Unusual dealkylations and rearrangements in aromatic nucleophilic substitution

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The reaction of 2,4-dinitrohalobenzenes with di-isopropylamine produces mainly N-(2,4-dinitrophenyl)-isopropylamine and N-(2,4-dinitrophenyl)-n-propylamine instead of the expected straightforward substitution product. Dealkylations are also observed in the reactions with isopropylcyclohexylamine and...

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Autores principales: Nudelman, N.S., Socolovsky, S.E.
Formato: JOUR
Acceso en línea:http://hdl.handle.net/20.500.12110/paper_00404039_v21_n35_p3331_Nudelman
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Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA) de Universidad de Buenos Aires
id todo:paper_00404039_v21_n35_p3331_Nudelman
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spelling todo:paper_00404039_v21_n35_p3331_Nudelman2023-10-03T14:50:47Z Unusual dealkylations and rearrangements in aromatic nucleophilic substitution Nudelman, N.S. Socolovsky, S.E. The reaction of 2,4-dinitrohalobenzenes with di-isopropylamine produces mainly N-(2,4-dinitrophenyl)-isopropylamine and N-(2,4-dinitrophenyl)-n-propylamine instead of the expected straightforward substitution product. Dealkylations are also observed in the reactions with isopropylcyclohexylamine and dicyclohexylamine. A carbanionic mechanism is proposed. © 1980. Fil:Socolovsky, S.E. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. JOUR info:eu-repo/semantics/openAccess http://creativecommons.org/licenses/by/2.5/ar http://hdl.handle.net/20.500.12110/paper_00404039_v21_n35_p3331_Nudelman
institution Universidad de Buenos Aires
institution_str I-28
repository_str R-134
collection Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA)
description The reaction of 2,4-dinitrohalobenzenes with di-isopropylamine produces mainly N-(2,4-dinitrophenyl)-isopropylamine and N-(2,4-dinitrophenyl)-n-propylamine instead of the expected straightforward substitution product. Dealkylations are also observed in the reactions with isopropylcyclohexylamine and dicyclohexylamine. A carbanionic mechanism is proposed. © 1980.
format JOUR
author Nudelman, N.S.
Socolovsky, S.E.
spellingShingle Nudelman, N.S.
Socolovsky, S.E.
Unusual dealkylations and rearrangements in aromatic nucleophilic substitution
author_facet Nudelman, N.S.
Socolovsky, S.E.
author_sort Nudelman, N.S.
title Unusual dealkylations and rearrangements in aromatic nucleophilic substitution
title_short Unusual dealkylations and rearrangements in aromatic nucleophilic substitution
title_full Unusual dealkylations and rearrangements in aromatic nucleophilic substitution
title_fullStr Unusual dealkylations and rearrangements in aromatic nucleophilic substitution
title_full_unstemmed Unusual dealkylations and rearrangements in aromatic nucleophilic substitution
title_sort unusual dealkylations and rearrangements in aromatic nucleophilic substitution
url http://hdl.handle.net/20.500.12110/paper_00404039_v21_n35_p3331_Nudelman
work_keys_str_mv AT nudelmanns unusualdealkylationsandrearrangementsinaromaticnucleophilicsubstitution
AT socolovskyse unusualdealkylationsandrearrangementsinaromaticnucleophilicsubstitution
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