A racemic and enantiopure unsymmetric diiron(III) complex with a chiral o-carborane-based pyridylalcohol ligand: Combined chiroptical, magnetic, and nonlinear optical properties
The design of molecule-based systems combining magnetic, chiroptical and second-order optical nonlinear properties is still very rare. We report an unusually unsymmetric diiron(III) complex 1, in which three bulky chiral carboranylpyridinealkoxide ligands (oCBhmp-) bridge both metal ions and the com...
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| Acceso en línea: | http://hdl.handle.net/20.500.12110/paper_09476539_v20_n4_p1081_DiSalvo |
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todo:paper_09476539_v20_n4_p1081_DiSalvo2023-10-03T15:49:29Z A racemic and enantiopure unsymmetric diiron(III) complex with a chiral o-carborane-based pyridylalcohol ligand: Combined chiroptical, magnetic, and nonlinear optical properties Di Salvo, F. Tsang, M.Y. Teixidor, F. Viñas, C. Planas, J.G. Crassous, J. Vanthuyne, N. Aliaga-Alcalde, N. Ruiz, E. Coquerel, G. Clevers, S. Dupray, V. Choquesillo-Lazarte, D. Light, M.E. Hursthouse, M.B. boron chirality iron second-harmonic generation spontaneous resolution 2 pyridine(Hydroxymethyl) Coordination complex Multifunctional properties Non-linear optical properties Optical nonlinear Second-harmonic Single-crystal and powder Spontaneous resolution Boron Chirality Iron Ligands Metal ions Optical properties Synthesis (chemical) Vapors X ray diffraction Stereochemistry The design of molecule-based systems combining magnetic, chiroptical and second-order optical nonlinear properties is still very rare. We report an unusually unsymmetric diiron(III) complex 1, in which three bulky chiral carboranylpyridinealkoxide ligands (oCBhmp-) bridge both metal ions and the complex shows the above-mentioned properties. The introduction of o-carborane into the 2-(hydroxymethyl)pyridine (hmpH) architecture significantly alters the coordination of the simple or aryl-substituted 2-hmpH. The unusual architecture observed in 1 seems to be triggered by the poor nucleophilicity of our alkoxide ligand (oCBhmp-). A very rare case of spontaneous resolution takes place on precipitation or exposure to solvent vapor for the bulk compound, as confirmed by a combination of single-crystal and powder X-ray diffraction, second-harmonic generation, and circular dichroism. The corresponding enantiopure complexes (+)1 and (-)1 have also been synthesized and fully characterized. This research provides a new building block with unique geometry and electronics to construct coordination complexes with multifunctional properties. Copyright © 2014 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim. Fil:Di Salvo, F. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. JOUR info:eu-repo/semantics/openAccess http://creativecommons.org/licenses/by/2.5/ar http://hdl.handle.net/20.500.12110/paper_09476539_v20_n4_p1081_DiSalvo |
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Universidad de Buenos Aires |
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I-28 |
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R-134 |
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Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA) |
| topic |
boron chirality iron second-harmonic generation spontaneous resolution 2 pyridine(Hydroxymethyl) Coordination complex Multifunctional properties Non-linear optical properties Optical nonlinear Second-harmonic Single-crystal and powder Spontaneous resolution Boron Chirality Iron Ligands Metal ions Optical properties Synthesis (chemical) Vapors X ray diffraction Stereochemistry |
| spellingShingle |
boron chirality iron second-harmonic generation spontaneous resolution 2 pyridine(Hydroxymethyl) Coordination complex Multifunctional properties Non-linear optical properties Optical nonlinear Second-harmonic Single-crystal and powder Spontaneous resolution Boron Chirality Iron Ligands Metal ions Optical properties Synthesis (chemical) Vapors X ray diffraction Stereochemistry Di Salvo, F. Tsang, M.Y. Teixidor, F. Viñas, C. Planas, J.G. Crassous, J. Vanthuyne, N. Aliaga-Alcalde, N. Ruiz, E. Coquerel, G. Clevers, S. Dupray, V. Choquesillo-Lazarte, D. Light, M.E. Hursthouse, M.B. A racemic and enantiopure unsymmetric diiron(III) complex with a chiral o-carborane-based pyridylalcohol ligand: Combined chiroptical, magnetic, and nonlinear optical properties |
| topic_facet |
boron chirality iron second-harmonic generation spontaneous resolution 2 pyridine(Hydroxymethyl) Coordination complex Multifunctional properties Non-linear optical properties Optical nonlinear Second-harmonic Single-crystal and powder Spontaneous resolution Boron Chirality Iron Ligands Metal ions Optical properties Synthesis (chemical) Vapors X ray diffraction Stereochemistry |
| description |
The design of molecule-based systems combining magnetic, chiroptical and second-order optical nonlinear properties is still very rare. We report an unusually unsymmetric diiron(III) complex 1, in which three bulky chiral carboranylpyridinealkoxide ligands (oCBhmp-) bridge both metal ions and the complex shows the above-mentioned properties. The introduction of o-carborane into the 2-(hydroxymethyl)pyridine (hmpH) architecture significantly alters the coordination of the simple or aryl-substituted 2-hmpH. The unusual architecture observed in 1 seems to be triggered by the poor nucleophilicity of our alkoxide ligand (oCBhmp-). A very rare case of spontaneous resolution takes place on precipitation or exposure to solvent vapor for the bulk compound, as confirmed by a combination of single-crystal and powder X-ray diffraction, second-harmonic generation, and circular dichroism. The corresponding enantiopure complexes (+)1 and (-)1 have also been synthesized and fully characterized. This research provides a new building block with unique geometry and electronics to construct coordination complexes with multifunctional properties. Copyright © 2014 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim. |
| format |
JOUR |
| author |
Di Salvo, F. Tsang, M.Y. Teixidor, F. Viñas, C. Planas, J.G. Crassous, J. Vanthuyne, N. Aliaga-Alcalde, N. Ruiz, E. Coquerel, G. Clevers, S. Dupray, V. Choquesillo-Lazarte, D. Light, M.E. Hursthouse, M.B. |
| author_facet |
Di Salvo, F. Tsang, M.Y. Teixidor, F. Viñas, C. Planas, J.G. Crassous, J. Vanthuyne, N. Aliaga-Alcalde, N. Ruiz, E. Coquerel, G. Clevers, S. Dupray, V. Choquesillo-Lazarte, D. Light, M.E. Hursthouse, M.B. |
| author_sort |
Di Salvo, F. |
| title |
A racemic and enantiopure unsymmetric diiron(III) complex with a chiral o-carborane-based pyridylalcohol ligand: Combined chiroptical, magnetic, and nonlinear optical properties |
| title_short |
A racemic and enantiopure unsymmetric diiron(III) complex with a chiral o-carborane-based pyridylalcohol ligand: Combined chiroptical, magnetic, and nonlinear optical properties |
| title_full |
A racemic and enantiopure unsymmetric diiron(III) complex with a chiral o-carborane-based pyridylalcohol ligand: Combined chiroptical, magnetic, and nonlinear optical properties |
| title_fullStr |
A racemic and enantiopure unsymmetric diiron(III) complex with a chiral o-carborane-based pyridylalcohol ligand: Combined chiroptical, magnetic, and nonlinear optical properties |
| title_full_unstemmed |
A racemic and enantiopure unsymmetric diiron(III) complex with a chiral o-carborane-based pyridylalcohol ligand: Combined chiroptical, magnetic, and nonlinear optical properties |
| title_sort |
racemic and enantiopure unsymmetric diiron(iii) complex with a chiral o-carborane-based pyridylalcohol ligand: combined chiroptical, magnetic, and nonlinear optical properties |
| url |
http://hdl.handle.net/20.500.12110/paper_09476539_v20_n4_p1081_DiSalvo |
| work_keys_str_mv |
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1782029900254806016 |