Characterization of two new copper(II) complexes with saccharinate and benzimidazole as ligands

The crystal structure of the complexes [Cu(sac)2-(bzim)2(H2O)] (1) and [Cu(sac)2(bzim)(H2O)(EtOH)] · 2 EtOH (2) (sac = saccharinate anion; bzim = benzimidazole; EtOH = ethanol) was determined by single crystal X-ray diffractometry. Complex 1 crystallizes in the monoclinic C2/c space group with Z = 8...

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Autores principales: Williams, P.A.M., Ferrer, E.G., Pasquevich, K.A., Baran, E.J., Chaia, Z., Castellano, E.E., Piro, O.E.
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Acceso en línea:http://hdl.handle.net/20.500.12110/paper_00442313_v626_n12_p2509_Williams
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spelling todo:paper_00442313_v626_n12_p2509_Williams2023-10-03T14:51:38Z Characterization of two new copper(II) complexes with saccharinate and benzimidazole as ligands Williams, P.A.M. Ferrer, E.G. Pasquevich, K.A. Baran, E.J. Chaia, Z. Castellano, E.E. Piro, O.E. Benzimidazole Copper(II) Crystal structures Electronic spectra IR-spectra Saccharinate Thermal behaviour The crystal structure of the complexes [Cu(sac)2-(bzim)2(H2O)] (1) and [Cu(sac)2(bzim)(H2O)(EtOH)] · 2 EtOH (2) (sac = saccharinate anion; bzim = benzimidazole; EtOH = ethanol) was determined by single crystal X-ray diffractometry. Complex 1 crystallizes in the monoclinic C2/c space group with Z = 8 whereas complex 2 belongs to the triclinic P1̄ space group with Z = 2. Room temperature magnetic susceptibilities as well as electronic and IR spectra of both complexes were discussed. Their thermal behaviour was investigated by means of TG and DTA methods. Fil:Chaia, Z. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. JOUR info:eu-repo/semantics/openAccess http://creativecommons.org/licenses/by/2.5/ar http://hdl.handle.net/20.500.12110/paper_00442313_v626_n12_p2509_Williams
institution Universidad de Buenos Aires
institution_str I-28
repository_str R-134
collection Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA)
topic Benzimidazole
Copper(II)
Crystal structures
Electronic spectra
IR-spectra
Saccharinate
Thermal behaviour
spellingShingle Benzimidazole
Copper(II)
Crystal structures
Electronic spectra
IR-spectra
Saccharinate
Thermal behaviour
Williams, P.A.M.
Ferrer, E.G.
Pasquevich, K.A.
Baran, E.J.
Chaia, Z.
Castellano, E.E.
Piro, O.E.
Characterization of two new copper(II) complexes with saccharinate and benzimidazole as ligands
topic_facet Benzimidazole
Copper(II)
Crystal structures
Electronic spectra
IR-spectra
Saccharinate
Thermal behaviour
description The crystal structure of the complexes [Cu(sac)2-(bzim)2(H2O)] (1) and [Cu(sac)2(bzim)(H2O)(EtOH)] · 2 EtOH (2) (sac = saccharinate anion; bzim = benzimidazole; EtOH = ethanol) was determined by single crystal X-ray diffractometry. Complex 1 crystallizes in the monoclinic C2/c space group with Z = 8 whereas complex 2 belongs to the triclinic P1̄ space group with Z = 2. Room temperature magnetic susceptibilities as well as electronic and IR spectra of both complexes were discussed. Their thermal behaviour was investigated by means of TG and DTA methods.
format JOUR
author Williams, P.A.M.
Ferrer, E.G.
Pasquevich, K.A.
Baran, E.J.
Chaia, Z.
Castellano, E.E.
Piro, O.E.
author_facet Williams, P.A.M.
Ferrer, E.G.
Pasquevich, K.A.
Baran, E.J.
Chaia, Z.
Castellano, E.E.
Piro, O.E.
author_sort Williams, P.A.M.
title Characterization of two new copper(II) complexes with saccharinate and benzimidazole as ligands
title_short Characterization of two new copper(II) complexes with saccharinate and benzimidazole as ligands
title_full Characterization of two new copper(II) complexes with saccharinate and benzimidazole as ligands
title_fullStr Characterization of two new copper(II) complexes with saccharinate and benzimidazole as ligands
title_full_unstemmed Characterization of two new copper(II) complexes with saccharinate and benzimidazole as ligands
title_sort characterization of two new copper(ii) complexes with saccharinate and benzimidazole as ligands
url http://hdl.handle.net/20.500.12110/paper_00442313_v626_n12_p2509_Williams
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