Excitation energy transfer and trapping in dye-loaded solid particles
The photophysics of several systems composed of a single dye or pairs of dyes attached to solid particles has been studied in the dry solid state at high dye concentrations taking into account light scattering and inner filter effects. Interaction among dye molecules and singlet-singlet energy trans...
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| Acceso en línea: | http://hdl.handle.net/20.500.12110/paper_00778923_v1130_n_p247_Rodriguez |
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todo:paper_00778923_v1130_n_p247_Rodriguez2023-10-03T14:54:18Z Excitation energy transfer and trapping in dye-loaded solid particles Rodríguez, H.B. San Román, E. Dye aggregation Energy trapping Quenching radius Solid particles dye absorption conference paper energy transfer energy trapping fluorescence analysis light scattering molecular interaction photochemical quenching radiation energy solid state The photophysics of several systems composed of a single dye or pairs of dyes attached to solid particles has been studied in the dry solid state at high dye concentrations taking into account light scattering and inner filter effects. Interaction among dye molecules and singlet-singlet energy transfer are relevant in these conditions, as has been demonstrated for pairs of dyes with suitable spectral overlap. For single dyes, after correction for radiative energy transfer, fluorescence quenching is observed as the surface concentration increases. This effect is explained by two different trapping models. Irrespective of the nature of the traps, concentration quenching may be of static (trap absorption) and dynamic (energy transfer) nature. The unraveling of energy trapping mechanisms is a key to the development of efficient photoactive solid materials. © 2008 New York Academy of Sciences. Fil:Rodríguez, H.B. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. Fil:San Román, E. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. SER info:eu-repo/semantics/openAccess http://creativecommons.org/licenses/by/2.5/ar http://hdl.handle.net/20.500.12110/paper_00778923_v1130_n_p247_Rodriguez |
| institution |
Universidad de Buenos Aires |
| institution_str |
I-28 |
| repository_str |
R-134 |
| collection |
Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA) |
| topic |
Dye aggregation Energy trapping Quenching radius Solid particles dye absorption conference paper energy transfer energy trapping fluorescence analysis light scattering molecular interaction photochemical quenching radiation energy solid state |
| spellingShingle |
Dye aggregation Energy trapping Quenching radius Solid particles dye absorption conference paper energy transfer energy trapping fluorescence analysis light scattering molecular interaction photochemical quenching radiation energy solid state Rodríguez, H.B. San Román, E. Excitation energy transfer and trapping in dye-loaded solid particles |
| topic_facet |
Dye aggregation Energy trapping Quenching radius Solid particles dye absorption conference paper energy transfer energy trapping fluorescence analysis light scattering molecular interaction photochemical quenching radiation energy solid state |
| description |
The photophysics of several systems composed of a single dye or pairs of dyes attached to solid particles has been studied in the dry solid state at high dye concentrations taking into account light scattering and inner filter effects. Interaction among dye molecules and singlet-singlet energy transfer are relevant in these conditions, as has been demonstrated for pairs of dyes with suitable spectral overlap. For single dyes, after correction for radiative energy transfer, fluorescence quenching is observed as the surface concentration increases. This effect is explained by two different trapping models. Irrespective of the nature of the traps, concentration quenching may be of static (trap absorption) and dynamic (energy transfer) nature. The unraveling of energy trapping mechanisms is a key to the development of efficient photoactive solid materials. © 2008 New York Academy of Sciences. |
| format |
SER |
| author |
Rodríguez, H.B. San Román, E. |
| author_facet |
Rodríguez, H.B. San Román, E. |
| author_sort |
Rodríguez, H.B. |
| title |
Excitation energy transfer and trapping in dye-loaded solid particles |
| title_short |
Excitation energy transfer and trapping in dye-loaded solid particles |
| title_full |
Excitation energy transfer and trapping in dye-loaded solid particles |
| title_fullStr |
Excitation energy transfer and trapping in dye-loaded solid particles |
| title_full_unstemmed |
Excitation energy transfer and trapping in dye-loaded solid particles |
| title_sort |
excitation energy transfer and trapping in dye-loaded solid particles |
| url |
http://hdl.handle.net/20.500.12110/paper_00778923_v1130_n_p247_Rodriguez |
| work_keys_str_mv |
AT rodriguezhb excitationenergytransferandtrappingindyeloadedsolidparticles AT sanromane excitationenergytransferandtrappingindyeloadedsolidparticles |
| _version_ |
1807317972332576768 |