Enhanced electrochemical oxidation of methanol on copper electrodes modified by electrocorrosion and electrodeposition

In this paper, we report a study of electrocatalytic oxidation of methanol on copper electrodes subjected to different surface treatments, either electrocorrosion or electrodeposition in the absence of strong hydrogen co-deposition. The surface morphology of treated electrodes was examined by Field...

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Detalles Bibliográficos
Autores principales: Carugno, S., Chassaing, E., Rosso, M., González, G.A.
Formato: JOUR
Materias:
Electrochemical properties
Electrochemical techniques
Microstructure
Oxidation
Surfaces
Cyclic voltammetric techniques
Effective surface area
Electro-catalytic oxidation
Field emission scanning electron microscopy
Methanol concentration
Oxidation of methanol
Surface concentration
Electrocatalysis
Electrochemical oxidation
Electrodeposition
Electrodes
Field emission microscopes
Methanol
Acceso en línea:http://hdl.handle.net/20.500.12110/paper_02540584_v143_n3_p1012_Carugno
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Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA) de Universidad de Buenos Aires
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spelling todo:paper_02540584_v143_n3_p1012_Carugno2023-10-03T15:11:30Z Enhanced electrochemical oxidation of methanol on copper electrodes modified by electrocorrosion and electrodeposition Carugno, S. Chassaing, E. Rosso, M. González, G.A. Electrochemical properties Electrochemical techniques Microstructure Oxidation Surfaces Cyclic voltammetric techniques Effective surface area Electro-catalytic oxidation Electrochemical techniques Field emission scanning electron microscopy Methanol concentration Oxidation of methanol Surface concentration Electrocatalysis Electrochemical oxidation Electrochemical properties Electrodeposition Electrodes Field emission microscopes Microstructure Oxidation Surfaces Methanol In this paper, we report a study of electrocatalytic oxidation of methanol on copper electrodes subjected to different surface treatments, either electrocorrosion or electrodeposition in the absence of strong hydrogen co-deposition. The surface morphology of treated electrodes was examined by Field Emission Scanning Electron Microscopy (FE-SEM). The effect of different treatment conditions and the methanol concentration dependence were evaluated by cyclic voltammetric technique. The results indicate that the oxidation of methanol can be enhanced by a suitable micro and nano structure generated by these treatments. This enhanced electrode activity is related to an increase of the effective surface area and/or to an increase of the surface concentration of electroactive molecules or intermediates. © 2013 Elsevier B.V. All rights reserved. Fil:González, G.A. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. JOUR info:eu-repo/semantics/openAccess http://creativecommons.org/licenses/by/2.5/ar http://hdl.handle.net/20.500.12110/paper_02540584_v143_n3_p1012_Carugno
institution Universidad de Buenos Aires
institution_str I-28
repository_str R-134
collection Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA)
topic Electrochemical properties
Electrochemical techniques
Microstructure
Oxidation
Surfaces
Cyclic voltammetric techniques
Effective surface area
Electro-catalytic oxidation
Electrochemical techniques
Field emission scanning electron microscopy
Methanol concentration
Oxidation of methanol
Surface concentration
Electrocatalysis
Electrochemical oxidation
Electrochemical properties
Electrodeposition
Electrodes
Field emission microscopes
Microstructure
Oxidation
Surfaces
Methanol
spellingShingle Electrochemical properties
Electrochemical techniques
Microstructure
Oxidation
Surfaces
Cyclic voltammetric techniques
Effective surface area
Electro-catalytic oxidation
Electrochemical techniques
Field emission scanning electron microscopy
Methanol concentration
Oxidation of methanol
Surface concentration
Electrocatalysis
Electrochemical oxidation
Electrochemical properties
Electrodeposition
Electrodes
Field emission microscopes
Microstructure
Oxidation
Surfaces
Methanol
Carugno, S.
Chassaing, E.
Rosso, M.
González, G.A.
Enhanced electrochemical oxidation of methanol on copper electrodes modified by electrocorrosion and electrodeposition
topic_facet Electrochemical properties
Electrochemical techniques
Microstructure
Oxidation
Surfaces
Cyclic voltammetric techniques
Effective surface area
Electro-catalytic oxidation
Electrochemical techniques
Field emission scanning electron microscopy
Methanol concentration
Oxidation of methanol
Surface concentration
Electrocatalysis
Electrochemical oxidation
Electrochemical properties
Electrodeposition
Electrodes
Field emission microscopes
Microstructure
Oxidation
Surfaces
Methanol
description In this paper, we report a study of electrocatalytic oxidation of methanol on copper electrodes subjected to different surface treatments, either electrocorrosion or electrodeposition in the absence of strong hydrogen co-deposition. The surface morphology of treated electrodes was examined by Field Emission Scanning Electron Microscopy (FE-SEM). The effect of different treatment conditions and the methanol concentration dependence were evaluated by cyclic voltammetric technique. The results indicate that the oxidation of methanol can be enhanced by a suitable micro and nano structure generated by these treatments. This enhanced electrode activity is related to an increase of the effective surface area and/or to an increase of the surface concentration of electroactive molecules or intermediates. © 2013 Elsevier B.V. All rights reserved.
format JOUR
author Carugno, S.
Chassaing, E.
Rosso, M.
González, G.A.
author_facet Carugno, S.
Chassaing, E.
Rosso, M.
González, G.A.
author_sort Carugno, S.
title Enhanced electrochemical oxidation of methanol on copper electrodes modified by electrocorrosion and electrodeposition
title_short Enhanced electrochemical oxidation of methanol on copper electrodes modified by electrocorrosion and electrodeposition
title_full Enhanced electrochemical oxidation of methanol on copper electrodes modified by electrocorrosion and electrodeposition
title_fullStr Enhanced electrochemical oxidation of methanol on copper electrodes modified by electrocorrosion and electrodeposition
title_full_unstemmed Enhanced electrochemical oxidation of methanol on copper electrodes modified by electrocorrosion and electrodeposition
title_sort enhanced electrochemical oxidation of methanol on copper electrodes modified by electrocorrosion and electrodeposition
url http://hdl.handle.net/20.500.12110/paper_02540584_v143_n3_p1012_Carugno
work_keys_str_mv AT carugnos enhancedelectrochemicaloxidationofmethanoloncopperelectrodesmodifiedbyelectrocorrosionandelectrodeposition
AT chassainge enhancedelectrochemicaloxidationofmethanoloncopperelectrodesmodifiedbyelectrocorrosionandelectrodeposition
AT rossom enhancedelectrochemicaloxidationofmethanoloncopperelectrodesmodifiedbyelectrocorrosionandelectrodeposition
AT gonzalezga enhancedelectrochemicaloxidationofmethanoloncopperelectrodesmodifiedbyelectrocorrosionandelectrodeposition
_version_ 1807316845101842432

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