Enantioselective electrocatalytic hydrogenation of ethyl pyruvate on carbon supported Pd electrodes
The electrocatalytic hydrogenation of ethyl pyruvate to yield S-ethyl lactate over palladium supported on carbon felt electrodes modified with cinchonidine has been found to yield an enantiomeric excess of 13%. The effect of electrode potential, ethyl pyruvate concentration and cinchonidine have bee...
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| Acceso en línea: | http://hdl.handle.net/20.500.12110/paper_13882481_v9_n11_p2725_Vago |
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todo:paper_13882481_v9_n11_p2725_Vago2023-10-03T16:12:40Z Enantioselective electrocatalytic hydrogenation of ethyl pyruvate on carbon supported Pd electrodes Vago, M. Williams, F.J. Calvo, E.J. Chirality Cinchonidine Electrocatalysis Enantioselectivity Ethyl pyruvate Hydrogenation Chirality Electrocatalysis Electrodes Enantioselectivity Hydrogenation Palladium Cinchonidine Ethyl pyruvate Esters The electrocatalytic hydrogenation of ethyl pyruvate to yield S-ethyl lactate over palladium supported on carbon felt electrodes modified with cinchonidine has been found to yield an enantiomeric excess of 13%. The effect of electrode potential, ethyl pyruvate concentration and cinchonidine have been investigated. The experimental results reported in the present study are in good agreement with the previously reported heterogeneous enantioselective hydrogenation using molecular hydrogen at high pressure. The electrocatalytic driven reaction avoids the dissociation of molecular hydrogen and thus the use of high pressure hydrogen. © 2007 Elsevier B.V. All rights reserved. JOUR info:eu-repo/semantics/openAccess http://creativecommons.org/licenses/by/2.5/ar http://hdl.handle.net/20.500.12110/paper_13882481_v9_n11_p2725_Vago |
| institution |
Universidad de Buenos Aires |
| institution_str |
I-28 |
| repository_str |
R-134 |
| collection |
Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA) |
| topic |
Chirality Cinchonidine Electrocatalysis Enantioselectivity Ethyl pyruvate Hydrogenation Chirality Electrocatalysis Electrodes Enantioselectivity Hydrogenation Palladium Cinchonidine Ethyl pyruvate Esters |
| spellingShingle |
Chirality Cinchonidine Electrocatalysis Enantioselectivity Ethyl pyruvate Hydrogenation Chirality Electrocatalysis Electrodes Enantioselectivity Hydrogenation Palladium Cinchonidine Ethyl pyruvate Esters Vago, M. Williams, F.J. Calvo, E.J. Enantioselective electrocatalytic hydrogenation of ethyl pyruvate on carbon supported Pd electrodes |
| topic_facet |
Chirality Cinchonidine Electrocatalysis Enantioselectivity Ethyl pyruvate Hydrogenation Chirality Electrocatalysis Electrodes Enantioselectivity Hydrogenation Palladium Cinchonidine Ethyl pyruvate Esters |
| description |
The electrocatalytic hydrogenation of ethyl pyruvate to yield S-ethyl lactate over palladium supported on carbon felt electrodes modified with cinchonidine has been found to yield an enantiomeric excess of 13%. The effect of electrode potential, ethyl pyruvate concentration and cinchonidine have been investigated. The experimental results reported in the present study are in good agreement with the previously reported heterogeneous enantioselective hydrogenation using molecular hydrogen at high pressure. The electrocatalytic driven reaction avoids the dissociation of molecular hydrogen and thus the use of high pressure hydrogen. © 2007 Elsevier B.V. All rights reserved. |
| format |
JOUR |
| author |
Vago, M. Williams, F.J. Calvo, E.J. |
| author_facet |
Vago, M. Williams, F.J. Calvo, E.J. |
| author_sort |
Vago, M. |
| title |
Enantioselective electrocatalytic hydrogenation of ethyl pyruvate on carbon supported Pd electrodes |
| title_short |
Enantioselective electrocatalytic hydrogenation of ethyl pyruvate on carbon supported Pd electrodes |
| title_full |
Enantioselective electrocatalytic hydrogenation of ethyl pyruvate on carbon supported Pd electrodes |
| title_fullStr |
Enantioselective electrocatalytic hydrogenation of ethyl pyruvate on carbon supported Pd electrodes |
| title_full_unstemmed |
Enantioselective electrocatalytic hydrogenation of ethyl pyruvate on carbon supported Pd electrodes |
| title_sort |
enantioselective electrocatalytic hydrogenation of ethyl pyruvate on carbon supported pd electrodes |
| url |
http://hdl.handle.net/20.500.12110/paper_13882481_v9_n11_p2725_Vago |
| work_keys_str_mv |
AT vagom enantioselectiveelectrocatalytichydrogenationofethylpyruvateoncarbonsupportedpdelectrodes AT williamsfj enantioselectiveelectrocatalytichydrogenationofethylpyruvateoncarbonsupportedpdelectrodes AT calvoej enantioselectiveelectrocatalytichydrogenationofethylpyruvateoncarbonsupportedpdelectrodes |
| _version_ |
1807322356823097344 |