Synthesis, structure, and reactivity of aliphatic primary nitrosamines stabilized by coordination to [IrCI5]2-
In the present work the formation of several primary aliphatic coordinated nitrosamines by reaction of the extremely reactive K[IrCl5(NO)] in acetonitrile solution with the corresponding amine is described. Complete characterization, including X-ray diffraction determinations for some examples, are...
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| Formato: | JOUR |
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| Acceso en línea: | http://hdl.handle.net/20.500.12110/paper_02767333_v27_n9_p1985_DiSalvo |
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todo:paper_02767333_v27_n9_p1985_DiSalvo2023-10-03T15:16:00Z Synthesis, structure, and reactivity of aliphatic primary nitrosamines stabilized by coordination to [IrCI5]2- Di Salvo, F. Estrin, D.A. Leitus, G. Doctorovich, F. Acetonitrile Chemical reactivity Coordination reactions Iridium compounds Ligands Synthesis (chemical) X ray diffraction Aliphatic coordinated nitrosamines Primary nitrosamines Amines In the present work the formation of several primary aliphatic coordinated nitrosamines by reaction of the extremely reactive K[IrCl5(NO)] in acetonitrile solution with the corresponding amine is described. Complete characterization, including X-ray diffraction determinations for some examples, are reported, and experimental evidence of their stability. Density functional theory calculations (DFT) helped to understand the role of the coordination environment of these complexes and to support, with excellent correlation with the experimental data, the proposed reaction pathways and stability studies. Complexes containing the highly unstable primary nitrosamines as ligands are generally scarce, and moreover, to our knowledge, our group has recently reported the first examples of isolated primary nitrosamines coordinated to the metal center only through the NO moiety. © 2008 American Chemical Society. Fil:Di Salvo, F. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. Fil:Estrin, D.A. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. Fil:Doctorovich, F. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. JOUR info:eu-repo/semantics/openAccess http://creativecommons.org/licenses/by/2.5/ar http://hdl.handle.net/20.500.12110/paper_02767333_v27_n9_p1985_DiSalvo |
| institution |
Universidad de Buenos Aires |
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I-28 |
| repository_str |
R-134 |
| collection |
Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA) |
| topic |
Acetonitrile Chemical reactivity Coordination reactions Iridium compounds Ligands Synthesis (chemical) X ray diffraction Aliphatic coordinated nitrosamines Primary nitrosamines Amines |
| spellingShingle |
Acetonitrile Chemical reactivity Coordination reactions Iridium compounds Ligands Synthesis (chemical) X ray diffraction Aliphatic coordinated nitrosamines Primary nitrosamines Amines Di Salvo, F. Estrin, D.A. Leitus, G. Doctorovich, F. Synthesis, structure, and reactivity of aliphatic primary nitrosamines stabilized by coordination to [IrCI5]2- |
| topic_facet |
Acetonitrile Chemical reactivity Coordination reactions Iridium compounds Ligands Synthesis (chemical) X ray diffraction Aliphatic coordinated nitrosamines Primary nitrosamines Amines |
| description |
In the present work the formation of several primary aliphatic coordinated nitrosamines by reaction of the extremely reactive K[IrCl5(NO)] in acetonitrile solution with the corresponding amine is described. Complete characterization, including X-ray diffraction determinations for some examples, are reported, and experimental evidence of their stability. Density functional theory calculations (DFT) helped to understand the role of the coordination environment of these complexes and to support, with excellent correlation with the experimental data, the proposed reaction pathways and stability studies. Complexes containing the highly unstable primary nitrosamines as ligands are generally scarce, and moreover, to our knowledge, our group has recently reported the first examples of isolated primary nitrosamines coordinated to the metal center only through the NO moiety. © 2008 American Chemical Society. |
| format |
JOUR |
| author |
Di Salvo, F. Estrin, D.A. Leitus, G. Doctorovich, F. |
| author_facet |
Di Salvo, F. Estrin, D.A. Leitus, G. Doctorovich, F. |
| author_sort |
Di Salvo, F. |
| title |
Synthesis, structure, and reactivity of aliphatic primary nitrosamines stabilized by coordination to [IrCI5]2- |
| title_short |
Synthesis, structure, and reactivity of aliphatic primary nitrosamines stabilized by coordination to [IrCI5]2- |
| title_full |
Synthesis, structure, and reactivity of aliphatic primary nitrosamines stabilized by coordination to [IrCI5]2- |
| title_fullStr |
Synthesis, structure, and reactivity of aliphatic primary nitrosamines stabilized by coordination to [IrCI5]2- |
| title_full_unstemmed |
Synthesis, structure, and reactivity of aliphatic primary nitrosamines stabilized by coordination to [IrCI5]2- |
| title_sort |
synthesis, structure, and reactivity of aliphatic primary nitrosamines stabilized by coordination to [irci5]2- |
| url |
http://hdl.handle.net/20.500.12110/paper_02767333_v27_n9_p1985_DiSalvo |
| work_keys_str_mv |
AT disalvof synthesisstructureandreactivityofaliphaticprimarynitrosaminesstabilizedbycoordinationtoirci52 AT estrinda synthesisstructureandreactivityofaliphaticprimarynitrosaminesstabilizedbycoordinationtoirci52 AT leitusg synthesisstructureandreactivityofaliphaticprimarynitrosaminesstabilizedbycoordinationtoirci52 AT doctorovichf synthesisstructureandreactivityofaliphaticprimarynitrosaminesstabilizedbycoordinationtoirci52 |
| _version_ |
1807323946584899584 |