The "dimer nucleophile mechanism" for reactions with rate-determining first step: Derivation of the whole kinetic law and further treatment of kinetic results
Overwhelming evidence has been previously reported for the existence of the so-called "dimer nucleophile mechanism" in aromatic nucleophilic substitutions by amines in aprotic solvents, for which the most prominent feature is the fourth-order kinetics (third order in amine) that has been o...
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Autores principales: | Alvaro, C.E.S., Nudelman, N.S. |
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Formato: | JOUR |
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Acceso en línea: | http://hdl.handle.net/20.500.12110/paper_05388066_v42_n12_p735_Alvaro |
Aporte de: |
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