The aromatic carbon-carbon ipso-substitution reaction
The aim of this review is to illustrate what we have dubbed an aromatic carbon-carbon ipso-substitution reaction in which a new Ar-C bond is formed at the expense of another Ar-C bond. The potentiality of several C-based leaving groups including alkyl, carbinol, CN, COOH, and carbonyl groups in aryl...
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| Acceso en línea: | http://hdl.handle.net/20.500.12110/paper_09476539_v16_n46_p13572_Bonesi |
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todo:paper_09476539_v16_n46_p13572_Bonesi2023-10-03T15:49:25Z The aromatic carbon-carbon ipso-substitution reaction Bonesi, S.M. Fagnoni, M. Ar-C bonds aromatic substitution arylation C-based leaving groups cleavage reactions Ar-C bonds Aromatic substitutions Arylations Cleavage reaction Leaving groups Alkylation Argon Aromatization Carboxylic acids Methanol Substitution reactions Aromatic compounds The aim of this review is to illustrate what we have dubbed an aromatic carbon-carbon ipso-substitution reaction in which a new Ar-C bond is formed at the expense of another Ar-C bond. The potentiality of several C-based leaving groups including alkyl, carbinol, CN, COOH, and carbonyl groups in arylation reactions will be illustrated accordingly for the preparation of biphenyl-, vinyl-, alkynyl-, and alkyl-substituted aromatics. Getting the bond back together: The strategies are unveiled for an aromatic C-C ipso-substitution reaction. This process allows for the one-pot cleavage of Ar-C bonds (e.g., in alkyl and acyl (hetero)aromatics, in benzonitriles, in α,α- disubstituted arylmethanols, and in carboxylic acids) for the formation of a new Ar-C bond (see picture). Copyright © 2010 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim. JOUR info:eu-repo/semantics/openAccess http://creativecommons.org/licenses/by/2.5/ar http://hdl.handle.net/20.500.12110/paper_09476539_v16_n46_p13572_Bonesi |
| institution |
Universidad de Buenos Aires |
| institution_str |
I-28 |
| repository_str |
R-134 |
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Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA) |
| topic |
Ar-C bonds aromatic substitution arylation C-based leaving groups cleavage reactions Ar-C bonds Aromatic substitutions Arylations Cleavage reaction Leaving groups Alkylation Argon Aromatization Carboxylic acids Methanol Substitution reactions Aromatic compounds |
| spellingShingle |
Ar-C bonds aromatic substitution arylation C-based leaving groups cleavage reactions Ar-C bonds Aromatic substitutions Arylations Cleavage reaction Leaving groups Alkylation Argon Aromatization Carboxylic acids Methanol Substitution reactions Aromatic compounds Bonesi, S.M. Fagnoni, M. The aromatic carbon-carbon ipso-substitution reaction |
| topic_facet |
Ar-C bonds aromatic substitution arylation C-based leaving groups cleavage reactions Ar-C bonds Aromatic substitutions Arylations Cleavage reaction Leaving groups Alkylation Argon Aromatization Carboxylic acids Methanol Substitution reactions Aromatic compounds |
| description |
The aim of this review is to illustrate what we have dubbed an aromatic carbon-carbon ipso-substitution reaction in which a new Ar-C bond is formed at the expense of another Ar-C bond. The potentiality of several C-based leaving groups including alkyl, carbinol, CN, COOH, and carbonyl groups in arylation reactions will be illustrated accordingly for the preparation of biphenyl-, vinyl-, alkynyl-, and alkyl-substituted aromatics. Getting the bond back together: The strategies are unveiled for an aromatic C-C ipso-substitution reaction. This process allows for the one-pot cleavage of Ar-C bonds (e.g., in alkyl and acyl (hetero)aromatics, in benzonitriles, in α,α- disubstituted arylmethanols, and in carboxylic acids) for the formation of a new Ar-C bond (see picture). Copyright © 2010 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim. |
| format |
JOUR |
| author |
Bonesi, S.M. Fagnoni, M. |
| author_facet |
Bonesi, S.M. Fagnoni, M. |
| author_sort |
Bonesi, S.M. |
| title |
The aromatic carbon-carbon ipso-substitution reaction |
| title_short |
The aromatic carbon-carbon ipso-substitution reaction |
| title_full |
The aromatic carbon-carbon ipso-substitution reaction |
| title_fullStr |
The aromatic carbon-carbon ipso-substitution reaction |
| title_full_unstemmed |
The aromatic carbon-carbon ipso-substitution reaction |
| title_sort |
aromatic carbon-carbon ipso-substitution reaction |
| url |
http://hdl.handle.net/20.500.12110/paper_09476539_v16_n46_p13572_Bonesi |
| work_keys_str_mv |
AT bonesism thearomaticcarboncarbonipsosubstitutionreaction AT fagnonim thearomaticcarboncarbonipsosubstitutionreaction AT bonesism aromaticcarboncarbonipsosubstitutionreaction AT fagnonim aromaticcarboncarbonipsosubstitutionreaction |
| _version_ |
1807321932421398528 |