N-Butylpyridinium undecachlorocarbadodecaborate and comparison with similar compounds

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The title compound, C 9H 14N +· CHB 11Cl 11 -, was obtained in the course of our continuing studies of the low-melting salts of closo- and nido-carborane cage anions with alkyl-pyridinium and dialkyl-imidazolium cations. The title compound is the first example of a pyridinium salt of a perchlorinate...

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Autores principales: Suarez, S.A., Foi, A., Eady, S., Larsen, A., Doctorovich, F.
Formato: JOUR
Materias:
Asymmetric unit
Carborane anions
Carborane cages
Counterions
Pyridinium salts
Title compounds
Positive ions
Negative ions
Acceso en línea:http://hdl.handle.net/20.500.12110/paper_01082701_v67_n10_po417_Suarez
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Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA) de Universidad de Buenos Aires
id todo:paper_01082701_v67_n10_po417_Suarez
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spelling todo:paper_01082701_v67_n10_po417_Suarez2023-10-03T14:57:54Z N-Butylpyridinium undecachlorocarbadodecaborate and comparison with similar compounds Suarez, S.A. Foi, A. Eady, S. Larsen, A. Doctorovich, F. Asymmetric unit Carborane anions Carborane cages Counterions Pyridinium salts Title compounds Positive ions Negative ions The title compound, C 9H 14N +· CHB 11Cl 11 -, was obtained in the course of our continuing studies of the low-melting salts of closo- and nido-carborane cage anions with alkyl-pyridinium and dialkyl-imidazolium cations. The title compound is the first example of a pyridinium salt of a perchlorinated carborane anion. The structure consists of one N-butyl-pyridinium cation counterbalanced by one perchlorinated carborane cage anion per asymmetric unit. By changing the counter-ion, different packings are observed, and to try to understand this the new structure is compared with five similar compounds. © 2011 International Union of Crystallography. Fil:Suarez, S.A. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. Fil:Doctorovich, F. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. JOUR info:eu-repo/semantics/openAccess http://creativecommons.org/licenses/by/2.5/ar http://hdl.handle.net/20.500.12110/paper_01082701_v67_n10_po417_Suarez
institution Universidad de Buenos Aires
institution_str I-28
repository_str R-134
collection Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA)
topic Asymmetric unit
Carborane anions
Carborane cages
Counterions
Pyridinium salts
Title compounds
Positive ions
Negative ions
spellingShingle Asymmetric unit
Carborane anions
Carborane cages
Counterions
Pyridinium salts
Title compounds
Positive ions
Negative ions
Suarez, S.A.
Foi, A.
Eady, S.
Larsen, A.
Doctorovich, F.
N-Butylpyridinium undecachlorocarbadodecaborate and comparison with similar compounds
topic_facet Asymmetric unit
Carborane anions
Carborane cages
Counterions
Pyridinium salts
Title compounds
Positive ions
Negative ions
description The title compound, C 9H 14N +· CHB 11Cl 11 -, was obtained in the course of our continuing studies of the low-melting salts of closo- and nido-carborane cage anions with alkyl-pyridinium and dialkyl-imidazolium cations. The title compound is the first example of a pyridinium salt of a perchlorinated carborane anion. The structure consists of one N-butyl-pyridinium cation counterbalanced by one perchlorinated carborane cage anion per asymmetric unit. By changing the counter-ion, different packings are observed, and to try to understand this the new structure is compared with five similar compounds. © 2011 International Union of Crystallography.
format JOUR
author Suarez, S.A.
Foi, A.
Eady, S.
Larsen, A.
Doctorovich, F.
author_facet Suarez, S.A.
Foi, A.
Eady, S.
Larsen, A.
Doctorovich, F.
author_sort Suarez, S.A.
title N-Butylpyridinium undecachlorocarbadodecaborate and comparison with similar compounds
title_short N-Butylpyridinium undecachlorocarbadodecaborate and comparison with similar compounds
title_full N-Butylpyridinium undecachlorocarbadodecaborate and comparison with similar compounds
title_fullStr N-Butylpyridinium undecachlorocarbadodecaborate and comparison with similar compounds
title_full_unstemmed N-Butylpyridinium undecachlorocarbadodecaborate and comparison with similar compounds
title_sort n-butylpyridinium undecachlorocarbadodecaborate and comparison with similar compounds
url http://hdl.handle.net/20.500.12110/paper_01082701_v67_n10_po417_Suarez
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