Withanolides with phytotoxic activity from two species of the genus salpichroa: S. origanifolia and s. tristis var. lehmannii
Seven new withanolides, salpichrolides O-U (1-7), the known 2,3-dihydrosalpichrolide B (9), a substance not previously isolated from a natural source, and three known compounds, salpichrolide D (8), salpichrolide A (10), and salpichrolide C (11), were isolated and characterized from the aerial parts...
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todo:paper_01633864_v76_n12_p2219_Nicotra2023-10-03T15:02:17Z Withanolides with phytotoxic activity from two species of the genus salpichroa: S. origanifolia and s. tristis var. lehmannii Nicotra, V.E. Basso, A.V. Ramacciotti, N.S. Misico, R.I. 2,3 dihydrosalpichrolide b salpichrolide a salpichrolide c salpichrolide o salpichrolide p salpichrolide q salpichrolide r salpichrolide s salpichrolide t salpichrolide u unclassified drug withanolide article lettuce mass spectrometry nuclear magnetic resonance spectroscopy oat phytotoxicity plant Salpichroa origanifolia Salpichroa tristis var. lehmannii Argentina Ergosterol Molecular Structure Solanaceae Withanolides Seven new withanolides, salpichrolides O-U (1-7), the known 2,3-dihydrosalpichrolide B (9), a substance not previously isolated from a natural source, and three known compounds, salpichrolide D (8), salpichrolide A (10), and salpichrolide C (11), were isolated and characterized from the aerial parts of Salpichroa origanifolia and S. tristis var. lehmannii. Compounds 1-4 and 8 have an oxygenated D ring, while compounds 5-7 and 9-11 possess a six-membered aromatic D ring. The structures of the isolated compounds were identified by analysis of their spectroscopic data including NMR and MS. Withanolides 1, 3, 8, 10, and 11 exhibited selective radicle growth inhibition toward Lactuca sativa (lettuce) at 150 and 400 ppm. © 2013 The American Chemical Society and American Society of Pharmacognosy. JOUR info:eu-repo/semantics/openAccess http://creativecommons.org/licenses/by/2.5/ar http://hdl.handle.net/20.500.12110/paper_01633864_v76_n12_p2219_Nicotra |
institution |
Universidad de Buenos Aires |
institution_str |
I-28 |
repository_str |
R-134 |
collection |
Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA) |
topic |
2,3 dihydrosalpichrolide b salpichrolide a salpichrolide c salpichrolide o salpichrolide p salpichrolide q salpichrolide r salpichrolide s salpichrolide t salpichrolide u unclassified drug withanolide article lettuce mass spectrometry nuclear magnetic resonance spectroscopy oat phytotoxicity plant Salpichroa origanifolia Salpichroa tristis var. lehmannii Argentina Ergosterol Molecular Structure Solanaceae Withanolides |
spellingShingle |
2,3 dihydrosalpichrolide b salpichrolide a salpichrolide c salpichrolide o salpichrolide p salpichrolide q salpichrolide r salpichrolide s salpichrolide t salpichrolide u unclassified drug withanolide article lettuce mass spectrometry nuclear magnetic resonance spectroscopy oat phytotoxicity plant Salpichroa origanifolia Salpichroa tristis var. lehmannii Argentina Ergosterol Molecular Structure Solanaceae Withanolides Nicotra, V.E. Basso, A.V. Ramacciotti, N.S. Misico, R.I. Withanolides with phytotoxic activity from two species of the genus salpichroa: S. origanifolia and s. tristis var. lehmannii |
topic_facet |
2,3 dihydrosalpichrolide b salpichrolide a salpichrolide c salpichrolide o salpichrolide p salpichrolide q salpichrolide r salpichrolide s salpichrolide t salpichrolide u unclassified drug withanolide article lettuce mass spectrometry nuclear magnetic resonance spectroscopy oat phytotoxicity plant Salpichroa origanifolia Salpichroa tristis var. lehmannii Argentina Ergosterol Molecular Structure Solanaceae Withanolides |
description |
Seven new withanolides, salpichrolides O-U (1-7), the known 2,3-dihydrosalpichrolide B (9), a substance not previously isolated from a natural source, and three known compounds, salpichrolide D (8), salpichrolide A (10), and salpichrolide C (11), were isolated and characterized from the aerial parts of Salpichroa origanifolia and S. tristis var. lehmannii. Compounds 1-4 and 8 have an oxygenated D ring, while compounds 5-7 and 9-11 possess a six-membered aromatic D ring. The structures of the isolated compounds were identified by analysis of their spectroscopic data including NMR and MS. Withanolides 1, 3, 8, 10, and 11 exhibited selective radicle growth inhibition toward Lactuca sativa (lettuce) at 150 and 400 ppm. © 2013 The American Chemical Society and American Society of Pharmacognosy. |
format |
JOUR |
author |
Nicotra, V.E. Basso, A.V. Ramacciotti, N.S. Misico, R.I. |
author_facet |
Nicotra, V.E. Basso, A.V. Ramacciotti, N.S. Misico, R.I. |
author_sort |
Nicotra, V.E. |
title |
Withanolides with phytotoxic activity from two species of the genus salpichroa: S. origanifolia and s. tristis var. lehmannii |
title_short |
Withanolides with phytotoxic activity from two species of the genus salpichroa: S. origanifolia and s. tristis var. lehmannii |
title_full |
Withanolides with phytotoxic activity from two species of the genus salpichroa: S. origanifolia and s. tristis var. lehmannii |
title_fullStr |
Withanolides with phytotoxic activity from two species of the genus salpichroa: S. origanifolia and s. tristis var. lehmannii |
title_full_unstemmed |
Withanolides with phytotoxic activity from two species of the genus salpichroa: S. origanifolia and s. tristis var. lehmannii |
title_sort |
withanolides with phytotoxic activity from two species of the genus salpichroa: s. origanifolia and s. tristis var. lehmannii |
url |
http://hdl.handle.net/20.500.12110/paper_01633864_v76_n12_p2219_Nicotra |
work_keys_str_mv |
AT nicotrave withanolideswithphytotoxicactivityfromtwospeciesofthegenussalpichroasoriganifoliaandstristisvarlehmannii AT bassoav withanolideswithphytotoxicactivityfromtwospeciesofthegenussalpichroasoriganifoliaandstristisvarlehmannii AT ramacciottins withanolideswithphytotoxicactivityfromtwospeciesofthegenussalpichroasoriganifoliaandstristisvarlehmannii AT misicori withanolideswithphytotoxicactivityfromtwospeciesofthegenussalpichroasoriganifoliaandstristisvarlehmannii |
_version_ |
1807315587847684096 |