Hybridization functions of intermetallic Ce compounds with group VI elements
Among the Cerium compounds, the heavier monochalcogenides CeY (Y = S,Se,Te) of cerium provide a class of compounds which together with the heavier monopnictides CeX (X = N,P,As,Sb,Bi) exhibit extremely interesting physical properties. The hybridization of the partially delocalized f-electrons seems...
Guardado en:
Autores principales: | , , |
---|---|
Formato: | JOUR |
Materias: | |
Acceso en línea: | http://hdl.handle.net/20.500.12110/paper_09214526_v384_n1-2_p202_RouraBas |
Aporte de: |
id |
todo:paper_09214526_v384_n1-2_p202_RouraBas |
---|---|
record_format |
dspace |
spelling |
todo:paper_09214526_v384_n1-2_p202_RouraBas2023-10-03T15:45:17Z Hybridization functions of intermetallic Ce compounds with group VI elements Roura-Bas, P. Vildosola, V. Llois, A.M. Crystal fields Highly correlated systems p-electron Band structure Electrons Fermi level Intermetallics Conduction band Density of states Monochalcogenides Cerium compounds Among the Cerium compounds, the heavier monochalcogenides CeY (Y = S,Se,Te) of cerium provide a class of compounds which together with the heavier monopnictides CeX (X = N,P,As,Sb,Bi) exhibit extremely interesting physical properties. The hybridization of the partially delocalized f-electrons seems to be responsible for the unusual properties, in particular the magnetic ones which show great chemical sensitivity. As compared to the monopnictides, the monochalcogenides have an additional anion p-electron which shifts the Fermi energy into the p-region of the Cerium 5d-derived density of states, and which should affect the hybridization function of the electrons in the conduction band. In this contribution we analyze the 4f-hybridization function and the crystal-field splittings of the compounds under study. © 2006 Elsevier B.V. All rights reserved. JOUR info:eu-repo/semantics/openAccess http://creativecommons.org/licenses/by/2.5/ar http://hdl.handle.net/20.500.12110/paper_09214526_v384_n1-2_p202_RouraBas |
institution |
Universidad de Buenos Aires |
institution_str |
I-28 |
repository_str |
R-134 |
collection |
Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA) |
topic |
Crystal fields Highly correlated systems p-electron Band structure Electrons Fermi level Intermetallics Conduction band Density of states Monochalcogenides Cerium compounds |
spellingShingle |
Crystal fields Highly correlated systems p-electron Band structure Electrons Fermi level Intermetallics Conduction band Density of states Monochalcogenides Cerium compounds Roura-Bas, P. Vildosola, V. Llois, A.M. Hybridization functions of intermetallic Ce compounds with group VI elements |
topic_facet |
Crystal fields Highly correlated systems p-electron Band structure Electrons Fermi level Intermetallics Conduction band Density of states Monochalcogenides Cerium compounds |
description |
Among the Cerium compounds, the heavier monochalcogenides CeY (Y = S,Se,Te) of cerium provide a class of compounds which together with the heavier monopnictides CeX (X = N,P,As,Sb,Bi) exhibit extremely interesting physical properties. The hybridization of the partially delocalized f-electrons seems to be responsible for the unusual properties, in particular the magnetic ones which show great chemical sensitivity. As compared to the monopnictides, the monochalcogenides have an additional anion p-electron which shifts the Fermi energy into the p-region of the Cerium 5d-derived density of states, and which should affect the hybridization function of the electrons in the conduction band. In this contribution we analyze the 4f-hybridization function and the crystal-field splittings of the compounds under study. © 2006 Elsevier B.V. All rights reserved. |
format |
JOUR |
author |
Roura-Bas, P. Vildosola, V. Llois, A.M. |
author_facet |
Roura-Bas, P. Vildosola, V. Llois, A.M. |
author_sort |
Roura-Bas, P. |
title |
Hybridization functions of intermetallic Ce compounds with group VI elements |
title_short |
Hybridization functions of intermetallic Ce compounds with group VI elements |
title_full |
Hybridization functions of intermetallic Ce compounds with group VI elements |
title_fullStr |
Hybridization functions of intermetallic Ce compounds with group VI elements |
title_full_unstemmed |
Hybridization functions of intermetallic Ce compounds with group VI elements |
title_sort |
hybridization functions of intermetallic ce compounds with group vi elements |
url |
http://hdl.handle.net/20.500.12110/paper_09214526_v384_n1-2_p202_RouraBas |
work_keys_str_mv |
AT rourabasp hybridizationfunctionsofintermetalliccecompoundswithgroupvielements AT vildosolav hybridizationfunctionsofintermetalliccecompoundswithgroupvielements AT lloisam hybridizationfunctionsofintermetalliccecompoundswithgroupvielements |
_version_ |
1782025364012269568 |