Improving bone cement toughness and contrast agent confinement by using acrylic branched polymers

A new biomedical material to be used as part of acrylic bone cement formulations is described. This new material is tough, its Young's Modulus is similar to the one of poly (methylmethacrylate) and the contrast agent, usually employed in acrylic bone cements, is homogeneously distributed among...

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Autores principales: Lissarrague, M.H., Fascio, M.L., Goyanes, S., D'Accorso, N.B.
Formato: JOUR
Materias:
Barium sulphate nanoparticles
Branched polymer
Natural rubber
Poly(methyl methacrylate)
Polyisoprene
Acrylic monomers
Barium
Biomedical engineering
Bone
Elastic moduli
Esters
Fourier transform infrared spectroscopy
Grafting (chemical)
Nanoparticles
Nuclear magnetic resonance spectroscopy
Polyisoprenes
Rubber
Sulfur compounds
Thermogravimetric analysis
Acrylic bone cements
Barium sulphates
Biomedical material
Branched Polymer
Grafting reactions
Methyl methacrylates
Microscopy technique
Polymeric matrices
Bone cement
biomaterial
bone cement
contrast medium
poly(methyl methacrylate)
rubber
chemistry
materials testing
Young modulus
Biocompatible Materials
Bone Cements
Contrast Media
Elastic Modulus
Materials Testing
Polymethyl Methacrylate
Acceso en línea:http://hdl.handle.net/20.500.12110/paper_09284931_v59_n_p901_Lissarrague
Aporte de:
Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA) de Universidad de Buenos Aires
id todo:paper_09284931_v59_n_p901_Lissarrague
record_format dspace
spelling todo:paper_09284931_v59_n_p901_Lissarrague2023-10-03T15:47:28Z Improving bone cement toughness and contrast agent confinement by using acrylic branched polymers Lissarrague, M.H. Fascio, M.L. Goyanes, S. D'Accorso, N.B. Barium sulphate nanoparticles Branched polymer Natural rubber Poly(methyl methacrylate) Polyisoprene Acrylic monomers Barium Biomedical engineering Bone Elastic moduli Esters Fourier transform infrared spectroscopy Grafting (chemical) Nanoparticles Nuclear magnetic resonance spectroscopy Polyisoprenes Rubber Sulfur compounds Thermogravimetric analysis Acrylic bone cements Barium sulphates Biomedical material Branched Polymer Grafting reactions Methyl methacrylates Microscopy technique Polymeric matrices Bone cement biomaterial bone cement contrast medium poly(methyl methacrylate) rubber chemistry materials testing Young modulus Biocompatible Materials Bone Cements Contrast Media Elastic Modulus Materials Testing Polymethyl Methacrylate Rubber A new biomedical material to be used as part of acrylic bone cement formulations is described. This new material is tough, its Young's Modulus is similar to the one of poly (methylmethacrylate) and the contrast agent, usually employed in acrylic bone cements, is homogeneously distributed among the polymeric matrix. Additionally, its wear coefficient is 66% lower than the one measured in poly(methyl methacrylate). The developed material is a branched polymer with polyisoprene backbone and poly(methyl methacrylate) side chains, which are capable of retaining barium sulphate nanoparticles thus avoiding their aggregation. The grafting reaction was carried out in presence of the nanoparticles, using methyl methacrylate as solvent. From the 1H-NMR spectra it was possible to determine the average number of MMA units per unit of isoprene (3.75:1). The ability to retain nanoparticles (about 8 wt.%), attributed to their interaction with the polymer branches, was determined by thermogravimetric analysis and confirmed by FTIR and microscopy techniques. By SEM microscopy it was also possible to determine the homogeneous spatial distribution of the barium sulphate nanoparticles along the polymer matrix. © 2015 Elsevier B.V. All rights reserved. Fil:Fascio, M.L. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. Fil:Goyanes, S. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. Fil:D'Accorso, N.B. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. JOUR info:eu-repo/semantics/openAccess http://creativecommons.org/licenses/by/2.5/ar http://hdl.handle.net/20.500.12110/paper_09284931_v59_n_p901_Lissarrague
institution Universidad de Buenos Aires
institution_str I-28
repository_str R-134
collection Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA)
topic Barium sulphate nanoparticles
Branched polymer
Natural rubber
Poly(methyl methacrylate)
Polyisoprene
Acrylic monomers
Barium
Biomedical engineering
Bone
Elastic moduli
Esters
Fourier transform infrared spectroscopy
Grafting (chemical)
Nanoparticles
Nuclear magnetic resonance spectroscopy
Polyisoprenes
Rubber
Sulfur compounds
Thermogravimetric analysis
Acrylic bone cements
Barium sulphates
Biomedical material
Branched Polymer
Grafting reactions
Methyl methacrylates
Microscopy technique
Polymeric matrices
Bone cement
biomaterial
bone cement
contrast medium
poly(methyl methacrylate)
rubber
chemistry
materials testing
Young modulus
Biocompatible Materials
Bone Cements
Contrast Media
Elastic Modulus
Materials Testing
Polymethyl Methacrylate
Rubber
spellingShingle Barium sulphate nanoparticles
Branched polymer
Natural rubber
Poly(methyl methacrylate)
Polyisoprene
Acrylic monomers
Barium
Biomedical engineering
Bone
Elastic moduli
Esters
Fourier transform infrared spectroscopy
Grafting (chemical)
Nanoparticles
Nuclear magnetic resonance spectroscopy
Polyisoprenes
Rubber
Sulfur compounds
Thermogravimetric analysis
Acrylic bone cements
Barium sulphates
Biomedical material
Branched Polymer
Grafting reactions
Methyl methacrylates
Microscopy technique
Polymeric matrices
Bone cement
biomaterial
bone cement
contrast medium
poly(methyl methacrylate)
rubber
chemistry
materials testing
Young modulus
Biocompatible Materials
Bone Cements
Contrast Media
Elastic Modulus
Materials Testing
Polymethyl Methacrylate
Rubber
Lissarrague, M.H.
Fascio, M.L.
Goyanes, S.
D'Accorso, N.B.
Improving bone cement toughness and contrast agent confinement by using acrylic branched polymers
topic_facet Barium sulphate nanoparticles
Branched polymer
Natural rubber
Poly(methyl methacrylate)
Polyisoprene
Acrylic monomers
Barium
Biomedical engineering
Bone
Elastic moduli
Esters
Fourier transform infrared spectroscopy
Grafting (chemical)
Nanoparticles
Nuclear magnetic resonance spectroscopy
Polyisoprenes
Rubber
Sulfur compounds
Thermogravimetric analysis
Acrylic bone cements
Barium sulphates
Biomedical material
Branched Polymer
Grafting reactions
Methyl methacrylates
Microscopy technique
Polymeric matrices
Bone cement
biomaterial
bone cement
contrast medium
poly(methyl methacrylate)
rubber
chemistry
materials testing
Young modulus
Biocompatible Materials
Bone Cements
Contrast Media
Elastic Modulus
Materials Testing
Polymethyl Methacrylate
Rubber
description A new biomedical material to be used as part of acrylic bone cement formulations is described. This new material is tough, its Young's Modulus is similar to the one of poly (methylmethacrylate) and the contrast agent, usually employed in acrylic bone cements, is homogeneously distributed among the polymeric matrix. Additionally, its wear coefficient is 66% lower than the one measured in poly(methyl methacrylate). The developed material is a branched polymer with polyisoprene backbone and poly(methyl methacrylate) side chains, which are capable of retaining barium sulphate nanoparticles thus avoiding their aggregation. The grafting reaction was carried out in presence of the nanoparticles, using methyl methacrylate as solvent. From the 1H-NMR spectra it was possible to determine the average number of MMA units per unit of isoprene (3.75:1). The ability to retain nanoparticles (about 8 wt.%), attributed to their interaction with the polymer branches, was determined by thermogravimetric analysis and confirmed by FTIR and microscopy techniques. By SEM microscopy it was also possible to determine the homogeneous spatial distribution of the barium sulphate nanoparticles along the polymer matrix. © 2015 Elsevier B.V. All rights reserved.
format JOUR
author Lissarrague, M.H.
Fascio, M.L.
Goyanes, S.
D'Accorso, N.B.
author_facet Lissarrague, M.H.
Fascio, M.L.
Goyanes, S.
D'Accorso, N.B.
author_sort Lissarrague, M.H.
title Improving bone cement toughness and contrast agent confinement by using acrylic branched polymers
title_short Improving bone cement toughness and contrast agent confinement by using acrylic branched polymers
title_full Improving bone cement toughness and contrast agent confinement by using acrylic branched polymers
title_fullStr Improving bone cement toughness and contrast agent confinement by using acrylic branched polymers
title_full_unstemmed Improving bone cement toughness and contrast agent confinement by using acrylic branched polymers
title_sort improving bone cement toughness and contrast agent confinement by using acrylic branched polymers
url http://hdl.handle.net/20.500.12110/paper_09284931_v59_n_p901_Lissarrague
work_keys_str_mv AT lissarraguemh improvingbonecementtoughnessandcontrastagentconfinementbyusingacrylicbranchedpolymers
AT fascioml improvingbonecementtoughnessandcontrastagentconfinementbyusingacrylicbranchedpolymers
AT goyaness improvingbonecementtoughnessandcontrastagentconfinementbyusingacrylicbranchedpolymers
AT daccorsonb improvingbonecementtoughnessandcontrastagentconfinementbyusingacrylicbranchedpolymers
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