Cu/MnOx-CeO2 and Ni/MnOx-CeO2 catalysts for the water-gas shift reaction: Metal-support interaction
Monometallic copper and nickel catalysts supported on cerium-manganese mixed oxides are prepared, characterized and evaluated for the Water-Gas Shift (WGS) reaction. Active metal loading of 2.5 wt% and 7.5 wt% are used to impregnate MnOx-CeO2 supports with 30% and 50% Mn:Ce molar ratio. The structur...
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| Acceso en línea: | http://hdl.handle.net/20.500.12110/paper_03603199_v39_n16_p8675_PoggioFraccari |
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todo:paper_03603199_v39_n16_p8675_PoggioFraccari2023-10-03T15:26:28Z Cu/MnOx-CeO2 and Ni/MnOx-CeO2 catalysts for the water-gas shift reaction: Metal-support interaction Poggio-Fraccari, E. Sambeth, J. Baronetti, G. Mariño, F. Cerium Fuel cells Hydrogen purification Ilmenite Manganese Spinel Catalysts Cerium Fuel cells Ilmenite Manganese Manganese oxide Metals Water gas shift Catalytic behavior Copper and nickel catalysts Hydrogen purification Ilmenite structure Metal-support interactions Spinel Water-gas shift reaction (WGS) Water-gas-shift reactions Loading Monometallic copper and nickel catalysts supported on cerium-manganese mixed oxides are prepared, characterized and evaluated for the Water-Gas Shift (WGS) reaction. Active metal loading of 2.5 wt% and 7.5 wt% are used to impregnate MnOx-CeO2 supports with 30% and 50% Mn:Ce molar ratio. The structure of the samples strongly depends on both the active metal employed and the manganese content in the mixed support. For both Cu and Ni samples, the best catalytic behavior is found in samples supported on the MnOx-CeO2 oxides with 30% Mn:Ce molar ratio, as a result of the presence of CuxMnyO4 spinel-type phases in the case of copper catalysts and the presence of a NiMnO3 mixed oxide with defect ilmenite structure in the case of nickel catalysts. © 2014, Hydrogen Energy Publications, LLC. Published by Elsevier Ltd. All rights reserved. JOUR info:eu-repo/semantics/openAccess http://creativecommons.org/licenses/by/2.5/ar http://hdl.handle.net/20.500.12110/paper_03603199_v39_n16_p8675_PoggioFraccari |
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Universidad de Buenos Aires |
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I-28 |
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R-134 |
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Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA) |
| topic |
Cerium Fuel cells Hydrogen purification Ilmenite Manganese Spinel Catalysts Cerium Fuel cells Ilmenite Manganese Manganese oxide Metals Water gas shift Catalytic behavior Copper and nickel catalysts Hydrogen purification Ilmenite structure Metal-support interactions Spinel Water-gas shift reaction (WGS) Water-gas-shift reactions Loading |
| spellingShingle |
Cerium Fuel cells Hydrogen purification Ilmenite Manganese Spinel Catalysts Cerium Fuel cells Ilmenite Manganese Manganese oxide Metals Water gas shift Catalytic behavior Copper and nickel catalysts Hydrogen purification Ilmenite structure Metal-support interactions Spinel Water-gas shift reaction (WGS) Water-gas-shift reactions Loading Poggio-Fraccari, E. Sambeth, J. Baronetti, G. Mariño, F. Cu/MnOx-CeO2 and Ni/MnOx-CeO2 catalysts for the water-gas shift reaction: Metal-support interaction |
| topic_facet |
Cerium Fuel cells Hydrogen purification Ilmenite Manganese Spinel Catalysts Cerium Fuel cells Ilmenite Manganese Manganese oxide Metals Water gas shift Catalytic behavior Copper and nickel catalysts Hydrogen purification Ilmenite structure Metal-support interactions Spinel Water-gas shift reaction (WGS) Water-gas-shift reactions Loading |
| description |
Monometallic copper and nickel catalysts supported on cerium-manganese mixed oxides are prepared, characterized and evaluated for the Water-Gas Shift (WGS) reaction. Active metal loading of 2.5 wt% and 7.5 wt% are used to impregnate MnOx-CeO2 supports with 30% and 50% Mn:Ce molar ratio. The structure of the samples strongly depends on both the active metal employed and the manganese content in the mixed support. For both Cu and Ni samples, the best catalytic behavior is found in samples supported on the MnOx-CeO2 oxides with 30% Mn:Ce molar ratio, as a result of the presence of CuxMnyO4 spinel-type phases in the case of copper catalysts and the presence of a NiMnO3 mixed oxide with defect ilmenite structure in the case of nickel catalysts. © 2014, Hydrogen Energy Publications, LLC. Published by Elsevier Ltd. All rights reserved. |
| format |
JOUR |
| author |
Poggio-Fraccari, E. Sambeth, J. Baronetti, G. Mariño, F. |
| author_facet |
Poggio-Fraccari, E. Sambeth, J. Baronetti, G. Mariño, F. |
| author_sort |
Poggio-Fraccari, E. |
| title |
Cu/MnOx-CeO2 and Ni/MnOx-CeO2 catalysts for the water-gas shift reaction: Metal-support interaction |
| title_short |
Cu/MnOx-CeO2 and Ni/MnOx-CeO2 catalysts for the water-gas shift reaction: Metal-support interaction |
| title_full |
Cu/MnOx-CeO2 and Ni/MnOx-CeO2 catalysts for the water-gas shift reaction: Metal-support interaction |
| title_fullStr |
Cu/MnOx-CeO2 and Ni/MnOx-CeO2 catalysts for the water-gas shift reaction: Metal-support interaction |
| title_full_unstemmed |
Cu/MnOx-CeO2 and Ni/MnOx-CeO2 catalysts for the water-gas shift reaction: Metal-support interaction |
| title_sort |
cu/mnox-ceo2 and ni/mnox-ceo2 catalysts for the water-gas shift reaction: metal-support interaction |
| url |
http://hdl.handle.net/20.500.12110/paper_03603199_v39_n16_p8675_PoggioFraccari |
| work_keys_str_mv |
AT poggiofraccarie cumnoxceo2andnimnoxceo2catalystsforthewatergasshiftreactionmetalsupportinteraction AT sambethj cumnoxceo2andnimnoxceo2catalystsforthewatergasshiftreactionmetalsupportinteraction AT baronettig cumnoxceo2andnimnoxceo2catalystsforthewatergasshiftreactionmetalsupportinteraction AT marinof cumnoxceo2andnimnoxceo2catalystsforthewatergasshiftreactionmetalsupportinteraction |
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1782025692220751872 |