanidebridgedbimetalliccompoundsasbuildingblocksforpolymericantennae AT yamazakis emissivecyanidebridgedbimetalliccompoundsasbuildingblocksforpolymericantennae AT alboresp emissivecyanidebridgedbimetalliccompoundsasbuildingblocksforpolymericantennae AT kleimanvd emissivecyanidebridgedbimetalliccompoundsasbuildingblocksforpolymericantennae AT baraldolm emissivecyanidebridgedbimetalliccompoundsasbuildingblocksforpolymericantennae |
_version_ |
1782024795472265216 |