Hydrogen isotope systematics of hair: Archeological and forensic applications

The hydrogen isotope systematics of hair have been explored and several applications demonstrate the type of information that can be recovered from archeological and forensic hair samples. Experiment with modern hair demonstrate that sources of protein-based hydrogen in keratin are food and water. O...

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Autores principales: Sharp, Z.D., Atudorei, V., Panarello, H.O., Fernández, J., Douthitt, C.
Formato: JOUR
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Acceso en línea:http://hdl.handle.net/20.500.12110/paper_03054403_v30_n12_p1709_Sharp
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spelling todo:paper_03054403_v30_n12_p1709_Sharp2023-10-03T15:21:41Z Hydrogen isotope systematics of hair: Archeological and forensic applications Sharp, Z.D. Atudorei, V. Panarello, H.O. Fernández, J. Douthitt, C. Anconcagua Fractionation Hair Hydrogen Inca mummy Isotopes Wooly mammoth archaeology hair hydrogen isotope The hydrogen isotope systematics of hair have been explored and several applications demonstrate the type of information that can be recovered from archeological and forensic hair samples. Experiment with modern hair demonstrate that sources of protein-based hydrogen in keratin are food and water. On the basis of a deuterium-enriched drinking study, it was found that ∼ 31% of hydrogen in human hair is derived from ingested water. At least 9% of total hydrogen in human hair is isotopically exchangeable with water or water vapor at 25 °C. Nearly complete exchange occurs in a matter of hours. The δD value of body water is approximately 17 ± 10‰ (n=7) more negative than human hair, although there is much scatter in data for modern hair, which is clearly related to variability of the isotopic composition of ingested food and water. Archeological hair samples were analyzed from (i) a 370 year old Incan mummy sacrificed at 5300 m altitude in Argentina (Geoarchaeology 14 (1999) 27) and (ii) from a Woolly Mammoth from Siberia. High spatial resolution data along the length of hair from the mummy indicate seasonal variations in carbon, nitrogen and hydrogen isotope ratios. No hydrogen isotope anomalies are seen in the youngest hair at the base of the scalp, indicating that the individual probably lived at ∼ 1600 m, and spent less than a week at high altitudes before death. The mammoth also preserves a seasonal signal, suggesting hair growth rates of ∼ 33 cm/year, faster than human hair, but slower than horse tail hair. The limited isotopic range across seasons for the mammoth is consistent with a north-south migration on the order of 1000 km. © 2003 Elsevier Ltd. All rights reserved. JOUR info:eu-repo/semantics/openAccess http://creativecommons.org/licenses/by/2.5/ar http://hdl.handle.net/20.500.12110/paper_03054403_v30_n12_p1709_Sharp
institution Universidad de Buenos Aires
institution_str I-28
repository_str R-134
collection Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA)
topic Anconcagua
Fractionation
Hair
Hydrogen
Inca mummy
Isotopes
Wooly mammoth
archaeology
hair
hydrogen isotope
spellingShingle Anconcagua
Fractionation
Hair
Hydrogen
Inca mummy
Isotopes
Wooly mammoth
archaeology
hair
hydrogen isotope
Sharp, Z.D.
Atudorei, V.
Panarello, H.O.
Fernández, J.
Douthitt, C.
Hydrogen isotope systematics of hair: Archeological and forensic applications
topic_facet Anconcagua
Fractionation
Hair
Hydrogen
Inca mummy
Isotopes
Wooly mammoth
archaeology
hair
hydrogen isotope
description The hydrogen isotope systematics of hair have been explored and several applications demonstrate the type of information that can be recovered from archeological and forensic hair samples. Experiment with modern hair demonstrate that sources of protein-based hydrogen in keratin are food and water. On the basis of a deuterium-enriched drinking study, it was found that ∼ 31% of hydrogen in human hair is derived from ingested water. At least 9% of total hydrogen in human hair is isotopically exchangeable with water or water vapor at 25 °C. Nearly complete exchange occurs in a matter of hours. The δD value of body water is approximately 17 ± 10‰ (n=7) more negative than human hair, although there is much scatter in data for modern hair, which is clearly related to variability of the isotopic composition of ingested food and water. Archeological hair samples were analyzed from (i) a 370 year old Incan mummy sacrificed at 5300 m altitude in Argentina (Geoarchaeology 14 (1999) 27) and (ii) from a Woolly Mammoth from Siberia. High spatial resolution data along the length of hair from the mummy indicate seasonal variations in carbon, nitrogen and hydrogen isotope ratios. No hydrogen isotope anomalies are seen in the youngest hair at the base of the scalp, indicating that the individual probably lived at ∼ 1600 m, and spent less than a week at high altitudes before death. The mammoth also preserves a seasonal signal, suggesting hair growth rates of ∼ 33 cm/year, faster than human hair, but slower than horse tail hair. The limited isotopic range across seasons for the mammoth is consistent with a north-south migration on the order of 1000 km. © 2003 Elsevier Ltd. All rights reserved.
format JOUR
author Sharp, Z.D.
Atudorei, V.
Panarello, H.O.
Fernández, J.
Douthitt, C.
author_facet Sharp, Z.D.
Atudorei, V.
Panarello, H.O.
Fernández, J.
Douthitt, C.
author_sort Sharp, Z.D.
title Hydrogen isotope systematics of hair: Archeological and forensic applications
title_short Hydrogen isotope systematics of hair: Archeological and forensic applications
title_full Hydrogen isotope systematics of hair: Archeological and forensic applications
title_fullStr Hydrogen isotope systematics of hair: Archeological and forensic applications
title_full_unstemmed Hydrogen isotope systematics of hair: Archeological and forensic applications
title_sort hydrogen isotope systematics of hair: archeological and forensic applications
url http://hdl.handle.net/20.500.12110/paper_03054403_v30_n12_p1709_Sharp
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AT panarelloho hydrogenisotopesystematicsofhairarcheologicalandforensicapplications
AT fernandezj hydrogenisotopesystematicsofhairarcheologicalandforensicapplications
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