Kinetic evidence for a methanolysis intermediate in aromatic nucleophilic substitution
The reactions of 2,4- and 2,6-dinitrochlorobenzene and 2,4-dinitroanisole with cyclohexylamine in benzene and in methanol have been examined. Computer analysis of the kinetic data shows the formation and fate of a solvolysis product in the reaction of 2,4-dinitrochlorobenzene in methanol. The result...
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| Acceso en línea: | http://hdl.handle.net/20.500.12110/paper_1472779X_v_n11_p1256_Nudelman |
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todo:paper_1472779X_v_n11_p1256_Nudelman2023-10-03T16:18:00Z Kinetic evidence for a methanolysis intermediate in aromatic nucleophilic substitution Nudelman, N.S. Garrido, D. The reactions of 2,4- and 2,6-dinitrochlorobenzene and 2,4-dinitroanisole with cyclohexylamine in benzene and in methanol have been examined. Computer analysis of the kinetic data shows the formation and fate of a solvolysis product in the reaction of 2,4-dinitrochlorobenzene in methanol. The results prove that an experimental failure to detect a solvolysis product is not evidence for a negligible solvolysis rate. JOUR info:eu-repo/semantics/openAccess http://creativecommons.org/licenses/by/2.5/ar http://hdl.handle.net/20.500.12110/paper_1472779X_v_n11_p1256_Nudelman |
| institution |
Universidad de Buenos Aires |
| institution_str |
I-28 |
| repository_str |
R-134 |
| collection |
Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA) |
| description |
The reactions of 2,4- and 2,6-dinitrochlorobenzene and 2,4-dinitroanisole with cyclohexylamine in benzene and in methanol have been examined. Computer analysis of the kinetic data shows the formation and fate of a solvolysis product in the reaction of 2,4-dinitrochlorobenzene in methanol. The results prove that an experimental failure to detect a solvolysis product is not evidence for a negligible solvolysis rate. |
| format |
JOUR |
| author |
Nudelman, N.S. Garrido, D. |
| spellingShingle |
Nudelman, N.S. Garrido, D. Kinetic evidence for a methanolysis intermediate in aromatic nucleophilic substitution |
| author_facet |
Nudelman, N.S. Garrido, D. |
| author_sort |
Nudelman, N.S. |
| title |
Kinetic evidence for a methanolysis intermediate in aromatic nucleophilic substitution |
| title_short |
Kinetic evidence for a methanolysis intermediate in aromatic nucleophilic substitution |
| title_full |
Kinetic evidence for a methanolysis intermediate in aromatic nucleophilic substitution |
| title_fullStr |
Kinetic evidence for a methanolysis intermediate in aromatic nucleophilic substitution |
| title_full_unstemmed |
Kinetic evidence for a methanolysis intermediate in aromatic nucleophilic substitution |
| title_sort |
kinetic evidence for a methanolysis intermediate in aromatic nucleophilic substitution |
| url |
http://hdl.handle.net/20.500.12110/paper_1472779X_v_n11_p1256_Nudelman |
| work_keys_str_mv |
AT nudelmanns kineticevidenceforamethanolysisintermediateinaromaticnucleophilicsubstitution AT garridod kineticevidenceforamethanolysisintermediateinaromaticnucleophilicsubstitution |
| _version_ |
1782028537758220288 |