Characterization of two new copper(II) complexes with saccharinate and benzimidazole as ligands
The crystal structure of the complexes [Cu(sac)2-(bzim)2(H2O)] (1) and [Cu(sac)2(bzim)(H2O)(EtOH)] · 2 EtOH (2) (sac = saccharinate anion; bzim = benzimidazole; EtOH = ethanol) was determined by single crystal X-ray diffractometry. Complex 1 crystallizes in the monoclinic C2/c space group with Z = 8...
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todo:paper_00442313_v626_n12_p2509_Williams2023-10-03T14:51:38Z Characterization of two new copper(II) complexes with saccharinate and benzimidazole as ligands Williams, P.A.M. Ferrer, E.G. Pasquevich, K.A. Baran, E.J. Chaia, Z. Castellano, E.E. Piro, O.E. Benzimidazole Copper(II) Crystal structures Electronic spectra IR-spectra Saccharinate Thermal behaviour The crystal structure of the complexes [Cu(sac)2-(bzim)2(H2O)] (1) and [Cu(sac)2(bzim)(H2O)(EtOH)] · 2 EtOH (2) (sac = saccharinate anion; bzim = benzimidazole; EtOH = ethanol) was determined by single crystal X-ray diffractometry. Complex 1 crystallizes in the monoclinic C2/c space group with Z = 8 whereas complex 2 belongs to the triclinic P1̄ space group with Z = 2. Room temperature magnetic susceptibilities as well as electronic and IR spectra of both complexes were discussed. Their thermal behaviour was investigated by means of TG and DTA methods. Fil:Chaia, Z. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. JOUR info:eu-repo/semantics/openAccess http://creativecommons.org/licenses/by/2.5/ar http://hdl.handle.net/20.500.12110/paper_00442313_v626_n12_p2509_Williams |
institution |
Universidad de Buenos Aires |
institution_str |
I-28 |
repository_str |
R-134 |
collection |
Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA) |
topic |
Benzimidazole Copper(II) Crystal structures Electronic spectra IR-spectra Saccharinate Thermal behaviour |
spellingShingle |
Benzimidazole Copper(II) Crystal structures Electronic spectra IR-spectra Saccharinate Thermal behaviour Williams, P.A.M. Ferrer, E.G. Pasquevich, K.A. Baran, E.J. Chaia, Z. Castellano, E.E. Piro, O.E. Characterization of two new copper(II) complexes with saccharinate and benzimidazole as ligands |
topic_facet |
Benzimidazole Copper(II) Crystal structures Electronic spectra IR-spectra Saccharinate Thermal behaviour |
description |
The crystal structure of the complexes [Cu(sac)2-(bzim)2(H2O)] (1) and [Cu(sac)2(bzim)(H2O)(EtOH)] · 2 EtOH (2) (sac = saccharinate anion; bzim = benzimidazole; EtOH = ethanol) was determined by single crystal X-ray diffractometry. Complex 1 crystallizes in the monoclinic C2/c space group with Z = 8 whereas complex 2 belongs to the triclinic P1̄ space group with Z = 2. Room temperature magnetic susceptibilities as well as electronic and IR spectra of both complexes were discussed. Their thermal behaviour was investigated by means of TG and DTA methods. |
format |
JOUR |
author |
Williams, P.A.M. Ferrer, E.G. Pasquevich, K.A. Baran, E.J. Chaia, Z. Castellano, E.E. Piro, O.E. |
author_facet |
Williams, P.A.M. Ferrer, E.G. Pasquevich, K.A. Baran, E.J. Chaia, Z. Castellano, E.E. Piro, O.E. |
author_sort |
Williams, P.A.M. |
title |
Characterization of two new copper(II) complexes with saccharinate and benzimidazole as ligands |
title_short |
Characterization of two new copper(II) complexes with saccharinate and benzimidazole as ligands |
title_full |
Characterization of two new copper(II) complexes with saccharinate and benzimidazole as ligands |
title_fullStr |
Characterization of two new copper(II) complexes with saccharinate and benzimidazole as ligands |
title_full_unstemmed |
Characterization of two new copper(II) complexes with saccharinate and benzimidazole as ligands |
title_sort |
characterization of two new copper(ii) complexes with saccharinate and benzimidazole as ligands |
url |
http://hdl.handle.net/20.500.12110/paper_00442313_v626_n12_p2509_Williams |
work_keys_str_mv |
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