Kinetics and Mechanism of the Thermal Reaction between Trifluoromethylhypofluorite and 1,1-Dichlorodifluoroethylene

The thermal addition of CF3OF to CF2CC12 has been studied between -7.0 and 29.7 °C. The pressure of CF3OF was varied between 6.4 and 196.7 Torr and that of CF2CC12 between 5.4 and 203 Torr. CF3CC12F, CF3o(CF2CC12)F and CF3o(CF2CCl2)1oCF3, where i = 2,3 … n, were the products. Above 110 Torr of olefi...

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Autores principales:	Dos Santos Afonso, M., Czarnowski, J.
Formato:	JOUR
Materias:	1,1-Dichlorodifluoroethylene, reaction with trifluoromethylhypofluorite CC12CF2, thermal reaction with CF3OF CF3OF, thermal reaction with CC12CF2 Perfluorobutene-2 Trifluoromethylhypofluorite, addition to 1,1-dichlorodifluoroethylene
Acceso en línea:	http://hdl.handle.net/20.500.12110/paper_09429352_v158_nPart_1_p25_DosSantosAfonso
Aporte de:	Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA) de Universidad de Buenos Aires

id	todo:paper_09429352_v158_nPart_1_p25_DosSantosAfonso
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spelling	todo:paper_09429352_v158_nPart_1_p25_DosSantosAfonso2023-10-03T15:49:01Z Kinetics and Mechanism of the Thermal Reaction between Trifluoromethylhypofluorite and 1,1-Dichlorodifluoroethylene Dos Santos Afonso, M. Czarnowski, J. 1,1-Dichlorodifluoroethylene, reaction with trifluoromethylhypofluorite CC12CF2, thermal reaction with CF3OF CF3OF, thermal reaction with CC12CF2 Perfluorobutene-2 Trifluoromethylhypofluorite, addition to 1,1-dichlorodifluoroethylene The thermal addition of CF3OF to CF2CC12 has been studied between -7.0 and 29.7 °C. The pressure of CF3OF was varied between 6.4 and 196.7 Torr and that of CF2CC12 between 5.4 and 203 Torr. CF3CC12F, CF3o(CF2CC12)F and CF3o(CF2CCl2)1oCF3, where i = 2,3 … n, were the products. Above 110 Torr of olefin, non-volatile condensate appeared. © by R. Oldenbourg Verlag JOUR info:eu-repo/semantics/openAccess http://creativecommons.org/licenses/by/2.5/ar http://hdl.handle.net/20.500.12110/paper_09429352_v158_nPart_1_p25_DosSantosAfonso
institution	Universidad de Buenos Aires
institution_str	I-28
repository_str	R-134
collection	Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA)
topic	1,1-Dichlorodifluoroethylene, reaction with trifluoromethylhypofluorite CC12CF2, thermal reaction with CF3OF CF3OF, thermal reaction with CC12CF2 Perfluorobutene-2 Trifluoromethylhypofluorite, addition to 1,1-dichlorodifluoroethylene
spellingShingle	1,1-Dichlorodifluoroethylene, reaction with trifluoromethylhypofluorite CC12CF2, thermal reaction with CF3OF CF3OF, thermal reaction with CC12CF2 Perfluorobutene-2 Trifluoromethylhypofluorite, addition to 1,1-dichlorodifluoroethylene Dos Santos Afonso, M. Czarnowski, J. Kinetics and Mechanism of the Thermal Reaction between Trifluoromethylhypofluorite and 1,1-Dichlorodifluoroethylene
topic_facet	1,1-Dichlorodifluoroethylene, reaction with trifluoromethylhypofluorite CC12CF2, thermal reaction with CF3OF CF3OF, thermal reaction with CC12CF2 Perfluorobutene-2 Trifluoromethylhypofluorite, addition to 1,1-dichlorodifluoroethylene
description	The thermal addition of CF3OF to CF2CC12 has been studied between -7.0 and 29.7 °C. The pressure of CF3OF was varied between 6.4 and 196.7 Torr and that of CF2CC12 between 5.4 and 203 Torr. CF3CC12F, CF3o(CF2CC12)F and CF3o(CF2CCl2)1oCF3, where i = 2,3 … n, were the products. Above 110 Torr of olefin, non-volatile condensate appeared. © by R. Oldenbourg Verlag
format	JOUR
author	Dos Santos Afonso, M. Czarnowski, J.
author_facet	Dos Santos Afonso, M. Czarnowski, J.
author_sort	Dos Santos Afonso, M.
title	Kinetics and Mechanism of the Thermal Reaction between Trifluoromethylhypofluorite and 1,1-Dichlorodifluoroethylene
title_short	Kinetics and Mechanism of the Thermal Reaction between Trifluoromethylhypofluorite and 1,1-Dichlorodifluoroethylene
title_full	Kinetics and Mechanism of the Thermal Reaction between Trifluoromethylhypofluorite and 1,1-Dichlorodifluoroethylene
title_fullStr	Kinetics and Mechanism of the Thermal Reaction between Trifluoromethylhypofluorite and 1,1-Dichlorodifluoroethylene
title_full_unstemmed	Kinetics and Mechanism of the Thermal Reaction between Trifluoromethylhypofluorite and 1,1-Dichlorodifluoroethylene
title_sort	kinetics and mechanism of the thermal reaction between trifluoromethylhypofluorite and 1,1-dichlorodifluoroethylene
url	http://hdl.handle.net/20.500.12110/paper_09429352_v158_nPart_1_p25_DosSantosAfonso
work_keys_str_mv	AT dossantosafonsom kineticsandmechanismofthethermalreactionbetweentrifluoromethylhypofluoriteand11dichlorodifluoroethylene AT czarnowskij kineticsandmechanismofthethermalreactionbetweentrifluoromethylhypofluoriteand11dichlorodifluoroethylene
_version_	1807318057940418560

Kinetics and Mechanism of the Thermal Reaction between Trifluoromethylhypofluorite and 1,1-Dichlorodifluoroethylene

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