Reduction of an amido zinc(II) phthalocyanine by diborane

1,2-Dicyano-4,5-di[(N,N-dimethylaminocarbonyl)methoxy]benzene (5) was synthesized in 80% yield from the corresponding 1,2-dibromo derivative 4. Octa(peripheral-amide)substituted zinc(II) phthalocyanine 6 was obtained from 5 and zinc acetate in the presence of 1,8-diazabicyclo[5.4.0]undec-7-ene. Phth...

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Autores principales:	Strassert, C.A., Dicelio, L.E., Awruch, J.
Formato:	JOUR
Materias:	Nucleophilic aromatic substitution Phthalocyanines Reduction Dyes Positive ions Semiconducting zinc compounds 1,2 dicyano 4,5 di[(n,n dimethylaminocarbonyl)methoxy]benzene 1,8 diazabicyclo[5.4.0]undec 7 ene 2,3,9,10,16,17,23,24 octakis[(n,n dimethylaminocarbonyl)methoxy]phthalocyaninatozinc(ii) 2,3,9,10,16,17,23,24 octakis[(n,n dimethylaminoethoxy)]phthalocyaninatozinc(ii) 2,3,9,10,16,17,23,24 octakis[(n,n,n triethylammonium)ethoxy]phthalocyaninatozinc(ii)octaiodide amido zinc(ii) phthalocyanine benzene derivative heterocyclic compound phthalocyanine derivative unclassified drug zinc acetate article drug synthesis matrix assisted laser desorption ionization time of flight mass spectrometry proton nuclear magnetic resonance reduction substitution reaction
Acceso en línea:	http://hdl.handle.net/20.500.12110/paper_00397881_v_n5_p799_Strassert
Aporte de:	Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA) de Universidad de Buenos Aires

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spelling	todo:paper_00397881_v_n5_p799_Strassert2023-10-03T14:49:54Z Reduction of an amido zinc(II) phthalocyanine by diborane Strassert, C.A. Dicelio, L.E. Awruch, J. Nucleophilic aromatic substitution Phthalocyanines Reduction Dyes Positive ions Nucleophilic aromatic substitution Phthalocyanines Reduction Semiconducting zinc compounds 1,2 dicyano 4,5 di[(n,n dimethylaminocarbonyl)methoxy]benzene 1,8 diazabicyclo[5.4.0]undec 7 ene 2,3,9,10,16,17,23,24 octakis[(n,n dimethylaminocarbonyl)methoxy]phthalocyaninatozinc(ii) 2,3,9,10,16,17,23,24 octakis[(n,n dimethylaminoethoxy)]phthalocyaninatozinc(ii) 2,3,9,10,16,17,23,24 octakis[(n,n,n triethylammonium)ethoxy]phthalocyaninatozinc(ii)octaiodide amido zinc(ii) phthalocyanine benzene derivative heterocyclic compound phthalocyanine derivative unclassified drug zinc acetate article drug synthesis matrix assisted laser desorption ionization time of flight mass spectrometry proton nuclear magnetic resonance reduction substitution reaction 1,2-Dicyano-4,5-di[(N,N-dimethylaminocarbonyl)methoxy]benzene (5) was synthesized in 80% yield from the corresponding 1,2-dibromo derivative 4. Octa(peripheral-amide)substituted zinc(II) phthalocyanine 6 was obtained from 5 and zinc acetate in the presence of 1,8-diazabicyclo[5.4.0]undec-7-ene. Phthalocyanine 7 was prepared via reduction of 6 with diborane. Treatment of 7 with methyl iodide afforded cationic dye 8. © Georg Thieme Verlag Stuttgart. Fil:Dicelio, L.E. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. JOUR info:eu-repo/semantics/openAccess http://creativecommons.org/licenses/by/2.5/ar http://hdl.handle.net/20.500.12110/paper_00397881_v_n5_p799_Strassert
institution	Universidad de Buenos Aires
institution_str	I-28
repository_str	R-134
collection	Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA)
topic	Nucleophilic aromatic substitution Phthalocyanines Reduction Dyes Positive ions Nucleophilic aromatic substitution Phthalocyanines Reduction Semiconducting zinc compounds 1,2 dicyano 4,5 di[(n,n dimethylaminocarbonyl)methoxy]benzene 1,8 diazabicyclo[5.4.0]undec 7 ene 2,3,9,10,16,17,23,24 octakis[(n,n dimethylaminocarbonyl)methoxy]phthalocyaninatozinc(ii) 2,3,9,10,16,17,23,24 octakis[(n,n dimethylaminoethoxy)]phthalocyaninatozinc(ii) 2,3,9,10,16,17,23,24 octakis[(n,n,n triethylammonium)ethoxy]phthalocyaninatozinc(ii)octaiodide amido zinc(ii) phthalocyanine benzene derivative heterocyclic compound phthalocyanine derivative unclassified drug zinc acetate article drug synthesis matrix assisted laser desorption ionization time of flight mass spectrometry proton nuclear magnetic resonance reduction substitution reaction
spellingShingle	Nucleophilic aromatic substitution Phthalocyanines Reduction Dyes Positive ions Nucleophilic aromatic substitution Phthalocyanines Reduction Semiconducting zinc compounds 1,2 dicyano 4,5 di[(n,n dimethylaminocarbonyl)methoxy]benzene 1,8 diazabicyclo[5.4.0]undec 7 ene 2,3,9,10,16,17,23,24 octakis[(n,n dimethylaminocarbonyl)methoxy]phthalocyaninatozinc(ii) 2,3,9,10,16,17,23,24 octakis[(n,n dimethylaminoethoxy)]phthalocyaninatozinc(ii) 2,3,9,10,16,17,23,24 octakis[(n,n,n triethylammonium)ethoxy]phthalocyaninatozinc(ii)octaiodide amido zinc(ii) phthalocyanine benzene derivative heterocyclic compound phthalocyanine derivative unclassified drug zinc acetate article drug synthesis matrix assisted laser desorption ionization time of flight mass spectrometry proton nuclear magnetic resonance reduction substitution reaction Strassert, C.A. Dicelio, L.E. Awruch, J. Reduction of an amido zinc(II) phthalocyanine by diborane
topic_facet	Nucleophilic aromatic substitution Phthalocyanines Reduction Dyes Positive ions Nucleophilic aromatic substitution Phthalocyanines Reduction Semiconducting zinc compounds 1,2 dicyano 4,5 di[(n,n dimethylaminocarbonyl)methoxy]benzene 1,8 diazabicyclo[5.4.0]undec 7 ene 2,3,9,10,16,17,23,24 octakis[(n,n dimethylaminocarbonyl)methoxy]phthalocyaninatozinc(ii) 2,3,9,10,16,17,23,24 octakis[(n,n dimethylaminoethoxy)]phthalocyaninatozinc(ii) 2,3,9,10,16,17,23,24 octakis[(n,n,n triethylammonium)ethoxy]phthalocyaninatozinc(ii)octaiodide amido zinc(ii) phthalocyanine benzene derivative heterocyclic compound phthalocyanine derivative unclassified drug zinc acetate article drug synthesis matrix assisted laser desorption ionization time of flight mass spectrometry proton nuclear magnetic resonance reduction substitution reaction
description	1,2-Dicyano-4,5-di[(N,N-dimethylaminocarbonyl)methoxy]benzene (5) was synthesized in 80% yield from the corresponding 1,2-dibromo derivative 4. Octa(peripheral-amide)substituted zinc(II) phthalocyanine 6 was obtained from 5 and zinc acetate in the presence of 1,8-diazabicyclo[5.4.0]undec-7-ene. Phthalocyanine 7 was prepared via reduction of 6 with diborane. Treatment of 7 with methyl iodide afforded cationic dye 8. © Georg Thieme Verlag Stuttgart.
format	JOUR
author	Strassert, C.A. Dicelio, L.E. Awruch, J.
author_facet	Strassert, C.A. Dicelio, L.E. Awruch, J.
author_sort	Strassert, C.A.
title	Reduction of an amido zinc(II) phthalocyanine by diborane
title_short	Reduction of an amido zinc(II) phthalocyanine by diborane
title_full	Reduction of an amido zinc(II) phthalocyanine by diborane
title_fullStr	Reduction of an amido zinc(II) phthalocyanine by diborane
title_full_unstemmed	Reduction of an amido zinc(II) phthalocyanine by diborane
title_sort	reduction of an amido zinc(ii) phthalocyanine by diborane
url	http://hdl.handle.net/20.500.12110/paper_00397881_v_n5_p799_Strassert
work_keys_str_mv	AT strassertca reductionofanamidozinciiphthalocyaninebydiborane AT diceliole reductionofanamidozinciiphthalocyaninebydiborane AT awruchj reductionofanamidozinciiphthalocyaninebydiborane
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Reduction of an amido zinc(II) phthalocyanine by diborane

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