Biological substrates: Green alternatives in trace elemental preconcentration and speciation analysis

Biological substrates have been introduced in Analytical Chemistry to encourage the development of environment-friendly methodologies. This kind of substrates offers advantages such as low cost, very simple production and biodegradability. Moreover, they are considered highly efficient materials for...

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Autores principales: Escudero, L.B., Maniero, M.Á., Agostini, E., Smichowski, P.N.
Formato: JOUR
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Acceso en línea:http://hdl.handle.net/20.500.12110/paper_01659936_v80_n_p531_Escudero
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spelling todo:paper_01659936_v80_n_p531_Escudero2023-10-03T15:03:09Z Biological substrates: Green alternatives in trace elemental preconcentration and speciation analysis Escudero, L.B. Maniero, M.Á. Agostini, E. Smichowski, P.N. Biological substrates Biosorption Metal Preconcentration Speciation Biodegradability Biological materials Biosorption Chemical analysis Metals Phase separation Substrates Trace analysis Trace elements Analytical methodology Analytical performance Biological substrates Comparison of methods On-line microextraction Pre-concentration Solid phase extraction techniques Speciation Extraction heavy metal nanomaterial nanoparticle trace element adsorption agricultural waste biomass biosorption chemical modification complex formation filamentous fungus food analysis fungus Gram negative bacterium Gram positive bacterium green chemistry heavy metal removal ion exchange metal recovery micromycete nonhuman oxidation reduction reaction plant seed precipitation priority journal Review seed husk solid phase extraction yeast Biological substrates have been introduced in Analytical Chemistry to encourage the development of environment-friendly methodologies. This kind of substrates offers advantages such as low cost, very simple production and biodegradability. Moreover, they are considered highly efficient materials for extraction and separation of elemental species.The current article reviews the applications of biological substrates in elemental preconcentration and speciation analysis, with emphasis in the latest analytical methodologies developed in this field. Batch and on-line microextraction techniques, based on biological substrates are presented and discussed. The applications of immobilized biological substrates are also commented in this work. Special attention is given to the novel immobilization of these substrates on nanomaterials and nanoparticles to develop solid phase extraction techniques. A comparison of methods using biological substrates in terms of analytical performance is provided. Finally, future trends, developments and challenges related to the use of biological substrates for trace metal determination are discussed. © 2016 Elsevier B.V. JOUR info:eu-repo/semantics/openAccess http://creativecommons.org/licenses/by/2.5/ar http://hdl.handle.net/20.500.12110/paper_01659936_v80_n_p531_Escudero
institution Universidad de Buenos Aires
institution_str I-28
repository_str R-134
collection Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA)
topic Biological substrates
Biosorption
Metal
Preconcentration
Speciation
Biodegradability
Biological materials
Biosorption
Chemical analysis
Metals
Phase separation
Substrates
Trace analysis
Trace elements
Analytical methodology
Analytical performance
Biological substrates
Comparison of methods
On-line microextraction
Pre-concentration
Solid phase extraction techniques
Speciation
Extraction
heavy metal
nanomaterial
nanoparticle
trace element
adsorption
agricultural waste
biomass
biosorption
chemical modification
complex formation
filamentous fungus
food analysis
fungus
Gram negative bacterium
Gram positive bacterium
green chemistry
heavy metal removal
ion exchange
metal recovery
micromycete
nonhuman
oxidation reduction reaction
plant seed
precipitation
priority journal
Review
seed husk
solid phase extraction
yeast
spellingShingle Biological substrates
Biosorption
Metal
Preconcentration
Speciation
Biodegradability
Biological materials
Biosorption
Chemical analysis
Metals
Phase separation
Substrates
Trace analysis
Trace elements
Analytical methodology
Analytical performance
Biological substrates
Comparison of methods
On-line microextraction
Pre-concentration
Solid phase extraction techniques
Speciation
Extraction
heavy metal
nanomaterial
nanoparticle
trace element
adsorption
agricultural waste
biomass
biosorption
chemical modification
complex formation
filamentous fungus
food analysis
fungus
Gram negative bacterium
Gram positive bacterium
green chemistry
heavy metal removal
ion exchange
metal recovery
micromycete
nonhuman
oxidation reduction reaction
plant seed
precipitation
priority journal
Review
seed husk
solid phase extraction
yeast
Escudero, L.B.
Maniero, M.Á.
Agostini, E.
Smichowski, P.N.
Biological substrates: Green alternatives in trace elemental preconcentration and speciation analysis
topic_facet Biological substrates
Biosorption
Metal
Preconcentration
Speciation
Biodegradability
Biological materials
Biosorption
Chemical analysis
Metals
Phase separation
Substrates
Trace analysis
Trace elements
Analytical methodology
Analytical performance
Biological substrates
Comparison of methods
On-line microextraction
Pre-concentration
Solid phase extraction techniques
Speciation
Extraction
heavy metal
nanomaterial
nanoparticle
trace element
adsorption
agricultural waste
biomass
biosorption
chemical modification
complex formation
filamentous fungus
food analysis
fungus
Gram negative bacterium
Gram positive bacterium
green chemistry
heavy metal removal
ion exchange
metal recovery
micromycete
nonhuman
oxidation reduction reaction
plant seed
precipitation
priority journal
Review
seed husk
solid phase extraction
yeast
description Biological substrates have been introduced in Analytical Chemistry to encourage the development of environment-friendly methodologies. This kind of substrates offers advantages such as low cost, very simple production and biodegradability. Moreover, they are considered highly efficient materials for extraction and separation of elemental species.The current article reviews the applications of biological substrates in elemental preconcentration and speciation analysis, with emphasis in the latest analytical methodologies developed in this field. Batch and on-line microextraction techniques, based on biological substrates are presented and discussed. The applications of immobilized biological substrates are also commented in this work. Special attention is given to the novel immobilization of these substrates on nanomaterials and nanoparticles to develop solid phase extraction techniques. A comparison of methods using biological substrates in terms of analytical performance is provided. Finally, future trends, developments and challenges related to the use of biological substrates for trace metal determination are discussed. © 2016 Elsevier B.V.
format JOUR
author Escudero, L.B.
Maniero, M.Á.
Agostini, E.
Smichowski, P.N.
author_facet Escudero, L.B.
Maniero, M.Á.
Agostini, E.
Smichowski, P.N.
author_sort Escudero, L.B.
title Biological substrates: Green alternatives in trace elemental preconcentration and speciation analysis
title_short Biological substrates: Green alternatives in trace elemental preconcentration and speciation analysis
title_full Biological substrates: Green alternatives in trace elemental preconcentration and speciation analysis
title_fullStr Biological substrates: Green alternatives in trace elemental preconcentration and speciation analysis
title_full_unstemmed Biological substrates: Green alternatives in trace elemental preconcentration and speciation analysis
title_sort biological substrates: green alternatives in trace elemental preconcentration and speciation analysis
url http://hdl.handle.net/20.500.12110/paper_01659936_v80_n_p531_Escudero
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AT manieroma biologicalsubstratesgreenalternativesintraceelementalpreconcentrationandspeciationanalysis
AT agostinie biologicalsubstratesgreenalternativesintraceelementalpreconcentrationandspeciationanalysis
AT smichowskipn biologicalsubstratesgreenalternativesintraceelementalpreconcentrationandspeciationanalysis
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