Surfactant presence in a multilayer polyelectrolyte-enzyme system improves its catalytic response

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Self-assembling of poly(allylamine) containing an osmium polypyridil complex (PAOs) alternatively with sodium dodecyl sulfate (SDS) and glucose oxidase (GOx) generates a ternary multilayer system, (PAOs/SDS/PAOs/GOx)n. The introduction of this anionic surfactant allows a sensitive increase of the po...

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Detalles Bibliográficos
Autores principales: Cortez, M.L., Cukierman, A.L., Battaglini, F.
Formato: JOUR
Materias:
Electrocatalysis
Glucose oxidase
Materials
Osmium polypyridil complex
Poly(allylamine)
Redox-active polyelectrolyte
Sodium dodecyl sulfate
Catalytic behaviors
Catalytic response
Enzyme systems
Hydrophobic interactions
Multi-layer systems
Self-assembling
Anionic surfactants
Diffusers (optical)
Enzymes
Glucose
Glucose sensors
Hydrophobicity
Multilayers
Osmium
Polyelectrolytes
Polymers
Sodium
Sodium sulfate
Surface treatment
Acceso en línea:http://hdl.handle.net/20.500.12110/paper_13882481_v11_n5_p990_Cortez
Aporte de:
Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA) de Universidad de Buenos Aires
id todo:paper_13882481_v11_n5_p990_Cortez
record_format dspace
spelling todo:paper_13882481_v11_n5_p990_Cortez2023-10-03T16:12:35Z Surfactant presence in a multilayer polyelectrolyte-enzyme system improves its catalytic response Cortez, M.L. Cukierman, A.L. Battaglini, F. Electrocatalysis Glucose oxidase Materials Osmium polypyridil complex Poly(allylamine) Redox-active polyelectrolyte Sodium dodecyl sulfate Catalytic behaviors Catalytic response Enzyme systems Hydrophobic interactions Multi-layer systems Poly(allylamine) Redox-active polyelectrolyte Self-assembling Sodium dodecyl sulfate Anionic surfactants Diffusers (optical) Electrocatalysis Enzymes Glucose Glucose sensors Hydrophobicity Multilayers Osmium Polyelectrolytes Polymers Sodium Sodium sulfate Surface treatment Glucose oxidase Self-assembling of poly(allylamine) containing an osmium polypyridil complex (PAOs) alternatively with sodium dodecyl sulfate (SDS) and glucose oxidase (GOx) generates a ternary multilayer system, (PAOs/SDS/PAOs/GOx)n. The introduction of this anionic surfactant allows a sensitive increase of the polyelectrolyte and the enzyme uptake at pH 7.0, enhancing its catalytic behavior in presence of glucose more than 5 times, compared to the system (PAOs/GOx)n constructed at the same pH. The balance between ionic and hydrophobic interactions in the construction of this system is discussed. © 2009 Elsevier B.V. All rights reserved. Fil:Cortez, M.L. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. Fil:Cukierman, A.L. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. Fil:Battaglini, F. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. JOUR info:eu-repo/semantics/openAccess http://creativecommons.org/licenses/by/2.5/ar http://hdl.handle.net/20.500.12110/paper_13882481_v11_n5_p990_Cortez
institution Universidad de Buenos Aires
institution_str I-28
repository_str R-134
collection Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA)
topic Electrocatalysis
Glucose oxidase
Materials
Osmium polypyridil complex
Poly(allylamine)
Redox-active polyelectrolyte
Sodium dodecyl sulfate
Catalytic behaviors
Catalytic response
Enzyme systems
Hydrophobic interactions
Multi-layer systems
Poly(allylamine)
Redox-active polyelectrolyte
Self-assembling
Sodium dodecyl sulfate
Anionic surfactants
Diffusers (optical)
Electrocatalysis
Enzymes
Glucose
Glucose sensors
Hydrophobicity
Multilayers
Osmium
Polyelectrolytes
Polymers
Sodium
Sodium sulfate
Surface treatment
Glucose oxidase
spellingShingle Electrocatalysis
Glucose oxidase
Materials
Osmium polypyridil complex
Poly(allylamine)
Redox-active polyelectrolyte
Sodium dodecyl sulfate
Catalytic behaviors
Catalytic response
Enzyme systems
Hydrophobic interactions
Multi-layer systems
Poly(allylamine)
Redox-active polyelectrolyte
Self-assembling
Sodium dodecyl sulfate
Anionic surfactants
Diffusers (optical)
Electrocatalysis
Enzymes
Glucose
Glucose sensors
Hydrophobicity
Multilayers
Osmium
Polyelectrolytes
Polymers
Sodium
Sodium sulfate
Surface treatment
Glucose oxidase
Cortez, M.L.
Cukierman, A.L.
Battaglini, F.
Surfactant presence in a multilayer polyelectrolyte-enzyme system improves its catalytic response
topic_facet Electrocatalysis
Glucose oxidase
Materials
Osmium polypyridil complex
Poly(allylamine)
Redox-active polyelectrolyte
Sodium dodecyl sulfate
Catalytic behaviors
Catalytic response
Enzyme systems
Hydrophobic interactions
Multi-layer systems
Poly(allylamine)
Redox-active polyelectrolyte
Self-assembling
Sodium dodecyl sulfate
Anionic surfactants
Diffusers (optical)
Electrocatalysis
Enzymes
Glucose
Glucose sensors
Hydrophobicity
Multilayers
Osmium
Polyelectrolytes
Polymers
Sodium
Sodium sulfate
Surface treatment
Glucose oxidase
description Self-assembling of poly(allylamine) containing an osmium polypyridil complex (PAOs) alternatively with sodium dodecyl sulfate (SDS) and glucose oxidase (GOx) generates a ternary multilayer system, (PAOs/SDS/PAOs/GOx)n. The introduction of this anionic surfactant allows a sensitive increase of the polyelectrolyte and the enzyme uptake at pH 7.0, enhancing its catalytic behavior in presence of glucose more than 5 times, compared to the system (PAOs/GOx)n constructed at the same pH. The balance between ionic and hydrophobic interactions in the construction of this system is discussed. © 2009 Elsevier B.V. All rights reserved.
format JOUR
author Cortez, M.L.
Cukierman, A.L.
Battaglini, F.
author_facet Cortez, M.L.
Cukierman, A.L.
Battaglini, F.
author_sort Cortez, M.L.
title Surfactant presence in a multilayer polyelectrolyte-enzyme system improves its catalytic response
title_short Surfactant presence in a multilayer polyelectrolyte-enzyme system improves its catalytic response
title_full Surfactant presence in a multilayer polyelectrolyte-enzyme system improves its catalytic response
title_fullStr Surfactant presence in a multilayer polyelectrolyte-enzyme system improves its catalytic response
title_full_unstemmed Surfactant presence in a multilayer polyelectrolyte-enzyme system improves its catalytic response
title_sort surfactant presence in a multilayer polyelectrolyte-enzyme system improves its catalytic response
url http://hdl.handle.net/20.500.12110/paper_13882481_v11_n5_p990_Cortez
work_keys_str_mv AT cortezml surfactantpresenceinamultilayerpolyelectrolyteenzymesystemimprovesitscatalyticresponse
AT cukiermanal surfactantpresenceinamultilayerpolyelectrolyteenzymesystemimprovesitscatalyticresponse
AT battaglinif surfactantpresenceinamultilayerpolyelectrolyteenzymesystemimprovesitscatalyticresponse
_version_ 1807317430486171648

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