Synthesis and characterization of zinc(II) oxydiacetate (oda) complexes. Crystal structures of [{Zn(oda)·0.3H2O}n], [Zn(oda)(bipy)(H2O)]·2.5H2O and [Zn(oda)(phen)(H2O)]·1.5H2O (bipy = 2,2′-bipyridine, phen = 1,10-phenanthroline)

Three novel zinc(II) oxydiacetate (oda) compounds [{Zn(oda)·0.3H2O}n] 1, [Zn(oda)(bipy)(H2O)]·2.5H2O 2 (bipy = 2,2′-bipyridine) and [Zn(oda)(phen)(H2O)]·1.5H2O 3 (phen = 1,10-phenanthroline) have been synthesized and their structures determined by single-crystal X-ray diffraction methods. Compound 1...

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Detalles Bibliográficos
Autores principales:	Baggio, R., Garland, M.T., Perec, M.
Formato:	JOUR
Acceso en línea:	http://hdl.handle.net/20.500.12110/paper_03009246_v_n13_p2747_Baggio
Aporte de:	Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA) de Universidad de Buenos Aires

id	todo:paper_03009246_v_n13_p2747_Baggio
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spelling	todo:paper_03009246_v_n13_p2747_Baggio2023-10-03T15:17:57Z Synthesis and characterization of zinc(II) oxydiacetate (oda) complexes. Crystal structures of [{Zn(oda)·0.3H2O}n], [Zn(oda)(bipy)(H2O)]·2.5H2O and [Zn(oda)(phen)(H2O)]·1.5H2O (bipy = 2,2′-bipyridine, phen = 1,10-phenanthroline) Baggio, R. Garland, M.T. Perec, M. Three novel zinc(II) oxydiacetate (oda) compounds [{Zn(oda)·0.3H2O}n] 1, [Zn(oda)(bipy)(H2O)]·2.5H2O 2 (bipy = 2,2′-bipyridine) and [Zn(oda)(phen)(H2O)]·1.5H2O 3 (phen = 1,10-phenanthroline) have been synthesized and their structures determined by single-crystal X-ray diffraction methods. Compound 1 consists of polymeric sheets formed by ZnO5 units bridged by carboxylate groups in anti-syn conformation along the z axis; 2 and 3 are mononuclear with the zinc atoms in distorted octahedral ZnN2O4 co-ordination geometries. Thermal decomposition of the compounds under an oxygen atmosphere affords ZnO at ca. 500°C. Fil:Baggio, R. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. Fil:Perec, M. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. JOUR info:eu-repo/semantics/openAccess http://creativecommons.org/licenses/by/2.5/ar http://hdl.handle.net/20.500.12110/paper_03009246_v_n13_p2747_Baggio
institution	Universidad de Buenos Aires
institution_str	I-28
repository_str	R-134
collection	Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA)
description	Three novel zinc(II) oxydiacetate (oda) compounds [{Zn(oda)·0.3H2O}n] 1, [Zn(oda)(bipy)(H2O)]·2.5H2O 2 (bipy = 2,2′-bipyridine) and [Zn(oda)(phen)(H2O)]·1.5H2O 3 (phen = 1,10-phenanthroline) have been synthesized and their structures determined by single-crystal X-ray diffraction methods. Compound 1 consists of polymeric sheets formed by ZnO5 units bridged by carboxylate groups in anti-syn conformation along the z axis; 2 and 3 are mononuclear with the zinc atoms in distorted octahedral ZnN2O4 co-ordination geometries. Thermal decomposition of the compounds under an oxygen atmosphere affords ZnO at ca. 500°C.
format	JOUR
author	Baggio, R. Garland, M.T. Perec, M.
spellingShingle	Baggio, R. Garland, M.T. Perec, M. Synthesis and characterization of zinc(II) oxydiacetate (oda) complexes. Crystal structures of [{Zn(oda)·0.3H2O}n], [Zn(oda)(bipy)(H2O)]·2.5H2O and [Zn(oda)(phen)(H2O)]·1.5H2O (bipy = 2,2′-bipyridine, phen = 1,10-phenanthroline)
author_facet	Baggio, R. Garland, M.T. Perec, M.
author_sort	Baggio, R.
title	Synthesis and characterization of zinc(II) oxydiacetate (oda) complexes. Crystal structures of [{Zn(oda)·0.3H2O}n], [Zn(oda)(bipy)(H2O)]·2.5H2O and [Zn(oda)(phen)(H2O)]·1.5H2O (bipy = 2,2′-bipyridine, phen = 1,10-phenanthroline)
title_short	Synthesis and characterization of zinc(II) oxydiacetate (oda) complexes. Crystal structures of [{Zn(oda)·0.3H2O}n], [Zn(oda)(bipy)(H2O)]·2.5H2O and [Zn(oda)(phen)(H2O)]·1.5H2O (bipy = 2,2′-bipyridine, phen = 1,10-phenanthroline)
title_full	Synthesis and characterization of zinc(II) oxydiacetate (oda) complexes. Crystal structures of [{Zn(oda)·0.3H2O}n], [Zn(oda)(bipy)(H2O)]·2.5H2O and [Zn(oda)(phen)(H2O)]·1.5H2O (bipy = 2,2′-bipyridine, phen = 1,10-phenanthroline)
title_fullStr	Synthesis and characterization of zinc(II) oxydiacetate (oda) complexes. Crystal structures of [{Zn(oda)·0.3H2O}n], [Zn(oda)(bipy)(H2O)]·2.5H2O and [Zn(oda)(phen)(H2O)]·1.5H2O (bipy = 2,2′-bipyridine, phen = 1,10-phenanthroline)
title_full_unstemmed	Synthesis and characterization of zinc(II) oxydiacetate (oda) complexes. Crystal structures of [{Zn(oda)·0.3H2O}n], [Zn(oda)(bipy)(H2O)]·2.5H2O and [Zn(oda)(phen)(H2O)]·1.5H2O (bipy = 2,2′-bipyridine, phen = 1,10-phenanthroline)
title_sort	synthesis and characterization of zinc(ii) oxydiacetate (oda) complexes. crystal structures of [{zn(oda)·0.3h2o}n], [zn(oda)(bipy)(h2o)]·2.5h2o and [zn(oda)(phen)(h2o)]·1.5h2o (bipy = 2,2′-bipyridine, phen = 1,10-phenanthroline)
url	http://hdl.handle.net/20.500.12110/paper_03009246_v_n13_p2747_Baggio
work_keys_str_mv	AT baggior synthesisandcharacterizationofzinciioxydiacetateodacomplexescrystalstructuresofznoda03h2onznodabipyh2o25h2oandznodaphenh2o15h2obipy22bipyridinephen110phenanthroline AT garlandmt synthesisandcharacterizationofzinciioxydiacetateodacomplexescrystalstructuresofznoda03h2onznodabipyh2o25h2oandznodaphenh2o15h2obipy22bipyridinephen110phenanthroline AT perecm synthesisandcharacterizationofzinciioxydiacetateodacomplexescrystalstructuresofznoda03h2onznodabipyh2o25h2oandznodaphenh2o15h2obipy22bipyridinephen110phenanthroline
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Synthesis and characterization of zinc(II) oxydiacetate (oda) complexes. Crystal structures of [{Zn(oda)·0.3H2O}n], [Zn(oda)(bipy)(H2O)]·2.5H2O and [Zn(oda)(phen)(H2O)]·1.5H2O (bipy = 2,2′-bipyridine, phen = 1,10-phenanthroline)

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