A complex containing three different kinds of Ru-N bonds: Ethoxydinitro-nitrosyl(N, N, N′, N′-tetramethylethylenediamine-κ 2N, N′)ruthenium(II)

The octahedral title compound, [Ru(C2H5O)(NO)(NO2)2-(C6H 16N2)], crystallizes in the rhombohedral space group P31 with an ethoxy ligand axially coordinated trans to the nitrosyl ligand. The RuII ion is equatorially coordinated by a tetramethylethylenediamine group acting as a bidentate ligand, and t...

Descripción completa

Guardado en:
Detalles Bibliográficos
Autores principales: Albores, P., Chaia, Z.D., Baraldo, L., Castellano, E.E., Piro, O.E.
Formato: JOUR
Materias:
Chemical bonds
Complexation
Crystallization
Ruthenium compounds
Solutions
Stereochemistry
Synthesis (chemical)
Hybridization
Ligands
Crystal structure
Acceso en línea:http://hdl.handle.net/20.500.12110/paper_01082701_v58_n4_pm235_Albores
Aporte de:
Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA) de Universidad de Buenos Aires
id todo:paper_01082701_v58_n4_pm235_Albores
record_format dspace
spelling todo:paper_01082701_v58_n4_pm235_Albores2023-10-03T14:57:49Z A complex containing three different kinds of Ru-N bonds: Ethoxydinitro-nitrosyl(N, N, N′, N′-tetramethylethylenediamine-κ 2N, N′)ruthenium(II) Albores, P. Chaia, Z.D. Baraldo, L. Castellano, E.E. Piro, O.E. Chemical bonds Complexation Crystallization Ruthenium compounds Solutions Stereochemistry Synthesis (chemical) Hybridization Ligands Crystal structure The octahedral title compound, [Ru(C2H5O)(NO)(NO2)2-(C6H 16N2)], crystallizes in the rhombohedral space group P31 with an ethoxy ligand axially coordinated trans to the nitrosyl ligand. The RuII ion is equatorially coordinated by a tetramethylethylenediamine group acting as a bidentate ligand, and to two nitro moieties whose planes are tilted with respect to the mean equatorial plane. Each nitrogen ligand bonded to the metallic centre has a different hybridization state. JOUR info:eu-repo/semantics/openAccess http://creativecommons.org/licenses/by/2.5/ar http://hdl.handle.net/20.500.12110/paper_01082701_v58_n4_pm235_Albores
institution Universidad de Buenos Aires
institution_str I-28
repository_str R-134
collection Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA)
topic Chemical bonds
Complexation
Crystallization
Ruthenium compounds
Solutions
Stereochemistry
Synthesis (chemical)
Hybridization
Ligands
Crystal structure
spellingShingle Chemical bonds
Complexation
Crystallization
Ruthenium compounds
Solutions
Stereochemistry
Synthesis (chemical)
Hybridization
Ligands
Crystal structure
Albores, P.
Chaia, Z.D.
Baraldo, L.
Castellano, E.E.
Piro, O.E.
A complex containing three different kinds of Ru-N bonds: Ethoxydinitro-nitrosyl(N, N, N′, N′-tetramethylethylenediamine-κ 2N, N′)ruthenium(II)
topic_facet Chemical bonds
Complexation
Crystallization
Ruthenium compounds
Solutions
Stereochemistry
Synthesis (chemical)
Hybridization
Ligands
Crystal structure
description The octahedral title compound, [Ru(C2H5O)(NO)(NO2)2-(C6H 16N2)], crystallizes in the rhombohedral space group P31 with an ethoxy ligand axially coordinated trans to the nitrosyl ligand. The RuII ion is equatorially coordinated by a tetramethylethylenediamine group acting as a bidentate ligand, and to two nitro moieties whose planes are tilted with respect to the mean equatorial plane. Each nitrogen ligand bonded to the metallic centre has a different hybridization state.
format JOUR
author Albores, P.
Chaia, Z.D.
Baraldo, L.
Castellano, E.E.
Piro, O.E.
author_facet Albores, P.
Chaia, Z.D.
Baraldo, L.
Castellano, E.E.
Piro, O.E.
author_sort Albores, P.
title A complex containing three different kinds of Ru-N bonds: Ethoxydinitro-nitrosyl(N, N, N′, N′-tetramethylethylenediamine-κ 2N, N′)ruthenium(II)
title_short A complex containing three different kinds of Ru-N bonds: Ethoxydinitro-nitrosyl(N, N, N′, N′-tetramethylethylenediamine-κ 2N, N′)ruthenium(II)
title_full A complex containing three different kinds of Ru-N bonds: Ethoxydinitro-nitrosyl(N, N, N′, N′-tetramethylethylenediamine-κ 2N, N′)ruthenium(II)
title_fullStr A complex containing three different kinds of Ru-N bonds: Ethoxydinitro-nitrosyl(N, N, N′, N′-tetramethylethylenediamine-κ 2N, N′)ruthenium(II)
title_full_unstemmed A complex containing three different kinds of Ru-N bonds: Ethoxydinitro-nitrosyl(N, N, N′, N′-tetramethylethylenediamine-κ 2N, N′)ruthenium(II)
title_sort complex containing three different kinds of ru-n bonds: ethoxydinitro-nitrosyl(n, n, n′, n′-tetramethylethylenediamine-κ 2n, n′)ruthenium(ii)
url http://hdl.handle.net/20.500.12110/paper_01082701_v58_n4_pm235_Albores
work_keys_str_mv AT alboresp acomplexcontainingthreedifferentkindsofrunbondsethoxydinitronitrosylnnnntetramethylethylenediaminek2nnrutheniumii
AT chaiazd acomplexcontainingthreedifferentkindsofrunbondsethoxydinitronitrosylnnnntetramethylethylenediaminek2nnrutheniumii
AT baraldol acomplexcontainingthreedifferentkindsofrunbondsethoxydinitronitrosylnnnntetramethylethylenediaminek2nnrutheniumii
AT castellanoee acomplexcontainingthreedifferentkindsofrunbondsethoxydinitronitrosylnnnntetramethylethylenediaminek2nnrutheniumii
AT pirooe acomplexcontainingthreedifferentkindsofrunbondsethoxydinitronitrosylnnnntetramethylethylenediaminek2nnrutheniumii
AT alboresp complexcontainingthreedifferentkindsofrunbondsethoxydinitronitrosylnnnntetramethylethylenediaminek2nnrutheniumii
AT chaiazd complexcontainingthreedifferentkindsofrunbondsethoxydinitronitrosylnnnntetramethylethylenediaminek2nnrutheniumii
AT baraldol complexcontainingthreedifferentkindsofrunbondsethoxydinitronitrosylnnnntetramethylethylenediaminek2nnrutheniumii
AT castellanoee complexcontainingthreedifferentkindsofrunbondsethoxydinitronitrosylnnnntetramethylethylenediaminek2nnrutheniumii
AT pirooe complexcontainingthreedifferentkindsofrunbondsethoxydinitronitrosylnnnntetramethylethylenediaminek2nnrutheniumii
_version_ 1807323940355309568

Ejemplares similares