A kinetic study of ethanol steam reforming using a nickel based catalyst
A kinetic study of ethanol steam reforming to produce hydrogen within the region of kinetic rate control was carried out. A Ni(II)-Al(III) lamellar double hydroxide as catalyst precursor was used. H2, CO, CO2 and CH4 were obtained as products. Using the Langmuir-Hinshelwood (L-H) approach, two kinet...
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| Acceso en línea: | http://hdl.handle.net/20.500.12110/paper_10225528_v51_n1-4_p39_Mas |
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todo:paper_10225528_v51_n1-4_p39_Mas2023-10-03T15:56:47Z A kinetic study of ethanol steam reforming using a nickel based catalyst Mas, V. Bergamini, M.L. Baronetti, G. Amadeo, N. Laborde, M. Ethanol steam reforming Hydrogen Kinetics Langmuir-hinshelwood approach Ni catalyst Catalyst precursors Double hydroxides Ethanol steam reforming Feed ratios General model High temperature High water Kinetic models Kinetic rates Kinetic study Langmuir-Hinshelwood Methane steam reforming Ni catalyst Nickel based catalysts Carbon dioxide Catalysts Enzyme kinetics Ethanol Hydrogen Kinetic theory Kinetics Methane Steam Steam engineering Steam reforming A kinetic study of ethanol steam reforming to produce hydrogen within the region of kinetic rate control was carried out. A Ni(II)-Al(III) lamellar double hydroxide as catalyst precursor was used. H2, CO, CO2 and CH4 were obtained as products. Using the Langmuir-Hinshelwood (L-H) approach, two kinetic models were proposed. The first was a general model including four reactions, two of them corresponding to ethanol steam reforming and the other two to methane steam reforming. When high temperatures and/or high water/ethanol feed ratios were used, the system could be reduced to two irreversible ethanol steam reforming reactions. © Springer Science+Business Media, LLC 2008. JOUR info:eu-repo/semantics/openAccess http://creativecommons.org/licenses/by/2.5/ar http://hdl.handle.net/20.500.12110/paper_10225528_v51_n1-4_p39_Mas |
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Universidad de Buenos Aires |
| institution_str |
I-28 |
| repository_str |
R-134 |
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Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA) |
| topic |
Ethanol steam reforming Hydrogen Kinetics Langmuir-hinshelwood approach Ni catalyst Catalyst precursors Double hydroxides Ethanol steam reforming Feed ratios General model High temperature High water Kinetic models Kinetic rates Kinetic study Langmuir-Hinshelwood Methane steam reforming Ni catalyst Nickel based catalysts Carbon dioxide Catalysts Enzyme kinetics Ethanol Hydrogen Kinetic theory Kinetics Methane Steam Steam engineering Steam reforming |
| spellingShingle |
Ethanol steam reforming Hydrogen Kinetics Langmuir-hinshelwood approach Ni catalyst Catalyst precursors Double hydroxides Ethanol steam reforming Feed ratios General model High temperature High water Kinetic models Kinetic rates Kinetic study Langmuir-Hinshelwood Methane steam reforming Ni catalyst Nickel based catalysts Carbon dioxide Catalysts Enzyme kinetics Ethanol Hydrogen Kinetic theory Kinetics Methane Steam Steam engineering Steam reforming Mas, V. Bergamini, M.L. Baronetti, G. Amadeo, N. Laborde, M. A kinetic study of ethanol steam reforming using a nickel based catalyst |
| topic_facet |
Ethanol steam reforming Hydrogen Kinetics Langmuir-hinshelwood approach Ni catalyst Catalyst precursors Double hydroxides Ethanol steam reforming Feed ratios General model High temperature High water Kinetic models Kinetic rates Kinetic study Langmuir-Hinshelwood Methane steam reforming Ni catalyst Nickel based catalysts Carbon dioxide Catalysts Enzyme kinetics Ethanol Hydrogen Kinetic theory Kinetics Methane Steam Steam engineering Steam reforming |
| description |
A kinetic study of ethanol steam reforming to produce hydrogen within the region of kinetic rate control was carried out. A Ni(II)-Al(III) lamellar double hydroxide as catalyst precursor was used. H2, CO, CO2 and CH4 were obtained as products. Using the Langmuir-Hinshelwood (L-H) approach, two kinetic models were proposed. The first was a general model including four reactions, two of them corresponding to ethanol steam reforming and the other two to methane steam reforming. When high temperatures and/or high water/ethanol feed ratios were used, the system could be reduced to two irreversible ethanol steam reforming reactions. © Springer Science+Business Media, LLC 2008. |
| format |
JOUR |
| author |
Mas, V. Bergamini, M.L. Baronetti, G. Amadeo, N. Laborde, M. |
| author_facet |
Mas, V. Bergamini, M.L. Baronetti, G. Amadeo, N. Laborde, M. |
| author_sort |
Mas, V. |
| title |
A kinetic study of ethanol steam reforming using a nickel based catalyst |
| title_short |
A kinetic study of ethanol steam reforming using a nickel based catalyst |
| title_full |
A kinetic study of ethanol steam reforming using a nickel based catalyst |
| title_fullStr |
A kinetic study of ethanol steam reforming using a nickel based catalyst |
| title_full_unstemmed |
A kinetic study of ethanol steam reforming using a nickel based catalyst |
| title_sort |
kinetic study of ethanol steam reforming using a nickel based catalyst |
| url |
http://hdl.handle.net/20.500.12110/paper_10225528_v51_n1-4_p39_Mas |
| work_keys_str_mv |
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