Single-Nanometer-Sized Low-Valence Metal Hydroxide Crystals: Synthesis via Epoxide-Mediated Alkalinization and Assembly toward Functional Mesoporous Materials
A study demonstrated a simple synthesis approach toward single-nanometer-sized crystals that work as nanobuilding blocks (NBBs) to form a great variety of mesoporous hydroxides and derived phases. The nanocrystals with diverse chemical compositions low-valence metal hydroxides, α-M(OH)2 (M = Mn(II),...
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| Formato: | JOUR |
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| Acceso en línea: | http://hdl.handle.net/20.500.12110/paper_08974756_v28_n16_p5606_Tarutani |
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todo:paper_08974756_v28_n16_p5606_Tarutani2023-10-03T15:43:54Z Single-Nanometer-Sized Low-Valence Metal Hydroxide Crystals: Synthesis via Epoxide-Mediated Alkalinization and Assembly toward Functional Mesoporous Materials Tarutani, N. Tokudome, Y. Jobbágy, M. Viva, F.A. Soler-Illia, G.J.A.A. Takahashi, M. Chromium compounds Manganese Metals Nanocrystals Aqueous ethanol solutions Chemical compositions Controlling agent Mesoporous Metal salt solution Nanobuilding blocks Nanocrystal formation Valence metals Mesoporous materials A study demonstrated a simple synthesis approach toward single-nanometer-sized crystals that work as nanobuilding blocks (NBBs) to form a great variety of mesoporous hydroxides and derived phases. The nanocrystals with diverse chemical compositions low-valence metal hydroxides, α-M(OH)2 (M = Mn(II), Fe(II), Co(II), Ni(II), and Cu(II)), and other (hydr)oxides composed of Al(III), Cr(III), Fe(III), Zr(IV), and Sn(IV)) were prepared in an aqueous ethanol solution. The nanocrystal formation was achieved by inducing a high supersaturation via the epoxidemediated alkalinization in a concentrated metal salt solution. A variety of carboxylic acids were used as growth controlling agents, permitting to finely control the size of low-valence metal hydroxide nanocrystals and to attain high stability against aggregation. Fil:Soler-Illia, G.J.A.A. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. JOUR info:eu-repo/semantics/openAccess http://creativecommons.org/licenses/by/2.5/ar http://hdl.handle.net/20.500.12110/paper_08974756_v28_n16_p5606_Tarutani |
| institution |
Universidad de Buenos Aires |
| institution_str |
I-28 |
| repository_str |
R-134 |
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Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA) |
| topic |
Chromium compounds Manganese Metals Nanocrystals Aqueous ethanol solutions Chemical compositions Controlling agent Mesoporous Metal salt solution Nanobuilding blocks Nanocrystal formation Valence metals Mesoporous materials |
| spellingShingle |
Chromium compounds Manganese Metals Nanocrystals Aqueous ethanol solutions Chemical compositions Controlling agent Mesoporous Metal salt solution Nanobuilding blocks Nanocrystal formation Valence metals Mesoporous materials Tarutani, N. Tokudome, Y. Jobbágy, M. Viva, F.A. Soler-Illia, G.J.A.A. Takahashi, M. Single-Nanometer-Sized Low-Valence Metal Hydroxide Crystals: Synthesis via Epoxide-Mediated Alkalinization and Assembly toward Functional Mesoporous Materials |
| topic_facet |
Chromium compounds Manganese Metals Nanocrystals Aqueous ethanol solutions Chemical compositions Controlling agent Mesoporous Metal salt solution Nanobuilding blocks Nanocrystal formation Valence metals Mesoporous materials |
| description |
A study demonstrated a simple synthesis approach toward single-nanometer-sized crystals that work as nanobuilding blocks (NBBs) to form a great variety of mesoporous hydroxides and derived phases. The nanocrystals with diverse chemical compositions low-valence metal hydroxides, α-M(OH)2 (M = Mn(II), Fe(II), Co(II), Ni(II), and Cu(II)), and other (hydr)oxides composed of Al(III), Cr(III), Fe(III), Zr(IV), and Sn(IV)) were prepared in an aqueous ethanol solution. The nanocrystal formation was achieved by inducing a high supersaturation via the epoxidemediated alkalinization in a concentrated metal salt solution. A variety of carboxylic acids were used as growth controlling agents, permitting to finely control the size of low-valence metal hydroxide nanocrystals and to attain high stability against aggregation. |
| format |
JOUR |
| author |
Tarutani, N. Tokudome, Y. Jobbágy, M. Viva, F.A. Soler-Illia, G.J.A.A. Takahashi, M. |
| author_facet |
Tarutani, N. Tokudome, Y. Jobbágy, M. Viva, F.A. Soler-Illia, G.J.A.A. Takahashi, M. |
| author_sort |
Tarutani, N. |
| title |
Single-Nanometer-Sized Low-Valence Metal Hydroxide Crystals: Synthesis via Epoxide-Mediated Alkalinization and Assembly toward Functional Mesoporous Materials |
| title_short |
Single-Nanometer-Sized Low-Valence Metal Hydroxide Crystals: Synthesis via Epoxide-Mediated Alkalinization and Assembly toward Functional Mesoporous Materials |
| title_full |
Single-Nanometer-Sized Low-Valence Metal Hydroxide Crystals: Synthesis via Epoxide-Mediated Alkalinization and Assembly toward Functional Mesoporous Materials |
| title_fullStr |
Single-Nanometer-Sized Low-Valence Metal Hydroxide Crystals: Synthesis via Epoxide-Mediated Alkalinization and Assembly toward Functional Mesoporous Materials |
| title_full_unstemmed |
Single-Nanometer-Sized Low-Valence Metal Hydroxide Crystals: Synthesis via Epoxide-Mediated Alkalinization and Assembly toward Functional Mesoporous Materials |
| title_sort |
single-nanometer-sized low-valence metal hydroxide crystals: synthesis via epoxide-mediated alkalinization and assembly toward functional mesoporous materials |
| url |
http://hdl.handle.net/20.500.12110/paper_08974756_v28_n16_p5606_Tarutani |
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