Aromatic nucleophilic substitution in aprotic solvents using hydrogen-bonded biological amines. Kinetic studies and quantum chemical calculations

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Intermolecular and intramolecular non-bonding interactions play a crucial role in determining physical and biological properties of relevant amines, and we have recently reported that they are also responsible for changing mechanisms in aromatic nucleophilic substitution (ANS) involving amine nucleo...

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Detalles Bibliográficos
Autores principales: Alvaro, C.E.S., Bergero, F.D., Bolcic, F.M., Ramos, S.B., Sbarbati Nudelman, N.
Formato: JOUR
Materias:
aprotic solvents
aromatic nucleophilic substitution
biological amines
dimer nucleophile mechanism
hydrogen bonding
Amines
Amino acids
Aromatization
Calculations
Continuum mechanics
Copyrights
Density functional theory
Dimers
Hydrogen
Kinetic theory
Kinetics
Nucleophiles
Quantum chemistry
Solvents
Toluene
1-chloro-2 , 4-dinitrobenzene
Ab initio density functional theories (DFT)
Aprotic solvents
Aromatic nucleophilic substitution
Basis set superposition errors
Dimer nucleophile mechanisms
Quantum chemical calculations
Specific hydrogen bondings
Hydrogen bonds
Acceso en línea:http://hdl.handle.net/20.500.12110/paper_08943230_v29_n11_p565_Alvaro
Aporte de:
Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA) de Universidad de Buenos Aires

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