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spelling todo:paper_10765174_v54_n2_p195_Petroselli2023-10-03T16:03:28Z MALDI- and LDI-MS saponin fingerprint of leaves and stick components of commercial yerba mate (Ilex paraguariensis) Petroselli, G. Parapugna, T.L. Lagorio, M.G. Erra-Balsells, R. Ilex dumosa Ilex paraguariensis Saint Hilaire LDI-MS MALDI-MS matesaponin fingerprint Desorption Ionization Mass spectrometry Ultraviolet lasers Ilex dumosa Ilex paraguariensis LDI-MS MALDI-MS matesaponin fingerprint Metabolites saponin derivative Article electrospray mass spectrometry fast atom bombardment mass spectrometry Ilex paraguariensis isomer isomerism laser desorption ionization mass spectrometry matrix-assisted laser desorption-ionization mass spectrometry molecular weight nuclear magnetic resonance spectroscopy plant leaf plant stick plant structures plant tissue principal component analysis priority journal ultra performance liquid chromatography ultraviolet radiation Yerba mate (YM) is massively produced and consumed as an infusion in South America and spreading all over the world. This product is obtained from dried leaves of Ilex paraguariensis Saint Hilaire, mixed with fragments of dried branches (sticks). For its commercialization, YM must have a minimum percentage of leaves because its presence determines YM quality and price. Till today, a mechanical methodology to determine the relative amount of components (sticks, leaves, and powder) is used. There is not any modern analytical method that provides information for quick characterization of the YM components. Typical saponin fingerprints for leaves and sticks were found by using ultraviolet matrix-assisted laser desorption ionization and ultraviolet laser desorption ionization mass spectrometry. Then, their possible application as useful tools for quick characterization of components of commercial YM (leaves and sticks) is presented. Furthermore, fingerprints obtained from authentic samples of Ilex paraguariensis and Ilex dumosa are also included and discussed. Each Ilex show typical saponin fingerprints for leaves and sticks. © 2018 John Wiley & Sons, Ltd. JOUR info:eu-repo/semantics/openAccess http://creativecommons.org/licenses/by/2.5/ar http://hdl.handle.net/20.500.12110/paper_10765174_v54_n2_p195_Petroselli
institution Universidad de Buenos Aires
institution_str I-28
repository_str R-134
collection Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA)
topic Ilex dumosa
Ilex paraguariensis Saint Hilaire
LDI-MS
MALDI-MS
matesaponin fingerprint
Desorption
Ionization
Mass spectrometry
Ultraviolet lasers
Ilex dumosa
Ilex paraguariensis
LDI-MS
MALDI-MS
matesaponin fingerprint
Metabolites
saponin derivative
Article
electrospray mass spectrometry
fast atom bombardment mass spectrometry
Ilex paraguariensis
isomer
isomerism
laser desorption ionization mass spectrometry
matrix-assisted laser desorption-ionization mass spectrometry
molecular weight
nuclear magnetic resonance spectroscopy
plant leaf
plant stick
plant structures
plant tissue
principal component analysis
priority journal
ultra performance liquid chromatography
ultraviolet radiation
spellingShingle Ilex dumosa
Ilex paraguariensis Saint Hilaire
LDI-MS
MALDI-MS
matesaponin fingerprint
Desorption
Ionization
Mass spectrometry
Ultraviolet lasers
Ilex dumosa
Ilex paraguariensis
LDI-MS
MALDI-MS
matesaponin fingerprint
Metabolites
saponin derivative
Article
electrospray mass spectrometry
fast atom bombardment mass spectrometry
Ilex paraguariensis
isomer
isomerism
laser desorption ionization mass spectrometry
matrix-assisted laser desorption-ionization mass spectrometry
molecular weight
nuclear magnetic resonance spectroscopy
plant leaf
plant stick
plant structures
plant tissue
principal component analysis
priority journal
ultra performance liquid chromatography
ultraviolet radiation
Petroselli, G.
Parapugna, T.L.
Lagorio, M.G.
Erra-Balsells, R.
MALDI- and LDI-MS saponin fingerprint of leaves and stick components of commercial yerba mate (Ilex paraguariensis)
topic_facet Ilex dumosa
Ilex paraguariensis Saint Hilaire
LDI-MS
MALDI-MS
matesaponin fingerprint
Desorption
Ionization
Mass spectrometry
Ultraviolet lasers
Ilex dumosa
Ilex paraguariensis
LDI-MS
MALDI-MS
matesaponin fingerprint
Metabolites
saponin derivative
Article
electrospray mass spectrometry
fast atom bombardment mass spectrometry
Ilex paraguariensis
isomer
isomerism
laser desorption ionization mass spectrometry
matrix-assisted laser desorption-ionization mass spectrometry
molecular weight
nuclear magnetic resonance spectroscopy
plant leaf
plant stick
plant structures
plant tissue
principal component analysis
priority journal
ultra performance liquid chromatography
ultraviolet radiation
description Yerba mate (YM) is massively produced and consumed as an infusion in South America and spreading all over the world. This product is obtained from dried leaves of Ilex paraguariensis Saint Hilaire, mixed with fragments of dried branches (sticks). For its commercialization, YM must have a minimum percentage of leaves because its presence determines YM quality and price. Till today, a mechanical methodology to determine the relative amount of components (sticks, leaves, and powder) is used. There is not any modern analytical method that provides information for quick characterization of the YM components. Typical saponin fingerprints for leaves and sticks were found by using ultraviolet matrix-assisted laser desorption ionization and ultraviolet laser desorption ionization mass spectrometry. Then, their possible application as useful tools for quick characterization of components of commercial YM (leaves and sticks) is presented. Furthermore, fingerprints obtained from authentic samples of Ilex paraguariensis and Ilex dumosa are also included and discussed. Each Ilex show typical saponin fingerprints for leaves and sticks. © 2018 John Wiley & Sons, Ltd.
format JOUR
author Petroselli, G.
Parapugna, T.L.
Lagorio, M.G.
Erra-Balsells, R.
author_facet Petroselli, G.
Parapugna, T.L.
Lagorio, M.G.
Erra-Balsells, R.
author_sort Petroselli, G.
title MALDI- and LDI-MS saponin fingerprint of leaves and stick components of commercial yerba mate (Ilex paraguariensis)
title_short MALDI- and LDI-MS saponin fingerprint of leaves and stick components of commercial yerba mate (Ilex paraguariensis)
title_full MALDI- and LDI-MS saponin fingerprint of leaves and stick components of commercial yerba mate (Ilex paraguariensis)
title_fullStr MALDI- and LDI-MS saponin fingerprint of leaves and stick components of commercial yerba mate (Ilex paraguariensis)
title_full_unstemmed MALDI- and LDI-MS saponin fingerprint of leaves and stick components of commercial yerba mate (Ilex paraguariensis)
title_sort maldi- and ldi-ms saponin fingerprint of leaves and stick components of commercial yerba mate (ilex paraguariensis)
url http://hdl.handle.net/20.500.12110/paper_10765174_v54_n2_p195_Petroselli
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AT parapugnatl maldiandldimssaponinfingerprintofleavesandstickcomponentsofcommercialyerbamateilexparaguariensis
AT lagoriomg maldiandldimssaponinfingerprintofleavesandstickcomponentsofcommercialyerbamateilexparaguariensis
AT errabalsellsr maldiandldimssaponinfingerprintofleavesandstickcomponentsofcommercialyerbamateilexparaguariensis
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