Invariance of multipole polarisabilities of nuclear magnetic shielding within the approach of continuous transformation of the origin of the current density
Electric multipole polarisabilities of nuclear magnetic shielding of a molecule in the presence of external fields-a uniform magnetic and a non-uniform electric field-calculated via the approach of continuous transformation of the origin of the current density, are shown to be invariant in a transla...
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| Acceso en línea: | http://hdl.handle.net/20.500.12110/paper_1432881X_v118_n5-6_p863_Lazzeretti |
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todo:paper_1432881X_v118_n5-6_p863_Lazzeretti2023-10-03T16:14:04Z Invariance of multipole polarisabilities of nuclear magnetic shielding within the approach of continuous transformation of the origin of the current density Lazzeretti, P. Ferraro, M.B. Pagola, G.I. Caputo, M.C. Electric quadrupole polarisability of nuclear magnetic shielding Invariance of magnetic shielding multipole polarisabilities in a gauge translation Origin dependence of magnetic shielding multipole polarisabilities Electric multipole polarisabilities of nuclear magnetic shielding of a molecule in the presence of external fields-a uniform magnetic and a non-uniform electric field-calculated via the approach of continuous transformation of the origin of the current density, are shown to be invariant in a translation of the gauge of the vector potential. However, multipole polarisabilities depend upon the origin of the coordinate system for multipole higher than dipole, because of the intrinsic origin dependence of the related operators. © 2007 Springer-Verlag. Fil:Ferraro, M.B. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. Fil:Pagola, G.I. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. Fil:Caputo, M.C. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. JOUR info:eu-repo/semantics/openAccess http://creativecommons.org/licenses/by/2.5/ar http://hdl.handle.net/20.500.12110/paper_1432881X_v118_n5-6_p863_Lazzeretti |
| institution |
Universidad de Buenos Aires |
| institution_str |
I-28 |
| repository_str |
R-134 |
| collection |
Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA) |
| topic |
Electric quadrupole polarisability of nuclear magnetic shielding Invariance of magnetic shielding multipole polarisabilities in a gauge translation Origin dependence of magnetic shielding multipole polarisabilities |
| spellingShingle |
Electric quadrupole polarisability of nuclear magnetic shielding Invariance of magnetic shielding multipole polarisabilities in a gauge translation Origin dependence of magnetic shielding multipole polarisabilities Lazzeretti, P. Ferraro, M.B. Pagola, G.I. Caputo, M.C. Invariance of multipole polarisabilities of nuclear magnetic shielding within the approach of continuous transformation of the origin of the current density |
| topic_facet |
Electric quadrupole polarisability of nuclear magnetic shielding Invariance of magnetic shielding multipole polarisabilities in a gauge translation Origin dependence of magnetic shielding multipole polarisabilities |
| description |
Electric multipole polarisabilities of nuclear magnetic shielding of a molecule in the presence of external fields-a uniform magnetic and a non-uniform electric field-calculated via the approach of continuous transformation of the origin of the current density, are shown to be invariant in a translation of the gauge of the vector potential. However, multipole polarisabilities depend upon the origin of the coordinate system for multipole higher than dipole, because of the intrinsic origin dependence of the related operators. © 2007 Springer-Verlag. |
| format |
JOUR |
| author |
Lazzeretti, P. Ferraro, M.B. Pagola, G.I. Caputo, M.C. |
| author_facet |
Lazzeretti, P. Ferraro, M.B. Pagola, G.I. Caputo, M.C. |
| author_sort |
Lazzeretti, P. |
| title |
Invariance of multipole polarisabilities of nuclear magnetic shielding within the approach of continuous transformation of the origin of the current density |
| title_short |
Invariance of multipole polarisabilities of nuclear magnetic shielding within the approach of continuous transformation of the origin of the current density |
| title_full |
Invariance of multipole polarisabilities of nuclear magnetic shielding within the approach of continuous transformation of the origin of the current density |
| title_fullStr |
Invariance of multipole polarisabilities of nuclear magnetic shielding within the approach of continuous transformation of the origin of the current density |
| title_full_unstemmed |
Invariance of multipole polarisabilities of nuclear magnetic shielding within the approach of continuous transformation of the origin of the current density |
| title_sort |
invariance of multipole polarisabilities of nuclear magnetic shielding within the approach of continuous transformation of the origin of the current density |
| url |
http://hdl.handle.net/20.500.12110/paper_1432881X_v118_n5-6_p863_Lazzeretti |
| work_keys_str_mv |
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| _version_ |
1782027728832167936 |