The reaction of pentacyanonitrosylferrate(II) with primary amines as a source of stabilized aliphatic diazonium ions: A new route to secondary amines
Pentacyanonitrosylferrate(II), 1, reacts with n-butylamine to produce di-n-butylamine in high yields (81-95%). The absence of rearranged products indicates that the initially produced diazonium ion is stabilized by coordination to the metal. Benzylamine and 1,4-diaminobutane react with 1 to produce...
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| Formato: | JOUR |
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| Acceso en línea: | http://hdl.handle.net/20.500.12110/paper_00404039_v40_n25_p4635_Doctorovich |
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todo:paper_00404039_v40_n25_p4635_Doctorovich2023-10-03T14:50:53Z The reaction of pentacyanonitrosylferrate(II) with primary amines as a source of stabilized aliphatic diazonium ions: A new route to secondary amines Doctorovich, F. Trápani, C. Amine Complex Diazotization Iron Nitroprusside Pentacyanonitrosylferrate aliphatic compound amine benzylamine butylamine coordination compound diazonium compound dibenzylamine dibutylamine iron derivative metal pentacyanonitrosylferrate(ii) piperidine putrescine unclassified drug article chemical reaction reaction analysis synthesis Pentacyanonitrosylferrate(II), 1, reacts with n-butylamine to produce di-n-butylamine in high yields (81-95%). The absence of rearranged products indicates that the initially produced diazonium ion is stabilized by coordination to the metal. Benzylamine and 1,4-diaminobutane react with 1 to produce dibenzylamine and piperidine, respectively. JOUR info:eu-repo/semantics/openAccess http://creativecommons.org/licenses/by/2.5/ar http://hdl.handle.net/20.500.12110/paper_00404039_v40_n25_p4635_Doctorovich |
| institution |
Universidad de Buenos Aires |
| institution_str |
I-28 |
| repository_str |
R-134 |
| collection |
Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA) |
| topic |
Amine Complex Diazotization Iron Nitroprusside Pentacyanonitrosylferrate aliphatic compound amine benzylamine butylamine coordination compound diazonium compound dibenzylamine dibutylamine iron derivative metal pentacyanonitrosylferrate(ii) piperidine putrescine unclassified drug article chemical reaction reaction analysis synthesis |
| spellingShingle |
Amine Complex Diazotization Iron Nitroprusside Pentacyanonitrosylferrate aliphatic compound amine benzylamine butylamine coordination compound diazonium compound dibenzylamine dibutylamine iron derivative metal pentacyanonitrosylferrate(ii) piperidine putrescine unclassified drug article chemical reaction reaction analysis synthesis Doctorovich, F. Trápani, C. The reaction of pentacyanonitrosylferrate(II) with primary amines as a source of stabilized aliphatic diazonium ions: A new route to secondary amines |
| topic_facet |
Amine Complex Diazotization Iron Nitroprusside Pentacyanonitrosylferrate aliphatic compound amine benzylamine butylamine coordination compound diazonium compound dibenzylamine dibutylamine iron derivative metal pentacyanonitrosylferrate(ii) piperidine putrescine unclassified drug article chemical reaction reaction analysis synthesis |
| description |
Pentacyanonitrosylferrate(II), 1, reacts with n-butylamine to produce di-n-butylamine in high yields (81-95%). The absence of rearranged products indicates that the initially produced diazonium ion is stabilized by coordination to the metal. Benzylamine and 1,4-diaminobutane react with 1 to produce dibenzylamine and piperidine, respectively. |
| format |
JOUR |
| author |
Doctorovich, F. Trápani, C. |
| author_facet |
Doctorovich, F. Trápani, C. |
| author_sort |
Doctorovich, F. |
| title |
The reaction of pentacyanonitrosylferrate(II) with primary amines as a source of stabilized aliphatic diazonium ions: A new route to secondary amines |
| title_short |
The reaction of pentacyanonitrosylferrate(II) with primary amines as a source of stabilized aliphatic diazonium ions: A new route to secondary amines |
| title_full |
The reaction of pentacyanonitrosylferrate(II) with primary amines as a source of stabilized aliphatic diazonium ions: A new route to secondary amines |
| title_fullStr |
The reaction of pentacyanonitrosylferrate(II) with primary amines as a source of stabilized aliphatic diazonium ions: A new route to secondary amines |
| title_full_unstemmed |
The reaction of pentacyanonitrosylferrate(II) with primary amines as a source of stabilized aliphatic diazonium ions: A new route to secondary amines |
| title_sort |
reaction of pentacyanonitrosylferrate(ii) with primary amines as a source of stabilized aliphatic diazonium ions: a new route to secondary amines |
| url |
http://hdl.handle.net/20.500.12110/paper_00404039_v40_n25_p4635_Doctorovich |
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