Petrology and geochemistry of Carboniferous siliciclastics from the Argentine Frontal Cordillera: A test of methods for interpreting provenance and tectonic setting

Petrological and geochemical characteristics of sandstones and shales from the Carboniferous Cerro Agua Negra Formation (Río Blanco basin, western Argentina) are discussed. The sandstones are mostly feldspathic litharenites with subordinate litharenites and lithic arkoses, and their modal compositio...

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Autores principales: Spalletti, L.A., Limarino, C.O., Piñol, F.C.
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Acceso en línea:http://hdl.handle.net/20.500.12110/paper_08959811_v36_n_p32_Spalletti
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spelling todo:paper_08959811_v36_n_p32_Spalletti2023-10-03T15:43:03Z Petrology and geochemistry of Carboniferous siliciclastics from the Argentine Frontal Cordillera: A test of methods for interpreting provenance and tectonic setting Spalletti, L.A. Limarino, C.O. Piñol, F.C. Argentina Carboniferous Río Blanco Basin Sandstone petrology Sedimentary geochemistry Carboniferous chemical alteration chemical composition continental crust feldspar felsic rock lithology metasedimentary rock petrology plutonic rock provenance rare earth element remobilization sandstone sediment chemistry siliciclastic deposit source rock tectonic setting Argentina Blanco Basin Petrological and geochemical characteristics of sandstones and shales from the Carboniferous Cerro Agua Negra Formation (Río Blanco basin, western Argentina) are discussed. The sandstones are mostly feldspathic litharenites with subordinate litharenites and lithic arkoses, and their modal compositions indicate two major sources. The first represents a recycled orogen and can be identified as the Protoprecordillera, a N-S trending mountainous area that separated the Paganzo and Río Blanco basins and that was a positive element at least up until the end of the Carboniferous. The second was further east, in the Sierras Pampeanas terrane. It consisted of a variety of metasedimentary and felsic plutonic crystalline rocks. The Protoprecordillera must have been crossed by transverse valleys that facilitated the transfer of Pampean terrigenous material towards the Río Blanco basin. A lack of volcanogenic sand suggests that the basin was open towards proto-Pacific in the west, rather than being separated from it by a magmatic arc as previously suggested.Bulk geochemical analysis of different lithological types (arenites, wackes and shales) demonstrates a strong relationship between texture and chemical composition of the rocks, even taking into account the immobile elements. The largest differences are between shales and arenites, while the wackes have intermediate compositions. The CIA (chemical index of alteration) indicates partial remobilisation of oxides from source rocks and enrichment of aluminium and potassium in the shales, which reflects their potassic clay mineral composition. Overall, siliciclastics of the Cerro Agua Negra Formation have a similar composition to the upper continental crust (with slight net enrichment of SiO 2 in the arenites and of Al 2O 3 in the shales). Rare earth element profiles reflect terrigenous contributions, since they are enriched in light-REE, have a pronounced negative Eu anomaly and a relative depletion of the heavy-REE. The results show that discrimination plots commonly employed to infer provenance and tectonic setting from siliclastics are compromised where bulk chemical composition is strongly dependent on grain size and sorting. © 2011 Elsevier Ltd. Fil:Limarino, C.O. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. JOUR info:eu-repo/semantics/openAccess http://creativecommons.org/licenses/by/2.5/ar http://hdl.handle.net/20.500.12110/paper_08959811_v36_n_p32_Spalletti
institution Universidad de Buenos Aires
institution_str I-28
repository_str R-134
collection Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA)
topic Argentina
Carboniferous
Río Blanco Basin
Sandstone petrology
Sedimentary geochemistry
Carboniferous
chemical alteration
chemical composition
continental crust
feldspar
felsic rock
lithology
metasedimentary rock
petrology
plutonic rock
provenance
rare earth element
remobilization
sandstone
sediment chemistry
siliciclastic deposit
source rock
tectonic setting
Argentina
Blanco Basin
spellingShingle Argentina
Carboniferous
Río Blanco Basin
Sandstone petrology
Sedimentary geochemistry
Carboniferous
chemical alteration
chemical composition
continental crust
feldspar
felsic rock
lithology
metasedimentary rock
petrology
plutonic rock
provenance
rare earth element
remobilization
sandstone
sediment chemistry
siliciclastic deposit
source rock
tectonic setting
Argentina
Blanco Basin
Spalletti, L.A.
Limarino, C.O.
Piñol, F.C.
Petrology and geochemistry of Carboniferous siliciclastics from the Argentine Frontal Cordillera: A test of methods for interpreting provenance and tectonic setting
topic_facet Argentina
Carboniferous
Río Blanco Basin
Sandstone petrology
Sedimentary geochemistry
Carboniferous
chemical alteration
chemical composition
continental crust
feldspar
felsic rock
lithology
metasedimentary rock
petrology
plutonic rock
provenance
rare earth element
remobilization
sandstone
sediment chemistry
siliciclastic deposit
source rock
tectonic setting
Argentina
Blanco Basin
description Petrological and geochemical characteristics of sandstones and shales from the Carboniferous Cerro Agua Negra Formation (Río Blanco basin, western Argentina) are discussed. The sandstones are mostly feldspathic litharenites with subordinate litharenites and lithic arkoses, and their modal compositions indicate two major sources. The first represents a recycled orogen and can be identified as the Protoprecordillera, a N-S trending mountainous area that separated the Paganzo and Río Blanco basins and that was a positive element at least up until the end of the Carboniferous. The second was further east, in the Sierras Pampeanas terrane. It consisted of a variety of metasedimentary and felsic plutonic crystalline rocks. The Protoprecordillera must have been crossed by transverse valleys that facilitated the transfer of Pampean terrigenous material towards the Río Blanco basin. A lack of volcanogenic sand suggests that the basin was open towards proto-Pacific in the west, rather than being separated from it by a magmatic arc as previously suggested.Bulk geochemical analysis of different lithological types (arenites, wackes and shales) demonstrates a strong relationship between texture and chemical composition of the rocks, even taking into account the immobile elements. The largest differences are between shales and arenites, while the wackes have intermediate compositions. The CIA (chemical index of alteration) indicates partial remobilisation of oxides from source rocks and enrichment of aluminium and potassium in the shales, which reflects their potassic clay mineral composition. Overall, siliciclastics of the Cerro Agua Negra Formation have a similar composition to the upper continental crust (with slight net enrichment of SiO 2 in the arenites and of Al 2O 3 in the shales). Rare earth element profiles reflect terrigenous contributions, since they are enriched in light-REE, have a pronounced negative Eu anomaly and a relative depletion of the heavy-REE. The results show that discrimination plots commonly employed to infer provenance and tectonic setting from siliclastics are compromised where bulk chemical composition is strongly dependent on grain size and sorting. © 2011 Elsevier Ltd.
format JOUR
author Spalletti, L.A.
Limarino, C.O.
Piñol, F.C.
author_facet Spalletti, L.A.
Limarino, C.O.
Piñol, F.C.
author_sort Spalletti, L.A.
title Petrology and geochemistry of Carboniferous siliciclastics from the Argentine Frontal Cordillera: A test of methods for interpreting provenance and tectonic setting
title_short Petrology and geochemistry of Carboniferous siliciclastics from the Argentine Frontal Cordillera: A test of methods for interpreting provenance and tectonic setting
title_full Petrology and geochemistry of Carboniferous siliciclastics from the Argentine Frontal Cordillera: A test of methods for interpreting provenance and tectonic setting
title_fullStr Petrology and geochemistry of Carboniferous siliciclastics from the Argentine Frontal Cordillera: A test of methods for interpreting provenance and tectonic setting
title_full_unstemmed Petrology and geochemistry of Carboniferous siliciclastics from the Argentine Frontal Cordillera: A test of methods for interpreting provenance and tectonic setting
title_sort petrology and geochemistry of carboniferous siliciclastics from the argentine frontal cordillera: a test of methods for interpreting provenance and tectonic setting
url http://hdl.handle.net/20.500.12110/paper_08959811_v36_n_p32_Spalletti
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