Viscosity of concentrated sucrose and trehalose aqueous solutions including the supercooled regime
The viscosity of aqueous solutions of sucrose and trehalose is analyzed over a wide range of concentrations and temperatures covering the normal liquid and supercooled liquid regions, close to the glass transition temperature. These sugar solutions are fragile systems whose viscosity exhibits temper...
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Acceso en línea: | http://hdl.handle.net/20.500.12110/paper_00472689_v37_n3_p1503_Longinotti |
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todo:paper_00472689_v37_n3_p1503_Longinotti2023-10-03T14:52:26Z Viscosity of concentrated sucrose and trehalose aqueous solutions including the supercooled regime Longinotti, M.P. Corti, H.R. Aqueous solutions Fragility Sucrose Supercooled Trehalose Viscosity The viscosity of aqueous solutions of sucrose and trehalose is analyzed over a wide range of concentrations and temperatures covering the normal liquid and supercooled liquid regions, close to the glass transition temperature. These sugar solutions are fragile systems whose viscosity exhibits temperature dependence with a large departure from Arrhenius behavior. A description of the temperature and concentration dependences of the solution viscosity is given in terms of a scaled Arrhenius representation, which adopts the reduced temperature Tg T as the state variable. A comparison with results obtained from other theoretical or semiempirical equations is also presented. © 2008 American Institute of Physics. Fil:Longinotti, M.P. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. Fil:Corti, H.R. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. JOUR info:eu-repo/semantics/openAccess http://creativecommons.org/licenses/by/2.5/ar http://hdl.handle.net/20.500.12110/paper_00472689_v37_n3_p1503_Longinotti |
institution |
Universidad de Buenos Aires |
institution_str |
I-28 |
repository_str |
R-134 |
collection |
Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA) |
topic |
Aqueous solutions Fragility Sucrose Supercooled Trehalose Viscosity |
spellingShingle |
Aqueous solutions Fragility Sucrose Supercooled Trehalose Viscosity Longinotti, M.P. Corti, H.R. Viscosity of concentrated sucrose and trehalose aqueous solutions including the supercooled regime |
topic_facet |
Aqueous solutions Fragility Sucrose Supercooled Trehalose Viscosity |
description |
The viscosity of aqueous solutions of sucrose and trehalose is analyzed over a wide range of concentrations and temperatures covering the normal liquid and supercooled liquid regions, close to the glass transition temperature. These sugar solutions are fragile systems whose viscosity exhibits temperature dependence with a large departure from Arrhenius behavior. A description of the temperature and concentration dependences of the solution viscosity is given in terms of a scaled Arrhenius representation, which adopts the reduced temperature Tg T as the state variable. A comparison with results obtained from other theoretical or semiempirical equations is also presented. © 2008 American Institute of Physics. |
format |
JOUR |
author |
Longinotti, M.P. Corti, H.R. |
author_facet |
Longinotti, M.P. Corti, H.R. |
author_sort |
Longinotti, M.P. |
title |
Viscosity of concentrated sucrose and trehalose aqueous solutions including the supercooled regime |
title_short |
Viscosity of concentrated sucrose and trehalose aqueous solutions including the supercooled regime |
title_full |
Viscosity of concentrated sucrose and trehalose aqueous solutions including the supercooled regime |
title_fullStr |
Viscosity of concentrated sucrose and trehalose aqueous solutions including the supercooled regime |
title_full_unstemmed |
Viscosity of concentrated sucrose and trehalose aqueous solutions including the supercooled regime |
title_sort |
viscosity of concentrated sucrose and trehalose aqueous solutions including the supercooled regime |
url |
http://hdl.handle.net/20.500.12110/paper_00472689_v37_n3_p1503_Longinotti |
work_keys_str_mv |
AT longinottimp viscosityofconcentratedsucroseandtrehaloseaqueoussolutionsincludingthesupercooledregime AT cortihr viscosityofconcentratedsucroseandtrehaloseaqueoussolutionsincludingthesupercooledregime |
_version_ |
1782023490459664384 |