EPR insensitivity of the metal-nitrosyl spin-bearing moiety in complexes [LnRuII-NO.]k

A survey of 18 paramagnetic species [LnRu(NO)]k, including seven new examples studied by in situ electrolysis, reveals a surprisingly narrow range of EPR parameters despite a wide variety of ligands such as pyridine, polypyridines, imines, amines, nitriles, phosphanes, carbonyl, cyclopentadienides,...

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Detalles Bibliográficos
Autores principales:	Frantz, S., Sarkar, B., Sieger, M., Kaim, W., Roncaroli, F., Olabe, J.A., Záliš, S.
Formato:	JOUR
Materias:	Density functional calculations EPR spectroscopy Nitric oxide Radical complexes Ruthenium amine carbonyl derivative cyanide cyclopentadiene derivative halide hydroxide imine ligand metal nitric oxide nitrile nitrogen organometallic compound oxygen pyridine ruthenium thiocyanate analytic method article calculation complex formation electrolysis electron spin resonance magnetism nitrosylation
Acceso en línea:	http://hdl.handle.net/20.500.12110/paper_14341948_v_n14_p2902_Frantz
Aporte de:	Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA) de Universidad de Buenos Aires

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