ZnII-promoted D-homorearrangement of 17α-hydroxy-3β-methoxyandrost-5-ene-17β-carbaldehyde
The synthesis of 17α-hydroxy-3β-methoxyandrost-5-ene-17β-carbaldehyde and a highly efficient method for its D-homorearrangement is described. The transformation produced by the action of Zn IIafforded 17α-hydroxy-3β-methoxy-D-homoandrost-5-en-17a-one in a fast, stereospecific, and high-yield reactio...
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| Acceso en línea: | http://hdl.handle.net/20.500.12110/paper_14704358_v_n4_p453_Schor |
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todo:paper_14704358_v_n4_p453_Schor2023-10-03T16:17:39Z ZnII-promoted D-homorearrangement of 17α-hydroxy-3β-methoxyandrost-5-ene-17β-carbaldehyde Schor, L. Gros, E.G. Seldes, A.M. The synthesis of 17α-hydroxy-3β-methoxyandrost-5-ene-17β-carbaldehyde and a highly efficient method for its D-homorearrangement is described. The transformation produced by the action of Zn IIafforded 17α-hydroxy-3β-methoxy-D-homoandrost-5-en-17a-one in a fast, stereospecific, and high-yield reaction. © Royal Society of Chemistry. Fil:Schor, L. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. Fil:Gros, E.G. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. Fil:Seldes, A.M. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. JOUR info:eu-repo/semantics/openAccess http://creativecommons.org/licenses/by/2.5/ar http://hdl.handle.net/20.500.12110/paper_14704358_v_n4_p453_Schor |
| institution |
Universidad de Buenos Aires |
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I-28 |
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R-134 |
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Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA) |
| description |
The synthesis of 17α-hydroxy-3β-methoxyandrost-5-ene-17β-carbaldehyde and a highly efficient method for its D-homorearrangement is described. The transformation produced by the action of Zn IIafforded 17α-hydroxy-3β-methoxy-D-homoandrost-5-en-17a-one in a fast, stereospecific, and high-yield reaction. © Royal Society of Chemistry. |
| format |
JOUR |
| author |
Schor, L. Gros, E.G. Seldes, A.M. |
| spellingShingle |
Schor, L. Gros, E.G. Seldes, A.M. ZnII-promoted D-homorearrangement of 17α-hydroxy-3β-methoxyandrost-5-ene-17β-carbaldehyde |
| author_facet |
Schor, L. Gros, E.G. Seldes, A.M. |
| author_sort |
Schor, L. |
| title |
ZnII-promoted D-homorearrangement of 17α-hydroxy-3β-methoxyandrost-5-ene-17β-carbaldehyde |
| title_short |
ZnII-promoted D-homorearrangement of 17α-hydroxy-3β-methoxyandrost-5-ene-17β-carbaldehyde |
| title_full |
ZnII-promoted D-homorearrangement of 17α-hydroxy-3β-methoxyandrost-5-ene-17β-carbaldehyde |
| title_fullStr |
ZnII-promoted D-homorearrangement of 17α-hydroxy-3β-methoxyandrost-5-ene-17β-carbaldehyde |
| title_full_unstemmed |
ZnII-promoted D-homorearrangement of 17α-hydroxy-3β-methoxyandrost-5-ene-17β-carbaldehyde |
| title_sort |
znii-promoted d-homorearrangement of 17α-hydroxy-3β-methoxyandrost-5-ene-17β-carbaldehyde |
| url |
http://hdl.handle.net/20.500.12110/paper_14704358_v_n4_p453_Schor |
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