The thermal decomposition of copper(II) nicotinate and isonicotinate

The thermal decomposition of copper(II) nicotinate and isonicotinate yields, in a sharp transition, metallic copper as the final solid residue along with the release of carbon dioxide and pyridine. In the case of the nicotinate, small amounts of nicotinic acid are also detected. The decomposition is...

Descripción completa

Guardado en:
Detalles Bibliográficos
Autores principales: Sileo, E.E., Morando, P.J., Della Vedova, C.O., Blesa, M.A.
Formato: JOUR
Acceso en línea:http://hdl.handle.net/20.500.12110/paper_00406031_v138_n2_p233_Sileo
Aporte de:
Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA) de Universidad de Buenos Aires
id todo:paper_00406031_v138_n2_p233_Sileo
record_format dspace
spelling todo:paper_00406031_v138_n2_p233_Sileo2023-10-03T14:51:02Z The thermal decomposition of copper(II) nicotinate and isonicotinate Sileo, E.E. Morando, P.J. Della Vedova, C.O. Blesa, M.A. The thermal decomposition of copper(II) nicotinate and isonicotinate yields, in a sharp transition, metallic copper as the final solid residue along with the release of carbon dioxide and pyridine. In the case of the nicotinate, small amounts of nicotinic acid are also detected. The decomposition is started by homolytic RC(O)O-Cu bond scission, which is equivalent to electron transfer from RC(O)O- to Cu(II). © 1989. Fil:Sileo, E.E. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. JOUR info:eu-repo/semantics/openAccess http://creativecommons.org/licenses/by/2.5/ar http://hdl.handle.net/20.500.12110/paper_00406031_v138_n2_p233_Sileo
institution Universidad de Buenos Aires
institution_str I-28
repository_str R-134
collection Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA)
description The thermal decomposition of copper(II) nicotinate and isonicotinate yields, in a sharp transition, metallic copper as the final solid residue along with the release of carbon dioxide and pyridine. In the case of the nicotinate, small amounts of nicotinic acid are also detected. The decomposition is started by homolytic RC(O)O-Cu bond scission, which is equivalent to electron transfer from RC(O)O- to Cu(II). © 1989.
format JOUR
author Sileo, E.E.
Morando, P.J.
Della Vedova, C.O.
Blesa, M.A.
spellingShingle Sileo, E.E.
Morando, P.J.
Della Vedova, C.O.
Blesa, M.A.
The thermal decomposition of copper(II) nicotinate and isonicotinate
author_facet Sileo, E.E.
Morando, P.J.
Della Vedova, C.O.
Blesa, M.A.
author_sort Sileo, E.E.
title The thermal decomposition of copper(II) nicotinate and isonicotinate
title_short The thermal decomposition of copper(II) nicotinate and isonicotinate
title_full The thermal decomposition of copper(II) nicotinate and isonicotinate
title_fullStr The thermal decomposition of copper(II) nicotinate and isonicotinate
title_full_unstemmed The thermal decomposition of copper(II) nicotinate and isonicotinate
title_sort thermal decomposition of copper(ii) nicotinate and isonicotinate
url http://hdl.handle.net/20.500.12110/paper_00406031_v138_n2_p233_Sileo
work_keys_str_mv AT sileoee thethermaldecompositionofcopperiinicotinateandisonicotinate
AT morandopj thethermaldecompositionofcopperiinicotinateandisonicotinate
AT dellavedovaco thethermaldecompositionofcopperiinicotinateandisonicotinate
AT blesama thethermaldecompositionofcopperiinicotinateandisonicotinate
AT sileoee thermaldecompositionofcopperiinicotinateandisonicotinate
AT morandopj thermaldecompositionofcopperiinicotinateandisonicotinate
AT dellavedovaco thermaldecompositionofcopperiinicotinateandisonicotinate
AT blesama thermaldecompositionofcopperiinicotinateandisonicotinate
_version_ 1807321280544768000

Ejemplares similares