Mesoporous microspheres of nickel-based layered hydroxides by aerosol-assisted self-assembly using crystalline nano-building blocks
Structural control in micro- and nanometer scales is necessary to design highly functional materials. Crystalline mesoporous microspheres (MMSs) are expected to improve electrochemical, catalytic, and adsorption performances. In this study, we focused on the preparation of templated MMSs of nickel-b...
| Autores principales: | , , , , |
|---|---|
| Formato: | JOUR |
| Materias: | |
| Acceso en línea: | http://hdl.handle.net/20.500.12110/paper_09280707_v89_n1_p216_Tarutani |
| Aporte de: |
| id |
todo:paper_09280707_v89_n1_p216_Tarutani |
|---|---|
| record_format |
dspace |
| spelling |
todo:paper_09280707_v89_n1_p216_Tarutani2023-10-03T15:47:19Z Mesoporous microspheres of nickel-based layered hydroxides by aerosol-assisted self-assembly using crystalline nano-building blocks Tarutani, N. Tokudome, Y. Jobbágy, M. Soler-Illia, G.J.A.A. Takahashi, M. Crystalline mesoporous microspheres Epoxide-mediated alkalinization Layered double hydroxides Layered nickel hydroxides Nano-building blocks Aerosols Association reactions Crystalline materials Film preparation Functional materials Mesoporous materials Microspheres Self assembly Structural dynamics Crystalline mesoporous Epoxide-mediated alkalinization Layered double hydroxides Nanobuilding blocks Nickel hydroxides Nickel compounds Structural control in micro- and nanometer scales is necessary to design highly functional materials. Crystalline mesoporous microspheres (MMSs) are expected to improve electrochemical, catalytic, and adsorption performances. In this study, we focused on the preparation of templated MMSs of nickel-based layered hydroxides by using pre-crystallized nano-building blocks (NBBs). Layered nickel hydroxide nanoparticles were prepared through an epoxide-mediated alkalinization process and used as NBBs to construct microspheres. The spherical particles in micrometer scale were synthesized by an aerosol-assisted assembly of the NBBs dispersed in a solvent, in the presence of supramolecular templates. It was found that controlling the crystallization as well as the surface philicity permits to yield the NBBs with an adequately small size and interparticle interactions that generate self-assembled MMSs akin to those obtained in NBB-based mesoporous thin films. The preparation technique demonstrated here is highly versatile; templated MMSs with various chemical compositions of nickel-based layered double hydroxides were successfully obtained. [Figure not available: see fulltext.] © 2018, Springer Science+Business Media, LLC, part of Springer Nature. JOUR info:eu-repo/semantics/openAccess http://creativecommons.org/licenses/by/2.5/ar http://hdl.handle.net/20.500.12110/paper_09280707_v89_n1_p216_Tarutani |
| institution |
Universidad de Buenos Aires |
| institution_str |
I-28 |
| repository_str |
R-134 |
| collection |
Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA) |
| topic |
Crystalline mesoporous microspheres Epoxide-mediated alkalinization Layered double hydroxides Layered nickel hydroxides Nano-building blocks Aerosols Association reactions Crystalline materials Film preparation Functional materials Mesoporous materials Microspheres Self assembly Structural dynamics Crystalline mesoporous Epoxide-mediated alkalinization Layered double hydroxides Nanobuilding blocks Nickel hydroxides Nickel compounds |
| spellingShingle |
Crystalline mesoporous microspheres Epoxide-mediated alkalinization Layered double hydroxides Layered nickel hydroxides Nano-building blocks Aerosols Association reactions Crystalline materials Film preparation Functional materials Mesoporous materials Microspheres Self assembly Structural dynamics Crystalline mesoporous Epoxide-mediated alkalinization Layered double hydroxides Nanobuilding blocks Nickel hydroxides Nickel compounds Tarutani, N. Tokudome, Y. Jobbágy, M. Soler-Illia, G.J.A.A. Takahashi, M. Mesoporous microspheres of nickel-based layered hydroxides by aerosol-assisted self-assembly using crystalline nano-building blocks |
| topic_facet |
Crystalline mesoporous microspheres Epoxide-mediated alkalinization Layered double hydroxides Layered nickel hydroxides Nano-building blocks Aerosols Association reactions Crystalline materials Film preparation Functional materials Mesoporous materials Microspheres Self assembly Structural dynamics Crystalline mesoporous Epoxide-mediated alkalinization Layered double hydroxides Nanobuilding blocks Nickel hydroxides Nickel compounds |
| description |
Structural control in micro- and nanometer scales is necessary to design highly functional materials. Crystalline mesoporous microspheres (MMSs) are expected to improve electrochemical, catalytic, and adsorption performances. In this study, we focused on the preparation of templated MMSs of nickel-based layered hydroxides by using pre-crystallized nano-building blocks (NBBs). Layered nickel hydroxide nanoparticles were prepared through an epoxide-mediated alkalinization process and used as NBBs to construct microspheres. The spherical particles in micrometer scale were synthesized by an aerosol-assisted assembly of the NBBs dispersed in a solvent, in the presence of supramolecular templates. It was found that controlling the crystallization as well as the surface philicity permits to yield the NBBs with an adequately small size and interparticle interactions that generate self-assembled MMSs akin to those obtained in NBB-based mesoporous thin films. The preparation technique demonstrated here is highly versatile; templated MMSs with various chemical compositions of nickel-based layered double hydroxides were successfully obtained. [Figure not available: see fulltext.] © 2018, Springer Science+Business Media, LLC, part of Springer Nature. |
| format |
JOUR |
| author |
Tarutani, N. Tokudome, Y. Jobbágy, M. Soler-Illia, G.J.A.A. Takahashi, M. |
| author_facet |
Tarutani, N. Tokudome, Y. Jobbágy, M. Soler-Illia, G.J.A.A. Takahashi, M. |
| author_sort |
Tarutani, N. |
| title |
Mesoporous microspheres of nickel-based layered hydroxides by aerosol-assisted self-assembly using crystalline nano-building blocks |
| title_short |
Mesoporous microspheres of nickel-based layered hydroxides by aerosol-assisted self-assembly using crystalline nano-building blocks |
| title_full |
Mesoporous microspheres of nickel-based layered hydroxides by aerosol-assisted self-assembly using crystalline nano-building blocks |
| title_fullStr |
Mesoporous microspheres of nickel-based layered hydroxides by aerosol-assisted self-assembly using crystalline nano-building blocks |
| title_full_unstemmed |
Mesoporous microspheres of nickel-based layered hydroxides by aerosol-assisted self-assembly using crystalline nano-building blocks |
| title_sort |
mesoporous microspheres of nickel-based layered hydroxides by aerosol-assisted self-assembly using crystalline nano-building blocks |
| url |
http://hdl.handle.net/20.500.12110/paper_09280707_v89_n1_p216_Tarutani |
| work_keys_str_mv |
AT tarutanin mesoporousmicrospheresofnickelbasedlayeredhydroxidesbyaerosolassistedselfassemblyusingcrystallinenanobuildingblocks AT tokudomey mesoporousmicrospheresofnickelbasedlayeredhydroxidesbyaerosolassistedselfassemblyusingcrystallinenanobuildingblocks AT jobbagym mesoporousmicrospheresofnickelbasedlayeredhydroxidesbyaerosolassistedselfassemblyusingcrystallinenanobuildingblocks AT solerilliagjaa mesoporousmicrospheresofnickelbasedlayeredhydroxidesbyaerosolassistedselfassemblyusingcrystallinenanobuildingblocks AT takahashim mesoporousmicrospheresofnickelbasedlayeredhydroxidesbyaerosolassistedselfassemblyusingcrystallinenanobuildingblocks |
| _version_ |
1807322946766635008 |