4'-[2-(2-Ethoxy-ethoxy)eth-oxy]-bi-phenyl-4-carboxylic acid: Correlation between its crystalline and smectic phases

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The crystal structure of the dimeric title compound, C19H 22O5H, is dominated by a head-to-head hydrogen-bonding inter-action between centrosymmetrically related carboxyl groups in each monomer. The result is a dimeric axis of unusual length (ca 34 Å), but still shorter than what could be expected f...

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Autores principales:	Montani, R.S., Garay, R.O., Cukiernik, F.D., Garland, M.T., Baggio, R.
Formato:	JOUR
Materias:	Carboxylic acids Hydrogen Organic acids Carboxyl groups Hydrogen bondings Pm3 calculations Smectic mesophase Smectic phasis Title compounds Turning points Crystal structure
Acceso en línea:	http://hdl.handle.net/20.500.12110/paper_01082701_v65_n3_po81_Montani
Aporte de:	Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA) de Universidad de Buenos Aires

id	todo:paper_01082701_v65_n3_po81_Montani
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spelling	todo:paper_01082701_v65_n3_po81_Montani2023-10-03T14:57:52Z 4'-[2-(2-Ethoxy-ethoxy)eth-oxy]-bi-phenyl-4-carboxylic acid: Correlation between its crystalline and smectic phases Montani, R.S. Garay, R.O. Cukiernik, F.D. Garland, M.T. Baggio, R. Carboxylic acids Hydrogen Organic acids Carboxyl groups Hydrogen bondings Pm3 calculations Smectic mesophase Smectic phasis Title compounds Turning points Crystal structure The crystal structure of the dimeric title compound, C19H 22O5H, is dominated by a head-to-head hydrogen-bonding inter-action between centrosymmetrically related carboxyl groups in each monomer. The result is a dimeric axis of unusual length (ca 34 Å), but still shorter than what could be expected for a fully extended chain, owing to two turning points in the oligo-eth-oxy ends. This allows for an explanation of the structure of the smectic mesophase exhibited by this compound and at the same time fully validates former geometric estimations based on PM3 calculations. © 2009 International Union of Crystallography. Fil:Cukiernik, F.D. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. JOUR info:eu-repo/semantics/openAccess http://creativecommons.org/licenses/by/2.5/ar http://hdl.handle.net/20.500.12110/paper_01082701_v65_n3_po81_Montani
institution	Universidad de Buenos Aires
institution_str	I-28
repository_str	R-134
collection	Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA)
topic	Carboxylic acids Hydrogen Organic acids Carboxyl groups Hydrogen bondings Pm3 calculations Smectic mesophase Smectic phasis Title compounds Turning points Crystal structure
spellingShingle	Carboxylic acids Hydrogen Organic acids Carboxyl groups Hydrogen bondings Pm3 calculations Smectic mesophase Smectic phasis Title compounds Turning points Crystal structure Montani, R.S. Garay, R.O. Cukiernik, F.D. Garland, M.T. Baggio, R. 4'-[2-(2-Ethoxy-ethoxy)eth-oxy]-bi-phenyl-4-carboxylic acid: Correlation between its crystalline and smectic phases
topic_facet	Carboxylic acids Hydrogen Organic acids Carboxyl groups Hydrogen bondings Pm3 calculations Smectic mesophase Smectic phasis Title compounds Turning points Crystal structure
description	The crystal structure of the dimeric title compound, C19H 22O5H, is dominated by a head-to-head hydrogen-bonding inter-action between centrosymmetrically related carboxyl groups in each monomer. The result is a dimeric axis of unusual length (ca 34 Å), but still shorter than what could be expected for a fully extended chain, owing to two turning points in the oligo-eth-oxy ends. This allows for an explanation of the structure of the smectic mesophase exhibited by this compound and at the same time fully validates former geometric estimations based on PM3 calculations. © 2009 International Union of Crystallography.
format	JOUR
author	Montani, R.S. Garay, R.O. Cukiernik, F.D. Garland, M.T. Baggio, R.
author_facet	Montani, R.S. Garay, R.O. Cukiernik, F.D. Garland, M.T. Baggio, R.
author_sort	Montani, R.S.
title	4'-[2-(2-Ethoxy-ethoxy)eth-oxy]-bi-phenyl-4-carboxylic acid: Correlation between its crystalline and smectic phases
title_short	4'-[2-(2-Ethoxy-ethoxy)eth-oxy]-bi-phenyl-4-carboxylic acid: Correlation between its crystalline and smectic phases
title_full	4'-[2-(2-Ethoxy-ethoxy)eth-oxy]-bi-phenyl-4-carboxylic acid: Correlation between its crystalline and smectic phases
title_fullStr	4'-[2-(2-Ethoxy-ethoxy)eth-oxy]-bi-phenyl-4-carboxylic acid: Correlation between its crystalline and smectic phases
title_full_unstemmed	4'-[2-(2-Ethoxy-ethoxy)eth-oxy]-bi-phenyl-4-carboxylic acid: Correlation between its crystalline and smectic phases
title_sort	4'-[2-(2-ethoxy-ethoxy)eth-oxy]-bi-phenyl-4-carboxylic acid: correlation between its crystalline and smectic phases
url	http://hdl.handle.net/20.500.12110/paper_01082701_v65_n3_po81_Montani
work_keys_str_mv	AT montanirs 422ethoxyethoxyethoxybiphenyl4carboxylicacidcorrelationbetweenitscrystallineandsmecticphases AT garayro 422ethoxyethoxyethoxybiphenyl4carboxylicacidcorrelationbetweenitscrystallineandsmecticphases AT cukiernikfd 422ethoxyethoxyethoxybiphenyl4carboxylicacidcorrelationbetweenitscrystallineandsmecticphases AT garlandmt 422ethoxyethoxyethoxybiphenyl4carboxylicacidcorrelationbetweenitscrystallineandsmecticphases AT baggior 422ethoxyethoxyethoxybiphenyl4carboxylicacidcorrelationbetweenitscrystallineandsmecticphases
_version_	1782029227438112768

4'-[2-(2-Ethoxy-ethoxy)eth-oxy]-bi-phenyl-4-carboxylic acid: Correlation between its crystalline and smectic phases

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