The high-resolution 1h nmr spectra and conformations of n-acetyl-α-d-galactopyranosylamine peracetate and 1, 1-bis(acetamido)-l-deoxy-d-glucitol peracetate in aqueous medium

In contrast with the spectra previously measured with lower resolution equipment, the 500-MHz 1H NMR spectra of l, l-bis(acetam1do)-1-deoxy-D-gl ucitol peracetate and N-acetyl-α-D-galactopyranosylamine peracetate in aqueous solution were amenable to full resolution. The former compound shows a “sick...

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Autores principales: Matulewicz, M.C., Stortz, C.A., Jarret, R.M., Cerezo, A.S.
Formato: JOUR
Acceso en línea:http://hdl.handle.net/20.500.12110/paper_07328303_v6_n3_p515_Matulewicz
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Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA) de Universidad de Buenos Aires
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spelling todo:paper_07328303_v6_n3_p515_Matulewicz2023-10-03T15:37:34Z The high-resolution 1h nmr spectra and conformations of n-acetyl-α-d-galactopyranosylamine peracetate and 1, 1-bis(acetamido)-l-deoxy-d-glucitol peracetate in aqueous medium Matulewicz, M.C. Stortz, C.A. Jarret, R.M. Cerezo, A.S. In contrast with the spectra previously measured with lower resolution equipment, the 500-MHz 1H NMR spectra of l, l-bis(acetam1do)-1-deoxy-D-gl ucitol peracetate and N-acetyl-α-D-galactopyranosylamine peracetate in aqueous solution were amenable to full resolution. The former compound shows a “sickle” conformation produced by rotation of the C2–C3 bond out of the planar, zigzag arrangement, while the latter has a 4C1conformation. © 1987, Taylor & Francis Group, LLC. All rights reserved. JOUR info:eu-repo/semantics/openAccess http://creativecommons.org/licenses/by/2.5/ar http://hdl.handle.net/20.500.12110/paper_07328303_v6_n3_p515_Matulewicz
institution Universidad de Buenos Aires
institution_str I-28
repository_str R-134
collection Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA)
description In contrast with the spectra previously measured with lower resolution equipment, the 500-MHz 1H NMR spectra of l, l-bis(acetam1do)-1-deoxy-D-gl ucitol peracetate and N-acetyl-α-D-galactopyranosylamine peracetate in aqueous solution were amenable to full resolution. The former compound shows a “sickle” conformation produced by rotation of the C2–C3 bond out of the planar, zigzag arrangement, while the latter has a 4C1conformation. © 1987, Taylor & Francis Group, LLC. All rights reserved.
format JOUR
author Matulewicz, M.C.
Stortz, C.A.
Jarret, R.M.
Cerezo, A.S.
spellingShingle Matulewicz, M.C.
Stortz, C.A.
Jarret, R.M.
Cerezo, A.S.
The high-resolution 1h nmr spectra and conformations of n-acetyl-α-d-galactopyranosylamine peracetate and 1, 1-bis(acetamido)-l-deoxy-d-glucitol peracetate in aqueous medium
author_facet Matulewicz, M.C.
Stortz, C.A.
Jarret, R.M.
Cerezo, A.S.
author_sort Matulewicz, M.C.
title The high-resolution 1h nmr spectra and conformations of n-acetyl-α-d-galactopyranosylamine peracetate and 1, 1-bis(acetamido)-l-deoxy-d-glucitol peracetate in aqueous medium
title_short The high-resolution 1h nmr spectra and conformations of n-acetyl-α-d-galactopyranosylamine peracetate and 1, 1-bis(acetamido)-l-deoxy-d-glucitol peracetate in aqueous medium
title_full The high-resolution 1h nmr spectra and conformations of n-acetyl-α-d-galactopyranosylamine peracetate and 1, 1-bis(acetamido)-l-deoxy-d-glucitol peracetate in aqueous medium
title_fullStr The high-resolution 1h nmr spectra and conformations of n-acetyl-α-d-galactopyranosylamine peracetate and 1, 1-bis(acetamido)-l-deoxy-d-glucitol peracetate in aqueous medium
title_full_unstemmed The high-resolution 1h nmr spectra and conformations of n-acetyl-α-d-galactopyranosylamine peracetate and 1, 1-bis(acetamido)-l-deoxy-d-glucitol peracetate in aqueous medium
title_sort high-resolution 1h nmr spectra and conformations of n-acetyl-α-d-galactopyranosylamine peracetate and 1, 1-bis(acetamido)-l-deoxy-d-glucitol peracetate in aqueous medium
url http://hdl.handle.net/20.500.12110/paper_07328303_v6_n3_p515_Matulewicz
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