Quantitative analysis of metals in waste foundry sands by calibration free-laser induced breakdown spectroscopy

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Laser-induced breakdown spectroscopy (LIBS) was applied for quantitative analysis of the elemental composition of waste molding and core sands produced from industry as part of the casting process. To perform the analysis, waste foundry sands (WFS) were collected from metalcasting foundries and prep...

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Autores principales:	Díaz Pace, D.M., Miguel, R.E., Di Rocco, H.O., Anabitarte García, F., Pardini, L., Legnaioli, S., Lorenzetti, G., Palleschi, V.
Formato:	JOUR
Materias:	Laser-induced breakdown spectroscopy LIBS Plasma characterization Waste sand Atomic emission spectroscopy Binders Bins Calibration Chemical analysis Foundries Foundry sand Laser induced breakdown spectroscopy Magnesium Manganese Metal analysis Metals Sand Titanium Chemical characterization Complementary techniques Elemental compositions Laserinduced breakdown spectroscopy (LIBS) Metal concentrations Waste sands Spectrum analysis
Acceso en línea:	http://hdl.handle.net/20.500.12110/paper_05848547_v131_n_p58_DiazPace
Aporte de:	Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA) de Universidad de Buenos Aires

id	todo:paper_05848547_v131_n_p58_DiazPace
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spelling	todo:paper_05848547_v131_n_p58_DiazPace2023-10-03T15:36:04Z Quantitative analysis of metals in waste foundry sands by calibration free-laser induced breakdown spectroscopy Díaz Pace, D.M. Miguel, R.E. Di Rocco, H.O. Anabitarte García, F. Pardini, L. Legnaioli, S. Lorenzetti, G. Palleschi, V. Laser-induced breakdown spectroscopy LIBS Plasma characterization Waste sand Atomic emission spectroscopy Binders Bins Calibration Chemical analysis Foundries Foundry sand Laser induced breakdown spectroscopy Magnesium Manganese Metal analysis Metals Sand Titanium Chemical characterization Complementary techniques Elemental compositions Laserinduced breakdown spectroscopy (LIBS) LIBS Metal concentrations Plasma characterization Waste sands Spectrum analysis Laser-induced breakdown spectroscopy (LIBS) was applied for quantitative analysis of the elemental composition of waste molding and core sands produced from industry as part of the casting process. To perform the analysis, waste foundry sands (WFS) were collected from metalcasting foundries and prepared in the form of solid pellets with the addition of polyvinyl alcohol as binder. The measurements were carried out using the Mobile double pulse instrument for LIBS analysis (Modì). The spectral analysis was carried out with the calibration-free approach (CF-LIBS). Metal elements commonly found in WFS including Al, Ba, Fe, Li, Mg, Mn, Pb, Ti, Zr, and Zn, were detected and quantified. The metal concentrations for WFS were compared with virgin sand to assess the influence of the casting material as well as the binders used in the foundries to reclaim the sands. The results demonstrated the feasibility of LIBS method as an alternative or complementary technique for the chemical characterization of WFS. © 2017 Elsevier B.V. JOUR info:eu-repo/semantics/openAccess http://creativecommons.org/licenses/by/2.5/ar http://hdl.handle.net/20.500.12110/paper_05848547_v131_n_p58_DiazPace
institution	Universidad de Buenos Aires
institution_str	I-28
repository_str	R-134
collection	Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA)
topic	Laser-induced breakdown spectroscopy LIBS Plasma characterization Waste sand Atomic emission spectroscopy Binders Bins Calibration Chemical analysis Foundries Foundry sand Laser induced breakdown spectroscopy Magnesium Manganese Metal analysis Metals Sand Titanium Chemical characterization Complementary techniques Elemental compositions Laserinduced breakdown spectroscopy (LIBS) LIBS Metal concentrations Plasma characterization Waste sands Spectrum analysis
spellingShingle	Laser-induced breakdown spectroscopy LIBS Plasma characterization Waste sand Atomic emission spectroscopy Binders Bins Calibration Chemical analysis Foundries Foundry sand Laser induced breakdown spectroscopy Magnesium Manganese Metal analysis Metals Sand Titanium Chemical characterization Complementary techniques Elemental compositions Laserinduced breakdown spectroscopy (LIBS) LIBS Metal concentrations Plasma characterization Waste sands Spectrum analysis Díaz Pace, D.M. Miguel, R.E. Di Rocco, H.O. Anabitarte García, F. Pardini, L. Legnaioli, S. Lorenzetti, G. Palleschi, V. Quantitative analysis of metals in waste foundry sands by calibration free-laser induced breakdown spectroscopy
topic_facet	Laser-induced breakdown spectroscopy LIBS Plasma characterization Waste sand Atomic emission spectroscopy Binders Bins Calibration Chemical analysis Foundries Foundry sand Laser induced breakdown spectroscopy Magnesium Manganese Metal analysis Metals Sand Titanium Chemical characterization Complementary techniques Elemental compositions Laserinduced breakdown spectroscopy (LIBS) LIBS Metal concentrations Plasma characterization Waste sands Spectrum analysis
description	Laser-induced breakdown spectroscopy (LIBS) was applied for quantitative analysis of the elemental composition of waste molding and core sands produced from industry as part of the casting process. To perform the analysis, waste foundry sands (WFS) were collected from metalcasting foundries and prepared in the form of solid pellets with the addition of polyvinyl alcohol as binder. The measurements were carried out using the Mobile double pulse instrument for LIBS analysis (Modì). The spectral analysis was carried out with the calibration-free approach (CF-LIBS). Metal elements commonly found in WFS including Al, Ba, Fe, Li, Mg, Mn, Pb, Ti, Zr, and Zn, were detected and quantified. The metal concentrations for WFS were compared with virgin sand to assess the influence of the casting material as well as the binders used in the foundries to reclaim the sands. The results demonstrated the feasibility of LIBS method as an alternative or complementary technique for the chemical characterization of WFS. © 2017 Elsevier B.V.
format	JOUR
author	Díaz Pace, D.M. Miguel, R.E. Di Rocco, H.O. Anabitarte García, F. Pardini, L. Legnaioli, S. Lorenzetti, G. Palleschi, V.
author_facet	Díaz Pace, D.M. Miguel, R.E. Di Rocco, H.O. Anabitarte García, F. Pardini, L. Legnaioli, S. Lorenzetti, G. Palleschi, V.
author_sort	Díaz Pace, D.M.
title	Quantitative analysis of metals in waste foundry sands by calibration free-laser induced breakdown spectroscopy
title_short	Quantitative analysis of metals in waste foundry sands by calibration free-laser induced breakdown spectroscopy
title_full	Quantitative analysis of metals in waste foundry sands by calibration free-laser induced breakdown spectroscopy
title_fullStr	Quantitative analysis of metals in waste foundry sands by calibration free-laser induced breakdown spectroscopy
title_full_unstemmed	Quantitative analysis of metals in waste foundry sands by calibration free-laser induced breakdown spectroscopy
title_sort	quantitative analysis of metals in waste foundry sands by calibration free-laser induced breakdown spectroscopy
url	http://hdl.handle.net/20.500.12110/paper_05848547_v131_n_p58_DiazPace
work_keys_str_mv	AT diazpacedm quantitativeanalysisofmetalsinwastefoundrysandsbycalibrationfreelaserinducedbreakdownspectroscopy AT miguelre quantitativeanalysisofmetalsinwastefoundrysandsbycalibrationfreelaserinducedbreakdownspectroscopy AT diroccoho quantitativeanalysisofmetalsinwastefoundrysandsbycalibrationfreelaserinducedbreakdownspectroscopy AT anabitartegarciaf quantitativeanalysisofmetalsinwastefoundrysandsbycalibrationfreelaserinducedbreakdownspectroscopy AT pardinil quantitativeanalysisofmetalsinwastefoundrysandsbycalibrationfreelaserinducedbreakdownspectroscopy AT legnaiolis quantitativeanalysisofmetalsinwastefoundrysandsbycalibrationfreelaserinducedbreakdownspectroscopy AT lorenzettig quantitativeanalysisofmetalsinwastefoundrysandsbycalibrationfreelaserinducedbreakdownspectroscopy AT palleschiv quantitativeanalysisofmetalsinwastefoundrysandsbycalibrationfreelaserinducedbreakdownspectroscopy
_version_	1807316355433627648

Quantitative analysis of metals in waste foundry sands by calibration free-laser induced breakdown spectroscopy

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