Diffusion coefficients of iodide in high temperature aqueous solutions

The diffusion coefficients of iodide in water solutions containing NaHSO4 as supporting electrolyte have been measured between 102 and 215 °C using a high-temperature wall-tube cell. The temperature behavior of the diffusion coefficients is well described by the Arrhenius law and the activation ener...

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Autores principales:	Trevani, L.N., Calvo, E., Corti, H.R.
Formato:	JOUR
Materias:	Diffusion High temperature Iodide Solvation Wall-tube electrode iodide aqueous solution article calculation conductance diffusion nuclear energy potentiometry solvation temperature
Acceso en línea:	http://hdl.handle.net/20.500.12110/paper_13882481_v2_n5_p312_Trevani
Aporte de:	Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA) de Universidad de Buenos Aires

id	todo:paper_13882481_v2_n5_p312_Trevani
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spelling	todo:paper_13882481_v2_n5_p312_Trevani2023-10-03T16:12:37Z Diffusion coefficients of iodide in high temperature aqueous solutions Trevani, L.N. Calvo, E. Corti, H.R. Diffusion High temperature Iodide Solvation Wall-tube electrode iodide aqueous solution article calculation conductance diffusion nuclear energy potentiometry solvation temperature The diffusion coefficients of iodide in water solutions containing NaHSO4 as supporting electrolyte have been measured between 102 and 215 °C using a high-temperature wall-tube cell. The temperature behavior of the diffusion coefficients is well described by the Arrhenius law and the activation energy for the mass transport is 17 kJ mol-1. The results are compared to those calculated from the iodide conductivity at infinite dilution and to recent results from other authors. The solvation and speciation of the iodide ion in aqueous solutions at high temperature are analyzed. (C) 2000 Elsevier Science S.A. Fil:Trevani, L.N. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. Fil:Calvo, E. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. Fil:Corti, H.R. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. JOUR info:eu-repo/semantics/openAccess http://creativecommons.org/licenses/by/2.5/ar http://hdl.handle.net/20.500.12110/paper_13882481_v2_n5_p312_Trevani
institution	Universidad de Buenos Aires
institution_str	I-28
repository_str	R-134
collection	Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA)
topic	Diffusion High temperature Iodide Solvation Wall-tube electrode iodide aqueous solution article calculation conductance diffusion nuclear energy potentiometry solvation temperature
spellingShingle	Diffusion High temperature Iodide Solvation Wall-tube electrode iodide aqueous solution article calculation conductance diffusion nuclear energy potentiometry solvation temperature Trevani, L.N. Calvo, E. Corti, H.R. Diffusion coefficients of iodide in high temperature aqueous solutions
topic_facet	Diffusion High temperature Iodide Solvation Wall-tube electrode iodide aqueous solution article calculation conductance diffusion nuclear energy potentiometry solvation temperature
description	The diffusion coefficients of iodide in water solutions containing NaHSO4 as supporting electrolyte have been measured between 102 and 215 °C using a high-temperature wall-tube cell. The temperature behavior of the diffusion coefficients is well described by the Arrhenius law and the activation energy for the mass transport is 17 kJ mol-1. The results are compared to those calculated from the iodide conductivity at infinite dilution and to recent results from other authors. The solvation and speciation of the iodide ion in aqueous solutions at high temperature are analyzed. (C) 2000 Elsevier Science S.A.
format	JOUR
author	Trevani, L.N. Calvo, E. Corti, H.R.
author_facet	Trevani, L.N. Calvo, E. Corti, H.R.
author_sort	Trevani, L.N.
title	Diffusion coefficients of iodide in high temperature aqueous solutions
title_short	Diffusion coefficients of iodide in high temperature aqueous solutions
title_full	Diffusion coefficients of iodide in high temperature aqueous solutions
title_fullStr	Diffusion coefficients of iodide in high temperature aqueous solutions
title_full_unstemmed	Diffusion coefficients of iodide in high temperature aqueous solutions
title_sort	diffusion coefficients of iodide in high temperature aqueous solutions
url	http://hdl.handle.net/20.500.12110/paper_13882481_v2_n5_p312_Trevani
work_keys_str_mv	AT trevaniln diffusioncoefficientsofiodideinhightemperatureaqueoussolutions AT calvoe diffusioncoefficientsofiodideinhightemperatureaqueoussolutions AT cortihr diffusioncoefficientsofiodideinhightemperatureaqueoussolutions
_version_	1782030438229868544

Diffusion coefficients of iodide in high temperature aqueous solutions

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