Synthesis of anionic derivatives of methyl laminara-oligosaccharides and methyl β-maltoside
Anionic derivatives of methyl β-laminarabioside, methyl β-laminaratrioside and methyl β-maltoside, substituted in the primary hydroxyl groups, were synthesized and characterized spectroscopically. Sulfated methyl laminara-oligosaccharides (DP≥5) were also prepared. These model compounds for conforma...
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| Acceso en línea: | http://hdl.handle.net/20.500.12110/paper_03650375_v86_n3-6_p261_Leit |
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todo:paper_03650375_v86_n3-6_p261_Leit2023-10-03T15:27:53Z Synthesis of anionic derivatives of methyl laminara-oligosaccharides and methyl β-maltoside Leit, S. Fernández Cirelli, A. Anionic derivatives of methyl β-laminarabioside, methyl β-laminaratrioside and methyl β-maltoside, substituted in the primary hydroxyl groups, were synthesized and characterized spectroscopically. Sulfated methyl laminara-oligosaccharides (DP≥5) were also prepared. These model compounds for conformational studies allow the comparison of the influence of different anionic substituents (sulfate, phosphate, succinate and carboxylate) on the β-(1→3) and α-(1→4) glycosidic bond. JOUR info:eu-repo/semantics/openAccess http://creativecommons.org/licenses/by/2.5/ar http://hdl.handle.net/20.500.12110/paper_03650375_v86_n3-6_p261_Leit |
| institution |
Universidad de Buenos Aires |
| institution_str |
I-28 |
| repository_str |
R-134 |
| collection |
Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA) |
| description |
Anionic derivatives of methyl β-laminarabioside, methyl β-laminaratrioside and methyl β-maltoside, substituted in the primary hydroxyl groups, were synthesized and characterized spectroscopically. Sulfated methyl laminara-oligosaccharides (DP≥5) were also prepared. These model compounds for conformational studies allow the comparison of the influence of different anionic substituents (sulfate, phosphate, succinate and carboxylate) on the β-(1→3) and α-(1→4) glycosidic bond. |
| format |
JOUR |
| author |
Leit, S. Fernández Cirelli, A. |
| spellingShingle |
Leit, S. Fernández Cirelli, A. Synthesis of anionic derivatives of methyl laminara-oligosaccharides and methyl β-maltoside |
| author_facet |
Leit, S. Fernández Cirelli, A. |
| author_sort |
Leit, S. |
| title |
Synthesis of anionic derivatives of methyl laminara-oligosaccharides and methyl β-maltoside |
| title_short |
Synthesis of anionic derivatives of methyl laminara-oligosaccharides and methyl β-maltoside |
| title_full |
Synthesis of anionic derivatives of methyl laminara-oligosaccharides and methyl β-maltoside |
| title_fullStr |
Synthesis of anionic derivatives of methyl laminara-oligosaccharides and methyl β-maltoside |
| title_full_unstemmed |
Synthesis of anionic derivatives of methyl laminara-oligosaccharides and methyl β-maltoside |
| title_sort |
synthesis of anionic derivatives of methyl laminara-oligosaccharides and methyl β-maltoside |
| url |
http://hdl.handle.net/20.500.12110/paper_03650375_v86_n3-6_p261_Leit |
| work_keys_str_mv |
AT leits synthesisofanionicderivativesofmethyllaminaraoligosaccharidesandmethylbmaltoside AT fernandezcirellia synthesisofanionicderivativesofmethyllaminaraoligosaccharidesandmethylbmaltoside |
| _version_ |
1807321418324508672 |